Safety Data Sheet Revision Number: 005.0 Issue date: 08/28/2014 IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite Copper Anti-Seize IDH number: 504468 Product type: Lubricant Item number: 37616 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 2 of 6 Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 30 - 60 Copper 7440-50-8 10 - 30 Graphite 7782-42-5 10 - 30 Petroleum distillates, hydrotreated, light naphthenic 64742-53-6 10 - 30 Quartz (SiO2) 14808-60-7 1 - 5 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention. Skin contact: Wash with soap and water. If symptoms develop and persist, get medical attention. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Aspiration may cause pulmonary edema and pneumonitis. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Dry chemical. Carbon dioxide. foam Special firefighting procedures: None Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: No special environmental precautions required. Clean-up methods: Follow all local, state, federal and provincial regulations for disposal. Scrape up as much material as possible. Clean residue with soap and water. 7. HANDLING AND STORAGE Handling: Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Keep container closed. Storage: Keep in a cool, well ventilated area. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 3 of 6 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Distillates (petroleum), hydrotreated heavy naphthenic 5 mg/m3 TWA mist 10 mg/m3 STEL mist 5 mg/m3 TWA mist 500 ppm (2,000 mg/m3) PEL 5 mg/m3 PEL Mist. None None Copper 0.2 mg/m3 TWA (as Cu) Fume. 1 mg/m3 TWA (as Cu) Dust and mist. 1 mg/m3 PEL (as Cu) Dust and mist. 0.1 mg/m3 PEL (as Cu) Fume. None None Graphite 2 mg/m3 TWA Respirable fraction. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. 15 MPPCF TWA None None Petroleum distillates, hydrotreated, light naphthenic None 500 ppm (2,000 mg/m3) PEL 5 mg/m3 PEL Mist. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Use only with adequate ventilation. Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Observe OSHA regulations for respirator use (29 CFR 1910.134). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Color: Copper Odor: Mild, Petroleum Odor threshold: Not available. pH: Not applicable Vapor pressure: Not determined Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.18 Vapor density: Not determined Flash point: Product is a solid. Burn Rate: Approx 14 mm/2 minutes Flammable/Explosive limits - lower: Not determined Flammable/Explosive limits - upper: Not determined Autoignition temperature: Not determined Evaporation rate: Not determined Solubility in water: Insoluble Partition coefficient (n-octanol/water): Not determined VOC content: 0 % Viscosity: Not available. Decomposition temperature: Not available. IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 4 of 6 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Incompatible materials: Oxidizing agents. Reactivity: Not available. Conditions to avoid: None known 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Eyes, Skin Potential Health Effects/Symptoms Inhalation: Inhalation of copper fumes may result in metal fume fever. Symptoms include metallic taste, discoloration of skin or hair. This product has low volatility and is not expected to cause respiratory tract irritation during normal conditions of use. May cause respiratory tract irritation. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Principal hazard of ingestion is aspiration into the lungs and subsequent pneumonitis. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Distillates (petroleum), hydrotreated heavy naphthenic None Irritant Copper None Allergen, Blood, Central nervous system, Developmental, Gastrointestinal, Immune system, Irritant, Kidney, Liver, Mutagen, Sensory, Skin Graphite None Lung Petroleum distillates, hydrotreated, light naphthenic None Irritant Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Distillates (petroleum), hydrotreated heavy naphthenic No No No Copper No No No Graphite No No No Petroleum distillates, hydrotreated, light naphthenic No No No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper) Hazard class or division: 9 Identification number: UN 3077 Packing group: III Marine pollutant: Copper 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Copper (CAS# 7440-50-8). California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 08/28/2014 IDH number: 504468 Product name: Loctite Copper Anti-Seize Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.