Safety Data Sheet Revision Number: 007.0 Issue date: 03/31/2015 IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE IDH number: 756302 Product type: Silicone sealant Item number: 40505 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CONTENTS UNDER PRESSURE. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HARMFUL IF INHALED.CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. HAZARD CLASS HAZARD CATEGORY ACUTE TOXICITY INHALATION 4 SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 GASES UNDER PRESSURE Liq. Gas PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing mist or spray. Wash thoroughly after handling. Use only outdoors or in a well- ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Protect from sunlight. Store in a well-ventilated place. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 2 of 6 Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Reinforcing filler Proprietary 10 - 30 Oximino silane Proprietary 5 - 10 Norflurane 811-97-2 5 - 10 Silica, amorphous, treated 68909-20-6 1 - 5 Butanone oxime 96-29-7 1 - 5 Aluminum 7429-90-5 0.1 - 1 Reactive Silane Proprietary 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. If adverse health effects develop seek medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, extinguishing powder, carbon dioxide. Special firefighting procedures: Wear self contained breathing apparatus. Unusual fire or explosion hazards: None expected. Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors. Oxides of silicon. Thermal oxidation may result in the formation of formaldehyde. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow material to contaminate ground water system. Clean-up methods: Wipe up using absorbent material. Keep in suitable and closed containers for disposal. IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 3 of 6 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Storage: For safe storage, store between 8 ?C (46.4 ?F) and 28 ?C (82.4 ?F) Store in original container until ready to use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Reinforcing filler 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Oximino silane None None None None Norflurane None None 1,000 ppm (4,240 mg/m3) TWA None Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust. 6 mg/m3 TWA None None Butanone oxime None None 10 ppm (36 mg/m3) TWA (Skin sensitizer) None Aluminum 1 mg/m3 TWA Respirable fraction. 5 mg/m3 PEL (as Al) Respirable dust. 15 mg/m3 PEL (as Al) Total dust. None None Reactive Silane None None None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Gray Odor: mild Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Vapor density: Not available. Flash point: > 93.00 ?C (> 199.4 ?F) Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Polymerises in presence of water. IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 4 of 6 Partition coefficient (n-octanol/water): Not available. VOC content: 3.9 %; 53.7 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of silicon. Carbon dioxide, carbon monoxide and irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. Formaldehyde. Incompatible materials: Acids. Bases. Oxidizing agents. Reactivity: Not available. Conditions to avoid: Avoid contact with water. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Harmful if inhaled. When heated to temperatures exceeding 300? F (150? C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes eye irritation. Ingestion: Not expected under normal conditions of use. May be harmful if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Reinforcing filler Oral LD50 (RAT) = 6,450 mg/kg Nuisance dust Oximino silane None Irritant, Allergen Norflurane None Cardiac, Central nervous system, Irritant, Respiratory, Skin Silica, amorphous, treated None No Target Organs Butanone oxime None Allergen, Blood, Central nervous system, Eyes, Irritant, Some evidence of carcinogenicity Aluminum None Central nervous system, Irritant, Lung Reactive Silane None Irritant, Allergen Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Reinforcing filler No No No Oximino silane No No No Norflurane No No No Silica, amorphous, treated No No No Butanone oxime No No No Aluminum No No No Reactive Silane No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Cured rubber can be incinerated or landfilled following EPA and local regulations. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Aerosols Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Aerosols, non-flammable Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: AEROSOLS Hazard class or division: 2.2 Identification number: UN 1950 Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 03/31/2015 IDH number: 756302 Product name: LOCTITE SI 5699 GY AE known as 5699 Grey RTV 190ML AE Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.