Safety Data Sheet Revision Number: 003.0 Issue date: 08/07/2014 IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy IDH number: 502908 Product type: Coating Item number: 37580 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: EXTREMELY FLAMMABLE GAS. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE GAS. 1 SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat,sparks, open flames, hot surfaces - no smoking. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Storage: Store in a well-ventilated place. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 2 of 7 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Calcium carbonate 471-34-1 10 - 30 Hydrocarbon aliphatic aromatic naphthenic C9-12 64742-88-7 10 - 30 Propane 74-98-6 5 - 10 Asphalt 8052-42-4 5 - 10 Butane 106-97-8 5 - 10 Kaolin 1332-58-7 5 - 10 Methanol 67-56-1 1 - 5 Carbon black 1333-86-4 0.1 - 1 Toluene 108-88-3 0.1 - 1 Sodium benzoate 532-32-1 0.1 - 1 Ammonium hydroxide 1336-21-6 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water spray may be ineffective. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Unusual fire or explosion hazards: Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Hazardous combustion products: Oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 3 of 7 Clean-up methods: Remove all sources of ignition. Ventilate area. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed container until ready for disposal. 7. HANDLING AND STORAGE Handling: Not available. Storage: Not available. Shelf Life Statement: Not available. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Calcium carbonate 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Hydrocarbon aliphatic aromatic naphthenic C9-12 100 ppm TWA 500 ppm (2,900 mg/m3) TWA None None Propane Included in the regulation but with no data values. See regulation for further details 1,000 ppm (1,800 mg/m3) PEL None None Asphalt 0.5 mg/m3 TWA (as benzene solubles) Inhalable fraction. None None None Butane 1,000 ppm STEL None None None Kaolin 2 mg/m3 TWA Respirable fraction. 15 mg/m3 PEL Total dust. 5 mg/m3 PEL Respirable fraction. None None Methanol 200 ppm TWA (SKIN) 250 ppm STEL 200 ppm (260 mg/m3) PEL None None Carbon black 3 mg/m3 TWA Inhalable fraction. 3.5 mg/m3 PEL None None Toluene 20 ppm TWA 200 ppm TWA 300 ppm Ceiling 500 ppm MAX. CONC 10 minutes None None Sodium benzoate None None None None Ammonium hydroxide None None None None Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Respiratory protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH for dust which may be generated from this product, underlying paint, or the abrasive. Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Chemical resistant, impermeable gloves. IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 4 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Aerosol, Liquid Color: Black Odor: Solvent Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: > -18 - 201 ?C (> 0.4 - 393.8 ?F) Melting point/ range: Not available. Specific gravity: 0.98 Vapor density: Heavier than air. Flash point: < 0 ?C (< 32?F) ; (value for propellant). Flashback: This product exhibits flashback when tested for flame extension. Flame projection: 76 cm (29.92 inch) Flammable/Explosive limits - lower: 1 % Flammable/Explosive limits - upper: 36.5 % Autoignition temperature: Not available. Evaporation rate: Faster than ether., (Ether = 1) Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. VOC content: 28.47 % Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: None Incompatible materials: None Reactivity: Not available. Conditions to avoid: None known 11. TOXICOLOGICAL INFORMATION Product toxicity data: Some animal studies with poor controls have indicated that Bitumens (Asphalt) causes tumors, however, there is inadequate evidence that Bitumens alone is carcinogenic to humans., Prolonged overexposure to solvent ingredients in section 2 may cause adverse effects to the liver, urinary, and reproductive systems., Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 5 of 7 Potential Health Effects/Symptoms Inhalation: Drowsiness. Dizziness. Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritation. Ingestion: Not available. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Calcium carbonate Oral LD50 (RAT) = 6,450 mg/kg Nuisance dust Hydrocarbon aliphatic aromatic naphthenic C9-12 None Central nervous system, Irritant Propane Inhalation LC50 (RAT, 15 min) = > 1,442.847 mg/l Inhalation LC50 (RAT, 15 min) = > 1,464 mg/l Cardiac, Central nervous system, Irritant Asphalt None Central nervous system, Irritant, Respiratory Butane Inhalation LC50 (RAT, 4 h) = 658 mg/l Cardiac, Central nervous system, Irritant Kaolin Oral LD50 (RAT) = > 5,000 mg/kg Dermal LD50 (RAT) = > 5,000 mg/kg Nuisance dust Methanol Oral LD50 (RAT) = 5,628 mg/kg Oral LD50 (RABBIT) = 14.4 g/kg Dermal LD50 (RABBIT) = 15,800 mg/kg Inhalation LC50 (RAT, 6 h) = 87.5 mg/l Inhalation LC50 (RAT, 4 h) = 64000 ppm Eyes, Heart, Irritant, Kidney, Liver, Metabolic, Nervous System, Reproductive Carbon black Oral LD50 (RAT) = > 8,000 mg/kg Respiratory, Some evidence of carcinogenicity Toluene Oral LD50 (RAT) = 2.6 g/kg Oral LD50 (RAT) = 5,000 mg/kg Dermal LD50 (RABBIT) = 12,124 mg/kg Inhalation LC50 (RAT, 1 h) = 26700 ppm Inhalation LC50 (RAT, 2 h) = 12200 ppm Inhalation LC50 (RAT, 4 h) = 8000 ppm Behavioral, Cardiac, Central nervous system, Developmental, Ear, Irritant Sodium benzoate None Metabolic Ammonium hydroxide Oral LD50 (RAT) = 350 mg/kg Irritant, Corrosive Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Calcium carbonate No No No Hydrocarbon aliphatic aromatic naphthenic C9-12 No No No Propane No No No Asphalt No Group 2B No Butane No No No Kaolin No No No Methanol No No No Carbon black No Group 2B No Toluene No No No Sodium benzoate No No No Ammonium hydroxide No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: AEROSOLS Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Sudden Release, Fire CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Methanol (CAS# 67-56-1). CERCLA Reportable quantity: Butane (CAS# 106-97-8) 100 lbs. (45.4 kg) Propane (CAS# 74-98-6) 100 lbs. (45.4 kg) Asphalt (CAS# 8052-42-4) 100 lbs. (45.4 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. IDH number: 502908 Product name: LOCTITE SF 7607 AE known as Rubberized Undercoating Heavy Page 7 of 7 Prepared by: Lou Fabrizio, Regulatory Affairs Specialist Issue date: 08/07/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.