3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2020, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-0717-2 Version Number: 6.00 Issue Date: 01/16/20 Supercedes Date: 10/22/18 SECTION 1: Identification 1.1. Product identifier 3M? Acryl-Red Glazing Putty PN 05098 Product Identification Numbers 41-0003-6503-5, 41-0003-8045-5, 60-4550-4985-2, GT-6000-1812-8 7000045481 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Acute Toxicity (inhalation): Category 4. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Skin Sensitizer: Category 1B. Reproductive Toxicity: Category 1B. Specific Target Organ Toxicity (single exposure): Category 2. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 2 of 14 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause drowsiness or dizziness. May damage fertility or the unborn child. May cause damage to organs: respiratory system | Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 3 of 14 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Call a POISON CENTER or doctor/physician. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 11% of the mixture consists of ingredients of unknown acute oral toxicity. 11% of the mixture consists of ingredients of unknown acute dermal toxicity. 80% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Talc 14807-96-6 30 - 60 Trade Secret * Toluene 108-88-3 10 - 30 Trade Secret * N-Butyl Acetate 123-86-4 7 - 13 Trade Secret * Magnesium Carbonate 546-93-0 5 - 10 Trade Secret * Benzoate Esters Trade Secret* 5 - 10 Trade Secret * Nitrocellulose 9004-70-0 3 - 7 Trade Secret * Iron Oxide 1332-37-2 1 - 5 Trade Secret * Isopropyl Alcohol 67-63-0 1 - 5 Trade Secret * Rosin, Maleated, Esters with Glycerol 68038-41-5 1 - 5 Trade Secret * Chlorite (Mineral) 1318-59-8 0.1 - 1.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 4 of 14 If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 5 of 14 Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm N-Butyl Acetate 123-86-4 ACGIH TWA:50 ppm;STEL:150 ppm N-Butyl Acetate 123-86-4 OSHA TWA:710 mg/m3(150 ppm) Talc 14807-96-6 OSHA TWA:2 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Magnesium Carbonate 546-93-0 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. Provide appropriate local exhaust ventilation for sanding, grinding or machining. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 6 of 14 Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Red Odor Solvent Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point > 96 ?F [Details:MITS data] Flash Point 48 ?F [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.27 % Flammable Limits(UEL) 7.00 % Vapor Pressure <=27 psia [@ 131.0000000000 ?F] [Details:MITS data] Vapor Density 4.00 [Ref Std:AIR=1] Density 1.510 - 1.560 g/ml Specific Gravity 1.510 - 1.560 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 90,000 - 170,000 centipoise [@ 73.4 ?F ] [Details:MITS data] Hazardous Air Pollutants 0.287 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 464 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 30.3 % weight [Test Method:calculated per CARB title 2] Percent volatile 30.3 % weight VOC Less H2O & Exempt Solvents 464 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 7 of 14 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 8 of 14 Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE1 - 5 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg N-Butyl Acetate Dermal Rabbit LD50 > 5,000 mg/kg N-Butyl Acetate Inhalation- Dust/Mist (4 hours) Rat LC50 1.4 mg/l N-Butyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 20 mg/l N-Butyl Acetate Ingestion Rat LD50 > 8,800 mg/kg Magnesium Carbonate Dermal Professio nal judgeme nt LD50 estimated to be 2,000 - 5,000 mg/kg 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 9 of 14 Magnesium Carbonate Ingestion Rat LD50 > 2,000 mg/kg Nitrocellulose Dermal LD50 estimated to be > 5,000 mg/kg Nitrocellulose Ingestion Rat LD50 > 5,000 mg/kg Isopropyl Alcohol Dermal Rabbit LD50 12,870 mg/kg Isopropyl Alcohol Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l Isopropyl Alcohol Ingestion Rat LD50 4,710 mg/kg Iron Oxide Dermal Not available LD50 3,100 mg/kg Iron Oxide Ingestion Not available LD50 3,700 mg/kg Rosin, Maleated, Esters with Glycerol Dermal Professio nal judgeme nt LD50 estimated to be > 5,000 mg/kg Rosin, Maleated, Esters with Glycerol Ingestion Rat LD50 > 5,000 mg/kg Chlorite (Mineral) Dermal LD50 estimated to be > 5,000 mg/kg Chlorite (Mineral) Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Talc Rabbit No significant irritation Toluene Rabbit Irritant