Safety Data Sheet Revision Number: 006.0 Issue date: 03/31/2015 IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE IDH number: 743915 Product type: Silicone Item number: 40481 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CONTENTS UNDER PRESSURE. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION.CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 GASES UNDER PRESSURE Liquef. Gas PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Protect from sunlight. Store in a well-ventilated place. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 2 of 6 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Distillates (petroleum), hydrotreated middle 64742-46-7 5 - 10 Silicon dioxide 7631-86-9 5 - 10 Norflurane 811-97-2 5 - 10 Substituted Silane Proprietary 1 - 5 Acetic acid 64-19-7 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. Ingestion: Do not induce vomiting. In case of adverse health effects seek medical advice. Symptoms: See Section 11. Notes to physician: Treat symptomatically. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: None Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. Oxides of silicon. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow material to contaminate ground water system. Clean-up methods: Scrape up as much material as possible. Spilled material will solidify. Store in a partly filled, closed container until disposal. Maintain good ventilation for large spills. IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 3 of 6 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Storage: For safe storage, store between 0 ?C (32?F) and 60 ?C (140?F) Keep container closed. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Distillates (petroleum), hydrotreated middle 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 PEL Mist. None None Silicon dioxide 6 mg/m3 TWA 20 MPPCF TWA 0.8 mg/m3 TWA None 3 mg/m3 TWA Respirable fraction. Norflurane None None 1,000 ppm (4,240 mg/m3) TWA None Substituted Silane None None None None Acetic acid 15 ppm STEL 10 ppm TWA 10 ppm (25 mg/m3) PEL None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Skin protection: Butyl rubber gloves. Chemical resistant, impermeable gloves. Nitrile gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Aerosol, Paste Color: Translucent Odor: Acetic acid Odor threshold: Not available. pH: Not available. Vapor pressure: < 10 mm hg (20 ?C (68?F)) Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.03 at 20 ?C (68?F) Vapor density: Heavier than air. Flash point: > 93.33 ?C (> 199.99 ?F) Tagliabue closed cup Flammable/Explosive limits - lower: 4 % (acetic acid) Flammable/Explosive limits - upper: 19.9 % (acetic acid) Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Not soluble. Polymerizes in presence of water. Partition coefficient (n-octanol/water): Not available. VOC content: 3.9 %; 39.4 g/l (calculated) Viscosity: Not available. Decomposition temperature: Not available. IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 4 of 6 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of silicon. Oxides of carbon. Acetic acid is liberated slowly upon contact with moisture. Formaldehyde. Incompatible materials: Acids. Bases. Oxidizing agents. Water Reactivity: Not available. Conditions to avoid: Prolonged heating at temperatures above 150 ?C. Exposure to moisture. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Acetic acid produced during cure may irritate eyes, nose and throat. When heated to temperatures exceeding 300? F (150? C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: Not expected under normal conditions of use. Not expected to be harmful by ingestion. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Distillates (petroleum), hydrotreated middle None Irritant Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Norflurane None Cardiac, Central nervous system, Irritant, Respiratory, Skin Substituted Silane None Irritant, Allergen Acetic acid Oral LD50 (RABBIT) = 1,200 mg/kg Oral LD50 (RAT) = 3.53 g/kg Oral LD50 (RAT) = 3.31 g/kg Dermal LD50 (RABBIT) = 1,060 mg/kg Inhalation LC50 (RAT, 4 h) = 11.4 mg/l Allergen, Corrosive, Eyes, Gastrointestinal, Immune system, Irritant, Kidney Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Distillates (petroleum), hydrotreated middle No No No Silicon dioxide No No No Norflurane No No No Substituted Silane No No No Acetic acid No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Cured rubber can be incinerated or landfilled following EPA and local regulations. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Aerosols Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Aerosols, non-flammable Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: AEROSOLS Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Pressure CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 03/31/2015 IDH number: 743915 Product name: LOCTITE SI 595 RTV SILICONE- CLEAR known as 595 RTV Clear 190 ml AE Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.