Page: 1 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 1 / 14 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL Product Information 1-800-TEAMVAL SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : Causes serious eye irritation. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Other hazards Page: 2 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 2 / 14 None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 Skin Irrit. 2; H315 Eye Dam. 1; H318 2.50 MOLYBDENUM DISULFIDE 1317-33-5 Not a hazardous substance or mixture. 2.50 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If on skin, rinse well with water. First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Causes serious eye irritation. Page: 3 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 3 / 14 Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Oxides of phosphorus Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Page: 4 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 4 / 14 Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis MOLYBDENUM DISULFIDE 1317-33-5 TWA 15 mg/m3 total dust (Molybdenum) OSHA Z-1 TWA 10 mg/m3 Inhalable fraction (Molybdenum) ACGIH TWA 3 mg/m3 Respirable fraction (Molybdenum) ACGIH TWA 10 mg/m3 Total dust (Molybdenum) OSHA P0 PEL 10 mg/m3 CAL PEL Page: 5 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 5 / 14 Total dust (Molybdenum) PEL 3 mg/m3 respirable dust fraction (Molybdenum) CAL PEL Hazardous components without workplace control parameters Components CAS-No. Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection : Wear as appropriate: Impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. Page: 6 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 6 / 14 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : paste Physical state : liquid Colour : dark grey Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : 500 ?F / 260 ?C Boiling point/boiling range : 700 ?F / 371 ?C Flash point : 419 ?F / 215 ?C Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : No data available Density : 0.919 g/cm3 (20 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Page: 7 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 7 / 14 Auto-ignition temperature : > 315 ?C Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : > 20.5 mm2/s (40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. None known. Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : LD50 (Rat): 93,458 mg/kg Method: Acute toxicity estimate Acute dermal toxicity : LD50 (Rabbit): 2,599 mg/kg Method: Acute toxicity estimate Page: 8 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 8 / 14 Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Acute oral toxicity : LD50 (Rat): > 2,000 - 5,000 mg/kg Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Remarks: Information given is based on data obtained from similar substances. MOLYBDENUM DISULFIDE: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 2.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Remarks: May cause skin irritation in susceptible persons. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Result: Irritating to skin. MOLYBDENUM DISULFIDE: Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes serious eye irritation. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Result: Corrosive MOLYBDENUM DISULFIDE: Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Page: 9 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 9 / 14 Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Acute aquatic toxicity Category 3; Harmful to aquatic life. Chronic aquatic toxicity : Chronic aquatic toxicity Category 3; Harmful to aquatic life with long lasting effects. Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Toxicity to fish : LC50 (Fish): > 1 - 10 mg/l Exposure time: 96 h Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other : EC50 (Aquatic invertebrates): > 10 - 100 mg/l Page: 10 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 10 / 14 aquatic invertebrates Exposure time: 48 h Remarks: Information given is based on data obtained from similar substances. Toxicity to algae : EC50 (Green algae): > 10 - 100 mg/l Exposure time: 72 h Remarks: Information given is based on data obtained from similar substances. Persistence and degradability Components: Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts: Biodegradability : Biodegradation: 1.5 % Exposure time: 28 d Method: OECD Test Guideline 301B No data available Bioaccumulative potential Components: No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Page: 11 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 11 / 14 SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods Page: 12 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 12 / 14 *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : On the inventory, or in compliance with the inventory DSL : This product contains the following components that are not on the Canadian DSL nor NDSL. AICS : Not in compliance with the inventory ENCS : Not in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory KECI : Not in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) Page: 13 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 13 / 14 SECTION 16. OTHER INFORMATION Further information Revision Date: 05/22/2017 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H315 Causes skin irritation. H318 Causes serious eye damage. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 14 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 10/30/2018 SDS Number: R0257033 Valvoline? Full Synthetic Moly Fortified Gray Grease ? Trademark, Valvoline or its subsidiaries, registered in various countries VV985 Version: 1.2 14 / 14 FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System