MATERIAL SAFETY DATA SHEET 7309 01 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------- PRODUCT NUMBER HMIS CODES Health 2* 7309 Flammability 3 Reactivity 0 PRODUCT NAME KRYLON? CONTRACTOR Solvent Based Marking Paint, Fluorescent Safety Red MANUFACTURER'S NAME Medical Emergency Phone No. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 KRYLON Products Group Transportation Emergency Cleveland, OH 44115 (800) 424-9300 DATE OF PREPARATION Regulatory Information 15-AUG-07 (800) 832-2541 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------- 14 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 9 110-54-3 Hexane ACGIH TLV 50 ppm 127 mm OSHA PEL 50 ppm 4 107-83-5 Isohexane Isomers ACGIH TLV Not Available 211 mm OSHA PEL Not Available 2 96-14-0 3-Methylpentane ACGIH TLV 500 ppm 211 mm OSHA PEL Not Available 1 79-29-8 2,3-Dimethylbutane ACGIH TLV Not Available 230 mm OSHA PEL Not Available 6 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 2 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 10 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 17 14808-60-7 Quartz ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust Continued on page 2 7309 page 2 =========================================================================== 6 7727-43-7 Barium Sulfate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------- ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------- EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------- FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Continued on page 3 7309 page 3 =========================================================================== SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------- STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. Continued on page 4 7309 page 4 =========================================================================== RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------- PRODUCT WEIGHT 6.93 lb/gal 830 g/l SPECIFIC GRAVITY 0.83 BOILING POINT <0 - 325 F <-18 - 162 C MELTING POINT Not Available VOLATILE VOLUME 84 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 53.63% Less Water and Federally Exempt Solvents =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------- STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 7309 page 5 =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------- CHRONIC HEALTH HAZARDS Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. --------------------------------------------------------------------------- TOXICOLOGY DATA CAS No. Ingredient Name --------------------------------------------------------------------------- 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 Isohexane Isomers LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 3-Methylpentane LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 2,3-Dimethylbutane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 7727-43-7 Barium Sulfate LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 6 7309 page 6 =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------- ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------- WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------- US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------- SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------- 110-54-3 Hexane 9 108-88-3 Toluene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------- This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. Continued on page 7 7309 page 7 =========================================================================== The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.