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G181302 AIR RFSHR BLK CHRM
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Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 1 of 10 SECTION 1: Identification SECTION 2: Hazard identification Safety Data Sheet Copyright,2022, Meguiar's Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing Meguiar's Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 38-4409-9 Version Number: 3.01 Issue Date: 09/02/22 Supercedes Date: 04/13/20 1.1. Product identifier Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] Product Identification Numbers 14-1001-1683-0, 14-1001-2070-9 7012131356, 7012131360 1.2. Recommended use and restrictions on use Recommended use Automotive, Car Air Freshener 1.3. Supplier?s details MANUFACTURER: Meguiar's, Inc. DIVISION: Meguiar's ADDRESS: 17991 Mitchell South, Irvine, CA 92614, USA Telephone: 949-752-8000 (Fax: 949-752-5784) 1.4. Emergency telephone number CHEMTREC 1-800-424-9300 (24 hours) The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. 2.2. Label elements Signal word Danger Symbols Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 2 of 10 SECTION 3: Composition/information on ingredients SECTION 4: First aid measures Flame | Gas cylinder | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Ingredient C.A.S. No. % by Wt Propene, 1,3,3,3,-tetrafluoro-,(E)- 29118-24-9 60 - 80 Trade Secret * Ethyl Alcohol 64-17-5 10 - 30 Trade Secret * Any remaining components do not contribute to the hazards of this material. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: No need for first aid is anticipated. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. If Swallowed: No need for first aid is anticipated. 4.2. Most important symptoms and effects, both acute and delayed No critical symptoms or effects. See Section 11.1, information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 3 of 10 SECTION 5: Fire-fighting measures SECTION 6: Accidental release measures SECTION 7: Handling and storage SECTION 8: Exposure controls/personal protection Not applicable 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire extinguishing foam that is resistant to polar solvents. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. 7.1. Precautions for safe handling Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 8.1. Control parameters Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 4 of 10 SECTION 9: Physical and chemical properties Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1-Propene, 1,3,3,3-tetrafluoro- 29118-24-9 AIHA TWA:800 ppm Ethyl Alcohol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal carcin. Ethyl Alcohol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection No chemical protective gloves are required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Clear Colorless Odor Fresh Odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 13 ?F Flash Point 58 ?F Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 5 of 10 SECTION 10: Stability and reactivity SECTION 11: Toxicological information Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.81 g/ml Specific Gravity 0.81 Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 % weight Volatile Organic Compounds 24.3 % weight [Test Method:calculated per CARB title 2] Percent volatile 97.1 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 198.4 g/l [Test Method:calculated SCAQMD rule 443.1] 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids 10.6. Hazardous decomposition products Substance Condition None known. The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 6 of 10 Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: No known health effects. Additional Information: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Propene, 1,3,3,3,-tetrafluoro-,(E)- Inhalation- Gas (4 hours) Rat LC50 > 207,000 ppm Ethyl Alcohol Dermal Rabbit LD50 > 15,800 mg/kg Ethyl Alcohol Inhalation- Vapor (4 hours) Rat LC50 124.7 mg/l Ethyl Alcohol Ingestion Rat LD50 17,800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Propene, 1,3,3,3,-tetrafluoro-,(E)- Rabbit No significant irritation Ethyl Alcohol Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Ethyl Alcohol Rabbit Severe irritant Skin Sensitization Name Species Value Ethyl Alcohol Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 7 of 10 Propene, 1,3,3,3,-tetrafluoro-,(E)- In Vitro Not mutagenic Propene, 1,3,3,3,-tetrafluoro-,(E)- In vivo Not mutagenic Ethyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Ethyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Ethyl Alcohol Ingestion Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Propene, 1,3,3,3,-tetrafluoro-,(E)- Inhalation Not classified for female reproduction Rat NOAEL 20,000 ppm 2 generation Propene, 1,3,3,3,-tetrafluoro-,(E)- Inhalation Not classified for male reproduction Rat NOAEL 20,000 ppm 2 generation Propene, 1,3,3,3,-tetrafluoro-,(E)- Inhalation Not classified for development Rat NOAEL 15,000 ppm during gestation Ethyl Alcohol Inhalation Not classified for development Rat NOAEL 38 mg/l during gestation Ethyl Alcohol Ingestion Not classified for development Rat NOAEL 5,200 mg/kg/day premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human LOAEL 9.4 mg/l not available Ethyl Alcohol Inhalation central nervous system depression Not classified Human and animal NOAEL not available Ethyl Alcohol Ingestion central nervous system depression Not classified Multiple animal species NOAEL not available Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Propene, 1,3,3,3,- tetrafluoro-,(E)- Inhalation heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 5,000 ppm 91 days Propene, 1,3,3,3,- Inhalation hematopoietic Not classified Rat NOAEL 91 days tetrafluoro-,(E)- system | skin | 15,000 ppm endocrine system | gastrointestinal tract | bone, teeth, nails, and/or hair | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 8 of 10 SECTION 12: Ecological information SECTION 13: Disposal considerations SECTION 14: Transport Information system | vascular system Ethyl Alcohol Inhalation liver Some positive data exist, but the data are not sufficient for classification Rabbit LOAEL 124 mg/l 365 days Ethyl Alcohol Inhalation hematopoietic system | immune system Not classified Rat NOAEL 25 mg/l 14 days Ethyl Alcohol Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 8,000 mg/kg/day 4 months Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg/day 7 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. DOTG: LIMITED QUANTITY DOTW: UN1950, AEROSOLS, 2.1, LIMITED QUANTITY IATA: UN1950, AEROSOLS, FLAMMABLE, 2.1 IMO: UN1950, AEROSOLS, 2.1, LIMITED QUANTITY Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 9 of 10 Please contact the emergency numbers listed on the first page of the SDS for Transportation Information for this material. SECTION 15: Regulatory information Not applicable Health Hazards This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information 15.1. US Federal Regulations Contact manufacturer for more information EPCRA 311/312 Hazard Classifications: 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information NFPA Hazard Classification Health: 1 Flammability: 4 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 38-4409-9 Version Number: 3.01 Issue Date: 09/02/22 Supercedes Date: 04/13/20 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. Meguiar's Inc. MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the Meguiar's Inc. product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a Meguiar's Inc. product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the Meguiar's Inc. product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Gas under pressure Flammable (gases, aerosols, liquids, or solids) Physical Hazards Air Re-Fresher Odor Eliminator (Whole Car) Black Chrome Scent G1813 [G181302] 09/02/22 Page 10 of 10 Meguiar's Inc. provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, Meguiar's Inc. makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from Meguiar's Inc. Meguiar's, Inc. USA SDSs are available at www.Meguiars.com