Safety Data Sheet Revision Number: 003.0 Issue date: 08/19/2014 IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant IDH number: 503049 Product type: Lubricant Item number: 37584 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CONTENTS UNDER PRESSURE. FLAMMABLE AEROSOL. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE AEROSOL. 2 SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 2 of 6 governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Butane 106-97-8 10 - 30 Ammonia, aqueous solution Proprietary 0.1 - 1 Silicone Resin Proprietary 1 - 5 Propane 74-98-6 5 - 10 Petroleum Based Oil Proprietary 1 - 5 Naphtha, petroleum, heavy alkylate, <0.1% Benzene 64741-65-7 5 - 10 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Remove contaminated clothing and footwear. Wipe off with paper towel or cloth. Wash with soap and water. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Keep individual calm. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Vapor accumulation can flash or explode if ignited. Do not handle or store near an open flame, heat or other sources of ignition. Hazardous combustion products: Oxides of carbon. Oxides of silicon. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 3 of 6 Clean-up methods: Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep away from heat, spark and flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of ignition. Storage: Do not puncture, incinerate, or expose to temperatures above 48.9 ?C (120 ?F). Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Butane 1,000 ppm STEL None None None Ammonia, aqueous solution None None None None Silicone Resin None None None None Propane Included in the regulation but with no data values. See regulation for further details 1,000 ppm (1,800 mg/m3) PEL None None Petroleum Based Oil 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 TWA mist 5 mg/m3 PEL Mist. None None Naphtha, petroleum, heavy alkylate, <0.1% Benzene 5 mg/m3 TWA 5 mg/m3 TWA None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. In case of insufficient ventilation, wear suitable respiratory equipment. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Aerosol Color: Clear Odor: Petroleum Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: 0 - 211 ?F (-17.8 - 99.4 ?C) None Melting point/ range: Not available. Specific gravity: 0.81 Vapor density: Not available. IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 4 of 6 Flash point: < -18 ?C (< 0.4 ?F) Flashback: This product exhibits flashback when tested for flame extension. Flame projection: 18.00 cm (7.09 inch) Flammable/Explosive limits - lower: 1 % Flammable/Explosive limits - upper: 9.5 % Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. VOC content: 34 % Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Oxides of silicon. Irritating organic fragments. Incompatible materials: Strong oxidizing agents. Acids and bases. Avoid contact with flammable materials. Reactivity: Not available. Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 5 of 6 Potential Health Effects/Symptoms Inhalation: May cause respiratory tract irritation. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Skin contact: Causes skin irritation. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Eye contact: Causes serious eye irritation. Ingestion: Not a likely route of entry. May be harmful if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Butane Inhalation LC50 (RAT, 4 h) = 658 mg/l Cardiac, Central nervous system, Irritant Ammonia, aqueous solution Oral LD50 (RAT) = 350 mg/kg Irritant, Corrosive Silicone Resin None Irritant Propane Inhalation LC50 (RAT, 15 min) = > 1,442.847 mg/l Inhalation LC50 (RAT, 15 min) = > 1,464 mg/l Cardiac, Central nervous system, Irritant Petroleum Based Oil None Irritant Naphtha, petroleum, heavy alkylate, <0.1% Benzene None Irritant Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Butane No No No Ammonia, aqueous solution No No No Silicone Resin No No No Propane No No No Petroleum Based Oil No No No Naphtha, petroleum, heavy alkylate, <0.1% Benzene No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Depressurize cans. Do not incinerate. Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None IDH number: 503049 Product name: LOCTITE LB 8801 SIL LUBRICATION known as Silicone Lubricant Page 6 of 6 Water Transportation (IMO/IMDG) Proper shipping name: AEROSOLS Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire, Sudden Release CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: Butane (CAS# 106-97-8) 100 lbs. (45.4 kg) Propane (CAS# 74-98-6) 100 lbs. (45.4 kg) California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 08/19/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.