Lucas Marine Grease NLGI # 2 Not available. GHS product identifier Other means of identification Emergency telephone number (with hours of operation) Section 1. Identification : : : Identified uses Lucas Marine Grease NLGI # 2 SAFETY DATA SHEET Conforms to HazCom 2012/United States Not available. Product number : 10320, 10660 Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 Toll Free: (800) 342-2512 Tel: (951) 270-0154 Fax: (951) 270-1902 Website: www.LucasOil.com Supplier's details (951) 493-1149 (951) 847-5949 This email address is being protected from spambots. You need JavaScript enabled to view it. 7:00A.M. to 5:00P.M. Monday thru Friday : Section 2. Hazards identification SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Classification of the substance or mixture : Signal word : Warning Hazard statements : Causes serious eye irritation. Causes skin irritation. Hazard pictograms : Precautionary statements Prevention : Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling. GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 1/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 2. Hazards identification Response : IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Not applicable. Disposal : Not applicable. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Antimony, dialkyl dithiocarbamate 5 - 10 15890-25-2 Butene, homopolymer 1 - 5 9003-29-6 Lithium hydroxide, monohydrate 1 - 5 1310-66-3 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : 10320, 10660 CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation : : : Description of necessary first aid measures 2/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical No specific fire or explosion hazard. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : None known. Suitable extinguishing media : Unsuitable extinguishing media : 3/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 5. Fire-fighting measures No special measures are required. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Small spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. : Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling 4/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Antimony, dialkyl dithiocarbamate ACGIH TLV (United States, 6/2013). TWA: 0.5 mg/m?, (as Sb) 8 hours. OSHA PEL (United States, 2/2013). TWA: 0.5 mg/m?, (as Sb) 8 hours. NIOSH REL (United States, 4/2013). TWA: 0.5 mg/m?, (as Sb) 10 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 5/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Grease.] Not available. 0.92 >1 [Air = 1] Not available. Negligible. Petroleum.Odor pH Blue.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >200?C (>392?F) Not available. Not available. Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid High temperatures, sparks, or open flames. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Information on toxicological effects Acute toxicity Antimony, dialkyl dithiocarbamate LD50 Dermal Rabbit 16000 mg/kg - LD50 Oral Rat 16400 mg/kg - Product/ingredient name Result Species Dose Exposure 6/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 11. Toxicological information Carcinogenicity Specific target organ toxicity (single exposure) Irritation/Corrosion Sensitization There is no data available. There is no data available. There is no data available. Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact No known significant effects or critical hazards.General : Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Aspiration hazard Name Result Butene, homopolymer ASPIRATION HAZARD - Category 1 : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. There is no data available. 7/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 11. Toxicological information No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Oral 16835 mg/kg Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil There is no data available. There is no data available. Butene, homopolymer 7.6 to 7.8 314 to 1882 high Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods 8/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 14. Transport information - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : AERG : Not applicable. Section 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: Antimony, dialkyl dithiocarbamate : Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients No products were found. 9/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 15. Regulatory information None of the components are listed. No products were found. Massachusetts : SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. Antimony, dialkyl dithiocarbamate 15890-25-2 5 - 10 Antimony, dialkyl dithiocarbamate 15890-25-2 5 - 10 Form R - Reporting requirements Supplier notification California Prop. 65 New York : None of the components are listed. New Jersey : The following components are listed: Distillates (petroleum), hydrotreated heavy naphthenic; Distillates (petroleum), solvent-refined heavy paraffinic; Antimony, dialkyl dithiocarbamate; Lithium hydroxide, monohydrate Pennsylvania : The following components are listed: Antimony, dialkyl dithiocarbamate State regulations SARA 311/312 Classification : Immediate (acute) health hazard Butene, homopolymer 1 - 5 No. No. No. Yes. No. Lithium hydroxide, monohydrate 1 - 5 No. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Section 16. Other information History Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.) Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue mm/dd/yyyy : 03/15/2014 Health : 1* Flammability :2 Physical hazards : 0 Health : 012 Instability :Flammability : 10/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com Lucas Marine Grease NLGI # 2 Section 16. Other information Prepared by : Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Version : 1 KMK Regulatory Services Inc. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Revised Section(s) : Not applicable. 11/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com