Safety Data Sheet Revision Number: 003.0 Issue date: 08/28/2014 IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform IDH number: 491982 Product type: Silicone Item number: 37464 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HARMFUL IF INHALED. HAZARD CLASS HAZARD CATEGORY ACUTE TOXICITY INHALATION 4 EYE IRRITATION 2A SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Use only outdoors or in a well- ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Wash contaminated clothing before reuse. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 2 of 7 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Calcium carbonate 471-34-1 10 - 30 Garnet-group minerals 12178-41-5 10 - 30 Butan-2-one O,O',O''- (vinylsilylidyne)trioxime 2224-33-1 5 - 10 Octadecanoic acid 57-11-4 0.1 - 1 Aluminum 7429-90-5 0.1 - 1 Butan-2-one O,O',O'',O'''- silanetetrayltetraoxime 34206-40-1 0.1 - 1 Butanone oxime 96-29-7 1 - 5 White mineral oil (petroleum), highly refined 8042-47-5 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air in case of accidental inhalation of vapours or decomposition products. If symptoms develop and persist, get medical attention. Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. In case of adverse health effects seek medical advice. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self contained breathing apparatus. Prevent inhalation of fumes and gases. Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. Oxides of silicon. Formaldehyde. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow material to contaminate ground water system. Clean-up methods: Scrape up as much material as possible. Maintain good ventilation for large spills. Place scrap material in a well ventilated area and allow to cure to rubber. IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 3 of 7 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Storage: For safe storage, store between 0 ?C (32?F) and 32 ?C (89.6 ?F) Keep container closed. Store in a dry area below 90? F. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Calcium carbonate 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Garnet-group minerals None None None None Butan-2-one O,O',O''- (vinylsilylidyne)trioxime None None None None Octadecanoic acid 10 mg/m3 TWA None None None Aluminum 1 mg/m3 TWA Respirable fraction. 5 mg/m3 PEL (as Al) Respirable dust. 15 mg/m3 PEL (as Al) Total dust. None None Butan-2-one O,O',O'',O'''- silanetetrayltetraoxime None None None None Butanone oxime None None 10 ppm (36 mg/m3) TWA (Skin sensitizer) None White mineral oil (petroleum), highly refined 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 TWA mist 5 mg/m3 PEL Mist. None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. Eye/face protection: Safety goggles or safety glasses with side shields. Safety showers and eye wash stations should be available. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Nitrile gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Gray Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg Boiling point/range: > 200 ?C (> 392?F) no method Melting point/ range: Not available. Specific gravity: 1.5 at 20 ?C (68?F) Vapor density: Heavier than air. Flash point: > 93 ?C (> 199.4 ?F) Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 4 of 7 Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Polymerises in presence of water. Partition coefficient (n-octanol/water): Not available. VOC content: 3.31 %; 49.65 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: None under normal processing. Hazardous decomposition products: Oxides of silicon. Oxides of carbon. Methyl ethyl ketoxime formed during cure. Formaldehyde. Irritating fumes. Incompatible materials: Acids and bases. Oxidizing agents. Polymerizes on contact with water. Reactivity: Not available. Conditions to avoid: Avoid contact with acids and oxidizing agents. High temperatures. Moisture. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 5 of 7 Potential Health Effects/Symptoms Inhalation: When heated to temperatures exceeding 300? F (150? C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. The silane is a skin and eye irritant and prolonged contact may cause eye and skin burns. The low concentration makes such overexposure unlikely and minimizes its affect on health and safety. Harmful if inhaled. Skin contact: May cause allergic skin reaction. May cause skin irritation. Eye contact: Causes serious eye irritation. Ingestion: Not expected under normal conditions of use. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Calcium carbonate Oral LD50 (RAT) = 6,450 mg/kg Nuisance dust Garnet-group minerals None No Records Butan-2-one O,O',O''- (vinylsilylidyne)trioxime None Irritant, Allergen Octadecanoic acid Oral LD50 (RAT) = 4.6 g/kg Irritant Aluminum None Central nervous system, Irritant, Lung Butan-2-one O,O',O'',O'''- silanetetrayltetraoxime None Irritant, Allergen Butanone oxime None Allergen, Blood, Central nervous system, Eyes, Irritant, Some evidence of carcinogenicity White mineral oil (petroleum), highly refined None Irritant Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Calcium carbonate No No No Garnet-group minerals No No No Butan-2-one O,O',O''- (vinylsilylidyne)trioxime No No No Octadecanoic acid No No No Aluminum No No No Butan-2-one O,O',O'',O'''- silanetetrayltetraoxime No No No Butanone oxime No No No White mineral oil (petroleum), highly refined No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Cured rubber can be incinerated or landfilled following EPA and local regulations. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Exceptions: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist Issue date: 08/28/2014 IDH number: 491982 Product name: LOCTITE SI 5699 RTV SILICONE CINZA known as RTV 5699(TM) Grey High Perform Page 7 of 7 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (?Henkel?) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user?s responsibility to determine the suitability of Henkel?s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel?s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel?s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.