3M? Quick Fix Adhesive PN 08224 (Kit) 09/04/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-9548-4 Version Number: 3.00 Issue Date: 09/04/15 Supercedes Date: 01/28/14 Product identifier 3M? Quick Fix Adhesive PN 08224 (Kit) ID Number(s): 60-9800-2981-7 Recommended use Automotive, Adhesive and Accelerator for Bonding Metal and Plastic on Vehicles Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 07-9498-2, 07-7526-2 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Quick Fix Adhesive PN 08224 (Kit) 09/04/15 ________________________________________________________________________________________________________ Page 2 of 2 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-9498-2 Version Number: 6.02 Issue Date: 06/01/18 Supercedes Date: 05/24/18 SECTION 1: Identification 1.1. Product identifier 3M? Quick Fix Adhesive PN 08224 (Accelerator) Product Identification Numbers LB-K100-0118-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Accelerator for Quick Fix Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Skin Corrosion/Irritation: Category 2. Carcinogenicity: Category 1B. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 2 of 10 Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes skin irritation. May cause drowsiness or dizziness. May cause cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 3 of 10 Hydrotreated Light Naphtha (Petroleum) 64742-49-0 80 - 100 Trade Secret * N,N-Dimethyl-P-Toluidine 99-97-8 0.1 - 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 4 of 10 Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments N,N-Dimethyl-P-Toluidine 99-97-8 AIHA TWA:0.5 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 5 of 10 Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Sharp Solvent Odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 208 ?F Flash Point -4 ?C [Test Method:Tagliabue Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.1 % Flammable Limits(UEL) 7 % Vapor Pressure 40 mmHg [Details:CONDITIONS: @ 68 F] Vapor Density 3.1 Vapor Density Negligible Density 0.684 g/ml Specific Gravity 0.684 [Ref Std:WATER=1] [Details:CONDITIONS: @ 77 F] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity <=100 centipoise [@ 73.4 ?F ] [Details:MITS data] Hazardous Air Pollutants 0 % weight [Test Method:Calculated] 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 6 of 10 Volatile Organic Compounds 690 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 100.0 % weight [Test Method:calculated per CARB title 2] Percent volatile 100 % volume VOC Less H2O & Exempt Solvents 690 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 7 of 10 Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation N,N-Dimethyl-P-Toluidine 99-97-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE >12.5 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Hydrotreated Light Naphtha (Petroleum) Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Naphtha (Petroleum) Inhalation- Vapor (4 hours) Rat LC50 > 14.7 mg/l Hydrotreated Light Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg N,N-Dimethyl-P-Toluidine Dermal Rabbit LD50 > 2,000 mg/kg N,N-Dimethyl-P-Toluidine Inhalation- Dust/Mist (4 hours) Rat LC50 1.4 mg/l N,N-Dimethyl-P-Toluidine Ingestion Rat LD50 1,650 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Hydrotreated Light Naphtha (Petroleum) Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Hydrotreated Light Naphtha (Petroleum) Rabbit Mild irritant Skin Sensitization Name Species Value Hydrotreated Light Naphtha (Petroleum) Guinea pig Not classified Respiratory Sensitization 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 8 of 10 For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Hydrotreated Light Naphtha (Petroleum) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Hydrotreated Light Naphtha (Petroleum) Inhalation Mouse Some positive data exist, but the data are not sufficient for classification N,N-Dimethyl-P-Toluidine Ingestion Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Light Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Naphtha (Petroleum) Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Specific Target Organ Toxicity - repeated exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Aspiration Hazard Name Value Hydrotreated Light Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 9 of 10 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing N,N-Dimethyl-P-Toluidine 99-97-8 Carcinogen 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None 3M? Quick Fix Adhesive PN 08224 (Accelerator) 06/01/18 __________________________________________________________________________________________ Page 10 of 10 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-9498-2 Version Number: 6.02 Issue Date: 06/01/18 Supercedes Date: 05/24/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 1 of 9 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7526-2 Version Number: 4.03 Issue Date: 07/30/18 Supercedes Date: 05/31/18 SECTION 1: Identification 1.1. Product identifier 3M? Quick Fix Adhesive PN 08224 (Adhesive) Product Identification Numbers LB-K100-0122-6 1.2. Recommended use and restrictions on use Recommended use Adhesive, Adhesive for Bonding Metal and Plastic on Vehicles 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 4. Serious Eye Damage/Irritation: Category 2A. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Warning Symbols Exclamation mark | 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 2 of 9 Pictograms Hazard Statements Combustible liquid. Causes serious eye irritation. May cause respiratory irritation. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Supplemental Information: May bond tissue rapidly. Contact through clothing may cause thermal burns. Avoid eye and skin contact. If eyelids are bonded, do not force open. In case of skin bonding, quickly soak in warm water and avoid excessive force to free bonded area. 14% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Ethyl Cyanoacrylate 7085-85-0 80 - 100 Trade Secret * Acrylic Polymer Trade Secret* 5 - 15 Trade Secret * 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 3 of 9 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If unable to free bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. DO NOT force eyelids open. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 4 of 9 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethyl Cyanoacrylate 7085-85-0 ACGIH TWA:0.2 ppm;STEL:1 ppm Dermal/Respiratory Sensitizer ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 5 of 9 results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Do not wear cotton gloves. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Colorless Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=212 ?F Flash Point >=176 ?F [Test Method:Closed Cup] Evaporation rate Not Applicable Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 0.2 mmHg [Details:CONDITIONS: @ 75 F] Vapor Density No Data Available Density 1.0 - 1.2 g/ml Specific Gravity 1.0 - 1.2 [Ref Std:WATER=1] Solubility in Water Nil [Details:Polymerized by Water] Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 500 - 700 centipoise Hazardous Air Pollutants 0.0133 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 1092 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 91 % weight [Test Method:calculated per CARB title 2] Percent volatile 91 % weight VOC Less H2O & Exempt Solvents 1092 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 6 of 9 Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization may occur. 10.4. Conditions to avoid Not determined 10.5. Incompatible materials Strong bases Amines 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Nitrogen Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Bonds skin rapidly. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Contact through clothing may cause thermal burns. Eye Contact: Bonds eyelids rapidly. Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 7 of 9 Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Ethyl Cyanoacrylate Dermal Rabbit LD50 > 2,000 mg/kg Ethyl Cyanoacrylate Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Ethyl Cyanoacrylate Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Ethyl Cyanoacrylate Rabbit Severe irritant Skin Sensitization Name Species Value Ethyl Cyanoacrylate Human Not classified Respiratory Sensitization Name Species Value Ethyl Cyanoacrylate Human Not classified Germ Cell Mutagenicity Name Route Value Ethyl Cyanoacrylate In Vitro Not mutagenic Carcinogenicity For the component/components, either no data are currently available or the data are not sufficient for classification. Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethyl Cyanoacrylate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available occupational exposure Specific Target Organ Toxicity - repeated exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 8 of 9 Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations 3M? Quick Fix Adhesive PN 08224 (Adhesive) 07/30/18 __________________________________________________________________________________________ Page 9 of 9 Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-7526-2 Version Number: 4.03 Issue Date: 07/30/18 Supercedes Date: 05/31/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com