Safety Data Sheet Revision Number: 002.0 Issue date: 04/02/2014 IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT IDH number: 504465 Product type: Ultraviolet adhesive Item number: 37613 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: 860.571.5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: COMBUSTIBLE LIQUID. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE DAMAGE. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 4 SKIN IRRITATION 2 SERIOUS EYE DAMAGE 1 SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat,sparks, open flames, hot surfaces - no smoking. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. 5 % of the mixture consists of ingredient(s) of unknown acute toxicity. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 2 of 6 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Hydroxyalkyl methacrylate 27813-02-1 30 - 60 Propoxylated diacrylate Proprietary 30 - 60 Acrylic acid 79-10-7 1 - 5 Substituted silane Proprietary 1 - 5 2-Hydroxy-2-methylpropiophenone 7473-98-5 1 - 5 Subsituted Silane Proprietary 0.1 - 1 Methacrylic acid 79-41-4 0.1 - 1 Polyglycol dimethacrylate Proprietary 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Wash with soap and water. Remove contaminated clothing and footwear. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Keep individual calm. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: Not available. Hazardous combustion products: Oxides of carbon. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 3 of 6 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Storage: For safe storage, store at or below 38 ?C (100.4 ?F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Hydroxyalkyl methacrylate None None None 1 ppm TWA 3 ppm STEL Propoxylated diacrylate None None None None Acrylic acid 2 ppm TWA (SKIN) None None 1 ppm TWA 3 ppm STEL (SKIN) Substituted silane None None None None 2-Hydroxy-2-methylpropiophenone None None None 1 mg/m3 Subsituted Silane None None None None Methacrylic acid 20 ppm TWA None None None Polyglycol dimethacrylate None None None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Clear Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (27 ?C (80.6 ?F)) Boiling point/range: > 149 ?C (> 300.2 ?F) Melting point/ range: Not available. Specific gravity: 1.03 Vapor density: Not available. Flash point: 65 ?C (149?F) Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: Not available. Viscosity: Not available. Decomposition temperature: Not available. IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 4 of 6 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Irritating organic vapours. Incompatible materials: Strong oxidizing agents. Strong reducing agents. Acids. Alkalis. Other polymerization initiators. Reactivity: Not available. Conditions to avoid: Store away from incompatible materials. See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10). 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: May cause irritation to nose and throat. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye damage. Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Hydroxyalkyl methacrylate None Irritant, Allergen Propoxylated diacrylate None Allergen, Irritant Acrylic acid Oral LD50 (RAT) = 33.5 mg/kg Oral LD50 (RAT) = 2.5 g/kg Oral LD50 (RAT) = 193 mg/kg Oral LD50 (RAT) = 1,250 mg/kg Inhalation LC50 (RAT, 4 h) = 1,200 mg/l Allergen, Corrosive, Irritant, Kidney, Liver Substituted silane None Allergen, Irritant 2-Hydroxy-2-methylpropiophenone None No Target Organs Subsituted Silane None Irritant, Allergen Methacrylic acid Oral LD50 (RABBIT) = 1,200 mg/kg Oral LD50 (RAT) = 1,060 mg/kg Oral LD50 (RAT) = 2,224 mg/kg Dermal LD50 (RABBIT) = 500 mg/kg Inhalation LC50 (RAT, 4 h) = 7.1 mg/l Corrosive, Irritant, Allergen Polyglycol dimethacrylate None Irritant, Allergen Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Hydroxyalkyl methacrylate No No No Propoxylated diacrylate No No No Acrylic acid No No No Substituted silane No No No 2-Hydroxy-2-methylpropiophenone No No No Subsituted Silane No No No Methacrylic acid No No No Polyglycol dimethacrylate No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Combustible liquid, n.o.s. (Acrylic acid) Hazard class or division: Combustible Liquid Identification number: NA 1993 Packing group: III International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Fire CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Acrylic acid (CAS# 79-10-7). California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 04/02/2014 IDH number: 504465 Product name: LOCTITE 504465 WINDSHIELD REPAIR KIT known as LOCTITE? WINDSHIELD REPAIR KIT Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.