G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 1 of 10 Safety Data Sheet Copyright,2018Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 39-2021-2 Version Number: 1.02 Issue Date: 07/17/18 Supercedes Date: 07/12/18 SECTION 1: Identification 1.1. Product identifier G1903, Ultimate Tire Shine (31-19B): G190315 1.2. Recommended use and restrictions on use Recommended use Protective Coating 1.3. Supplier?s details MANUFACTURER: Meguiar's, Inc. DIVISION: Meguiar's ADDRESS: 17991 Mitchell South, Irvine, CA 92614, USA Telephone: 949-752-8000 (Fax: 949-752-5784) 1.4. Emergency telephone number CHEMTREC 1-800-424-9300 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Compressed gas. Serious Eye Damage/Irritation: Category 2A. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Gas cylinder G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 2 of 10 Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 8% of the mixture consists of ingredients of unknown acute oral toxicity. 8% of the mixture consists of ingredients of unknown acute dermal toxicity. 21% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt METHYL ACETATE 79-20-9 10 - 30 Trade Secret * Acetone 67-64-1 5 - 15 Trade Secret * Any remaining components do not contribute to the hazards of this material. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 3 of 10 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 4 of 10 Ingredient C.A.S. No. Agency Limit type Additional Comments Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) METHYL ACETATE 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm METHYL ACETATE 79-20-9 OSHA TWA:610 mg/m3(200 ppm) authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 5 of 10 clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Slight Chemical Odor, Clear, Liquid Aerosol Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point No Data Available Flash Point 20 ?F [Test Method:Estimated] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.78 g/cm3 Specific Gravity 0.78 [Ref Std:WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 50 centipoise Average particle size No Data Available Bulk density No Data Available Hazardous Air Pollutants No Data Available Molecular weight No Data Available Volatile Organic Compounds 22.6 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 178 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 62.3 % weight [Test Method:Estimated] Softening point No Data Available VOC Less H2O & Exempt Solvents 275 g/l [Test Method:calculated SCAQMD rule 443.1] * The values noted with an asterisk (*) in the above table are representative values based on testing of raw materials and selected products. Additionally, a material's characteristics may change depending upon the process and conditions of use at a facility, including further changes in particle size, or mixture with other materials. In order to obtain specific data for the material, we recommend the user conduct characterization testing based on the use factors at the specific facility. G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 6 of 10 SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Not determined 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 7 of 10 Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg METHYL ACETATE Dermal Rat LD50 > 2,000 mg/kg METHYL ACETATE Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l METHYL ACETATE Ingestion Rat LD50 > 5,000 mg/kg Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Vapor (4 hours) Rat LC50 76 mg/l Acetone Ingestion Rat LD50 5,800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value METHYL ACETATE Rabbit No significant irritation Acetone Mouse Minimal irritation Serious Eye Damage/Irritation Name Species Value METHYL ACETATE Rabbit Moderate irritant Acetone Rabbit Severe irritant Skin Sensitization Name Species Value METHYL ACETATE Human Not classified Respiratory Sensitization For the component/components, either no data are currently available, or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value METHYL ACETATE In Vitro Not mutagenic METHYL ACETATE In vivo Not mutagenic Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 8 of 10 Name Route Species Value Name Route Target Organ(s) Value Species Test Result Exposure Duration METHYL ACETATE Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days METHYL ACETATE Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL 6.1 mg/l 28 days Acetone Dermal eyes Not classified Guinea pig NOAEL Not available 3 weeks Acetone Inhalation hematopoietic system Not classified Human NOAEL 3 mg/l 6 weeks Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 days Acetone Inhalation kidney and/or bladder Not classified Guinea pig NOAEL 119 mg/l not available Acetone Inhalation heart | liver Not classified Rat NOAEL 45 mg/l 8 weeks Acetone Ingestion kidney and/or Not classified Rat NOAEL 900 13 weeks Carcinogenicity Acetone Not Specified Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700 mg/kg/day 13 weeks Acetone Inhalation Not classified for development Rat NOAEL 5.2 mg/l during organogenesis Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration METHYL ACETATE Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available METHYL ACETATE Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available METHYL ACETATE Inhalation blindness Not classified NOAEL Not available METHYL ACETATE Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Acetone Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 hours Acetone Inhalation liver Not classified Guinea pig NOAEL Not available Acetone Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 9 of 10 bladder mg/kg/day Acetone Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion hematopoietic system Not classified Rat NOAEL 200 mg/kg/day 13 weeks Acetone Ingestion liver Not classified Mouse NOAEL 3,896 mg/kg/day 14 days Acetone Ingestion eyes Not classified Rat NOAEL 3,400 mg/kg/day 13 weeks Acetone Ingestion respiratory system Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion muscles Not classified Rat NOAEL 2,500 mg/kg 13 weeks Acetone Ingestion skin | bone, teeth, nails, and/or hair Not classified Mouse NOAEL 11,298 mg/kg/day 13 weeks Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information DOTG: LIMITED QUANTITY DOTW: UN1950, AEROSOLS, 2.1, LIMITED QUANTITY G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 10 of 10 IATA: UN 1950, AEROSOLS, FLAMMABLE, 2.1 IMO: UN 1950, AEROSOLS, 2.1, LIMITED QUANTITY Please contact the emergency numbers listed on the first page of the SDS for Transportation Information for this material. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact manufacturer for more information EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 1 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 39-2021-2 Version Number: 1.02 Issue Date: 07/17/18 Supercedes Date: 07/12/18 G1903, Ultimate Tire Shine (31-19B): G190315 07/17/18 Page 11 of 10 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. Meguiar's, Inc. MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the Meguiar's, Inc. product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a Meguiar's, Inc. product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the Meguiar's, Inc. product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Meguiar's, Inc. provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, Meguiar's, Inc. makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from Meguiar's, Inc. Meguiar's, Inc. USA SDSs are available at www.Meguiars.com