SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 1 / 14 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? Full Synthetic Moly Fortified Gray Grease Product code : VV986 Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : Causes serious eye irritation. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 2 / 14 Other hazards The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: 98.9999 % SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 Skin Irrit. 2; H315 Eye Dam. 1; H318 >=1.00 - < 1.50 MOLYBDENUM DISULFIDE 1317-33-5 Not a hazardous substance or mixture. >=1.00 - < 1.50 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and : No symptoms known or expected. Causes serious eye irritation. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 3 / 14 delayed Notes to physician : No hazards which require special first aid measures. Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Unsuitable extinguishing media : High volume water jet Hazardous combustion products : No hazardous combustion products are known Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 4 / 14 Advice on safe handling : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis MOLYBDENUM DISULFIDE 1317-33-5 TWA 15 mg/m3 total dust (Molybdenum) OSHA Z-1 TWA 10 mg/m3 Inhalable particulate matter (Molybdenum) ACGIH TWA 3 mg/m3 Respirable particulate matter (Molybdenum) ACGIH TWA 10 mg/m3 Total dust (Molybdenum) OSHA P0 PEL 10 mg/m3 Total dust (Molybdenum) CAL PEL PEL 3 mg/m3 respirable dust fraction (Molybdenum) CAL PEL Personal protective equipment Respiratory protection : A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 5 / 14 purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : paste Colour : dark grey Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : 500 ?F / 260 ?C Boiling point/boiling range : 700 ?F / 371 ?C Flash point : 439 ?F / 226 ?C SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 6 / 14 Evaporation rate : No data available Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : No data available Density : 0.9084 g/cm3 (68 ?F / 20 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Ignition temperature : > 599 ?F / > 315 ?C Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : > 20.5 mm2/s (104 ?F / 40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 7 / 14 Possibility of hazardous reactions : No decomposition if stored and applied as directed. Conditions to avoid : None known. None known. No data available Incompatible materials : Strong oxidizing agents Not applicable Hazardous decomposition products No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : LD50 (Rat): 93,458 mg/kg Method: Acute toxicity estimate Acute dermal toxicity : LD50 (Rabbit): 2,599 mg/kg Method: Acute toxicity estimate Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Acute oral toxicity : LD50 (Rat): > 2,000 - 5,000 mg/kg Remarks: The toxicological data has been taken from products of similar composition. Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Remarks: The toxicological data has been taken from products of similar composition. MOLYBDENUM DISULFIDE: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 2.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Skin corrosion/irritation Not classified based on available information. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 8 / 14 Product: Result : No skin irritation Remarks : May cause skin irritation in susceptible persons. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Result : Irritating to skin. MOLYBDENUM DISULFIDE: Result : No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks : May cause irreversible eye damage. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Result : Corrosive MOLYBDENUM DISULFIDE: Result : No eye irritation Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 9 / 14 Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Toxicity to fish : LC50 (Fish): > 1 - 10 mg/l Exposure time: 96 h Remarks: The toxicological data has been taken from products of similar composition. Toxicity to daphnia and other aquatic invertebrates : EC50 (Aquatic invertebrates): > 10 - 100 mg/l Exposure time: 48 h Remarks: The toxicological data has been taken from products of similar composition. Toxicity to algae : EC50 (green algae): > 10 - 100 mg/l Exposure time: 72 h Remarks: The toxicological data has been taken from products of similar composition. Persistence and degradability Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Biodegradability : Biodegradation: 1.5 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: No data available Mobility in soil Components: No data available Other adverse effects No data available SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 10 / 14 Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations CFR_ROAD Not regulated as a dangerous good Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 11 / 14 SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Serious eye damage or eye irritation SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Phosphorodithioi c acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 >= 1 - < 5 % Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 >= 1 - < 5 % This product does not contain any priority pollutants related to the U.S. Clean Water Act The components of this product are reported in the following inventories: SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 12 / 14 TCSI : Not in compliance with the inventory TSCA : On the inventory, or in compliance with the inventory AIIC : Not in compliance with the inventory DSL : This product contains the following components that are not on the Canadian DSL nor NDSL. ENCS : Not in compliance with the inventory ISHL : Not in compliance with the inventory KECI : Not in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : Not in compliance with the inventory NZIoC : Not in compliance with the inventory TECI : Not in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. Inventories AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI (Thailand), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Internal information : R0257033 NFPA: HMIS III: SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 13 / 14 NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H315 Causes skin irritation. H318 Causes serious eye damage. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2/ Special hazard 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET Valvoline? Full Synthetic Moly Fortified Gray Grease Version: 1.4 Revision Date: 10/22/2021 Print Date: 06/21/2023 14 / 14 ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System