N-Butyl Acetate Rabbit Minimal irritation Magnesium Carbonate In vitro data No significant irritation Nitrocellulose Professio nal judgeme nt No significant irritation Isopropyl Alcohol Multiple animal species No significant irritation Iron Oxide Rabbit No significant irritation Rosin, Maleated, Esters with Glycerol Rabbit No significant irritation Chlorite (Mineral) Professio nal judgeme nt No significant irritation Serious Eye Damage/Irritation Name Species Value Talc Rabbit No significant irritation Toluene Rabbit Moderate irritant N-Butyl Acetate Rabbit Moderate irritant Magnesium Carbonate Rabbit Mild irritant Nitrocellulose Professio nal judgeme nt No significant irritation Isopropyl Alcohol Rabbit Severe irritant Iron Oxide Rabbit No significant irritation Rosin, Maleated, Esters with Glycerol Rabbit Moderate irritant Chlorite (Mineral) Professio nal judgeme nt No significant irritation Skin Sensitization 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 10 of 14 Name Species Value Toluene Guinea pig Not classified N-Butyl Acetate Multiple animal species Not classified Isopropyl Alcohol Guinea pig Not classified Iron Oxide Human Not classified Rosin, Maleated, Esters with Glycerol Mouse Sensitizing Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic N-Butyl Acetate In Vitro Not mutagenic Isopropyl Alcohol In Vitro Not mutagenic Isopropyl Alcohol In vivo Not mutagenic Iron Oxide In Vitro Not mutagenic Rosin, Maleated, Esters with Glycerol In Vitro Not mutagenic Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Isopropyl Alcohol Inhalation Rat Some positive data exist, but the data are not sufficient for classification Iron Oxide Inhalation Human Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Talc Ingestion Not classified for development Rat NOAEL 1,600 mg/kg during organogenesi s Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse N-Butyl Acetate Inhalation Not classified for female reproduction Rat NOAEL 7.1 mg/l premating & during gestation 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 11 of 14 N-Butyl Acetate Inhalation Not classified for development Rat NOAEL 7.1 mg/l premating & during gestation Isopropyl Alcohol Ingestion Not classified for development Rat NOAEL 400 mg/kg/day during organogenesi s Isopropyl Alcohol Inhalation Not classified for development Rat LOAEL 9 mg/l during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse N-Butyl Acetate Inhalation respiratory system May cause damage to organs Rat LOAEL 2.6 mg/l 4 hours N-Butyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available N-Butyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available not available N-Butyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Isopropyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Isopropyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Isopropyl Alcohol Inhalation auditory system Not classified Guinea pig NOAEL 13.4 mg/l 24 hours Isopropyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Rosin, Maleated, Esters with Glycerol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Not classified Rat NOAEL 18 mg/m3 113 weeks Toluene Inhalation auditory system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation nervous system May cause damage to organs though prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 12 of 14 Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks N-Butyl Acetate Inhalation olfactory system Not classified Rat NOAEL 2.4 mg/l 14 weeks N-Butyl Acetate Inhalation liver | kidney and/or bladder Not classified Rabbit NOAEL 7.26 mg/l 13 days Isopropyl Alcohol Inhalation kidney and/or bladder Not classified Rat NOAEL 12.3 mg/l 24 months Isopropyl Alcohol Inhalation nervous system Not classified Rat NOAEL 12 mg/l 13 weeks Isopropyl Alcohol Ingestion kidney and/or bladder Not classified Rat NOAEL 400 mg/kg/day 12 weeks Iron Oxide Inhalation pulmonary fibrosis | pneumoconiosis Not classified Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Toluene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 13 of 14 facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Acute toxicity Reproductive toxicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret 10 - 30 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None 3M? Acryl-Red Glazing Putty PN 05098 01/16/20 __________________________________________________________________________________________ Page 14 of 14 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-0717-2 Version Number: 6.00 Issue Date: 01/16/20 Supercedes Date: 10/22/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com