Page: 1 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 1 / 13 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries Relevant identified uses of the substance or mixture and uses advised against Recommended use : lubricant Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). GHS label elements This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical name CAS-No. Classification Concentration (%) Page: 2 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 2 / 13 Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Asp. Tox. 1; H304 >=20.00 - < 30.00 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). >=5.00 - < 10.00 SECTION 4. FIRST AID MEASURES General advice : No hazards which require special first aid measures. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. In case of eye contact : Remove contact lenses. Protect unharmed eye. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: acne Page: 3 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 3 / 13 stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. Page: 4 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 4 / 13 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Materials to avoid : No materials to be especially mentioned. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable fraction ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable fraction ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Engineering measures : General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Page: 5 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 5 / 13 Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: Safety shoes Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : General industrial hygiene practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : amber Odour : mild Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : > 424 ?F / 218 ?C (1013 hPa) Flash point : > 390 ?F / > 199 ?C Method: Pensky-Martens closed cup Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : 6 %(V) Calculated Explosive Limit Lower explosion limit : 1 %(V) Calculated Explosive Limit Vapour pressure : 1.3333333 hPa (20 ?C) Calculated Vapor Pressure Page: 6 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 6 / 13 Relative vapour density : No data available Relative density : No data available Density : 0.8520 g/cm3 (15.56 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : ca. 115 mm2/s (40 ?C) Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide Hydrocarbons SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Page: 7 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 7 / 13 Ingestion Acute toxicity Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg Skin corrosion/irritation Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Result: Slight, transient irritation DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result: Slight, transient irritation Serious eye damage/eye irritation Not classified based on available information. Product: Result: No eye irritation Remarks: Expected based on components. Remarks: Unlikely to cause eye irritation or injury. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Result: No eye irritation DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Page: 8 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 8 / 13 Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: May be fatal if swallowed and enters airways. DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: No aspiration toxicity classification Further information Product: Remarks: No data available Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity : Not classified based on available information. Chronic aquatic toxicity : Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Page: 9 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 9 / 13 Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l Persistence and degradability Components: No data available Bioaccumulative potential Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Partition coefficient: n- octanol/water : log Pow: Expected > 7 No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS Page: 10 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 10 / 13 Disposal methods General advice : Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Page: 11 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 11 / 13 Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : Not in compliance with the inventory TSCA : On the inventory, or in compliance with the inventory Page: 12 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 12 / 13 Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 05/22/2018 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H304 May be fatal if swallowed and enters airways. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). Flammability H e a lt h In s ta b ility 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 13 SAFETY DATA SHEET Revision Date: 05/22/2018 Print Date: 10/29/2018 SDS Number: R0338135 Valvoline? Full Synthetic Advanced MST SAE 5W-40 Motor Oil ? Trademark, Valvoline or its subsidiaries, registered in various countries VV966 Version: 1.6 13 / 13 List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System