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3M? Universal Adhesive - Clear, P.N. 08216 (6 oz.); P.N. 08217 (200 mL) 08/16/16 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7735-9 Version Number: 6.00 Issue Date: 08/16/16 Supercedes Date: 05/01/15 Product identifier 3M? Universal Adhesive - Clear, P.N. 08216 (6 oz.); P.N. 08217 (200 mL) ID Number(s): 41-0003-6660-3, 41-0003-8023-2, 41-3701-2160-4, 60-9800-2974-2 Recommended use Automotive, Structural Adhesive Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 07-7733-4, 07-7734-2 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Universal Adhesive - Clear, P.N. 08216 (6 oz.); P.N. 08217 (200 mL) 08/16/16 ________________________________________________________________________________________________________ Page 2 of 2 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 1 of 9 Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7734-2 Version Number: 7.01 Issue Date: 12/27/17 Supercedes Date: 04/22/15 SECTION 1: Identification 1.1. Product identifier 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 Product Identification Numbers LB-K100-0028-2 1.2. Recommended use and restrictions on use Recommended use Automotive, Use with Part A, MSDS 07-7733-4 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols Exclamation mark | 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 2 of 9 Pictograms Hazard Statements Causes eye irritation. May cause an allergic skin reaction. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Bisphenol A-Epichlorohydrin Copolymer 25068-38-6 95 - 100 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 3 of 9 Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from strong bases. Store away from oxidizing agents. 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 4 of 9 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS. 8.2. Exposure controls 8.2.1. Engineering controls Use in a well-ventilated area. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or machining. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Medium Syrup Odor, Color, Grade: Clear viscous liquid Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point > 260 ?C Flash Point 251 ?C [Test Method:Pensky-Martens Closed Cup] Evaporation rate No Data Available 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 5 of 9 Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure 0.03 mmHg [@ 76 ?C] Vapor Density No Data Available Density 1.17 g/ml Specific Gravity 1.17 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 10,000 - 30,000 centipoise Hazardous Air Pollutants 0 % weight [Test Method:Calculated] Volatile Organic Compounds 1 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method:calculated per CARB title 2] Percent volatile 0 % weight VOC Less H2O & Exempt Solvents 1 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong oxidizing agents Strong acids Strong bases Can react vigorously with strong Lewis or mineral acids.; Reaction with some curing agents may produce considerable heat and possible violent decomposition. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 6 of 9 present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Bisphenol A-Epichlorohydrin Copolymer Dermal Rat LD50 > 1,600 mg/kg Bisphenol A-Epichlorohydrin Copolymer Ingestion Rat LD50 > 1,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Bisphenol A-Epichlorohydrin Copolymer Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Bisphenol A-Epichlorohydrin Copolymer Rabbit Moderate irritant Skin Sensitization Name Species Value Bisphenol A-Epichlorohydrin Copolymer Human and animal Sensitizing Respiratory Sensitization Name Species Value Bisphenol A-Epichlorohydrin Copolymer Human Not classified Germ Cell Mutagenicity Name Route Value 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 7 of 9 Bisphenol A-Epichlorohydrin Copolymer In vivo Not mutagenic Bisphenol A-Epichlorohydrin Copolymer In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Bisphenol A-Epichlorohydrin Copolymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Bisphenol A-Epichlorohydrin Copolymer Ingestion Not classified for female reproduction Rat NOAEL 750 mg/kg/day 2 generation Bisphenol A-Epichlorohydrin Copolymer Ingestion Not classified for male reproduction Rat NOAEL 750 mg/kg/day 2 generation Bisphenol A-Epichlorohydrin Copolymer Dermal Not classified for development Rabbit NOAEL 300 mg/kg/day during organogenesi s Bisphenol A-Epichlorohydrin Copolymer Ingestion Not classified for development Rat NOAEL 750 mg/kg/day 2 generation Target Organ(s) Specific Target Organ Toxicity - single exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Bisphenol A- Epichlorohydrin Copolymer Dermal liver Not classified Rat NOAEL 1,000 mg/kg/day 2 years Bisphenol A- Epichlorohydrin Copolymer Dermal nervous system Not classified Rat NOAEL 1,000 mg/kg/day 13 weeks Bisphenol A- Epichlorohydrin Copolymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 28 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 8 of 9 Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Serious eye damage or eye irritation 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None 3M? Universal Adhesive - Clear/Part B, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 9 of 9 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-7734-2 Version Number: 7.01 Issue Date: 12/27/17 Supercedes Date: 04/22/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 1 of 9 Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7733-4 Version Number: 5.01 Issue Date: 12/27/17 Supercedes Date: 08/16/16 SECTION 1: Identification 1.1. Product identifier 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 Product Identification Numbers LB-K100-0028-1 1.2. Recommended use and restrictions on use Recommended use Automotive, Use with Part B, MSDS 07-7734-2 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 1C. 2.2. Label elements Signal word Danger Symbols Corrosion | 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 2 of 9 Pictograms Hazard Statements Causes severe skin burns and eye damage. Precautionary Statements General: Keep out of reach of children. Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves, protective clothing, and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Trade Secret* 60 - 100 Trade Secret * Bis[(Dimethylamino)Methyl]Phenol 71074-89-0 0.5 - 1.5 Trade Secret * Tris(2,4,6-Dimethylaminomonomethyl)Phenol 90-72-2 5 - 10 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 3 of 9 Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Sulfur During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Observe precautions from other sections. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 4 of 9 on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS. 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece air-purifying respirator suitable for organic vapors and particulates 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 5 of 9 For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Medium Syrup Odor, Color, Grade: Dark amber, pungent odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point No flash point Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure No Data Available Vapor Density No Data Available Density 1.1 g/ml Specific Gravity 1.1 [Ref Std:WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 8,000 - 15,000 centipoise Hazardous Air Pollutants 0 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 0 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method:calculated per CARB title 2] Percent volatile 00 % weight VOC Less H2O & Exempt Solvents 0 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 6 of 9 Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: May be harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Dermal Rabbit LD50 > 10,200 mg/kg Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Ingestion Rat LD50 2,600 mg/kg Tris(2,4,6-Dimethylaminomonomethyl)Phenol Dermal Rat LD50 1,280 mg/kg Tris(2,4,6-Dimethylaminomonomethyl)Phenol Ingestion Rat LD50 1,000 mg/kg Bis[(Dimethylamino)Methyl]Phenol Ingestion LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Rabbit No significant irritation 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 7 of 9 Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive Bis[(Dimethylamino)Methyl]Phenol similar compoun ds Corrosive Serious Eye Damage/Irritation Name Species Value Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Rabbit Mild irritant Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive Bis[(Dimethylamino)Methyl]Phenol similar compoun ds Corrosive Skin Sensitization Name Species Value Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Mouse Sensitizing Tris(2,4,6-Dimethylaminomonomethyl)Phenol Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 In Vitro Not mutagenic Tris(2,4,6-Dimethylaminomonomethyl)Phenol In Vitro Not mutagenic Carcinogenicity For the component/components, either no data are currently available or the data are not sufficient for classification. Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Tris(2,4,6- Dimethylaminomonomethy l)Phenol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 75 mg/kg/day 90 days Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg/day 90 days Mercaptan-Terminated Epoxy Curing Agent NJTS 800938-5952 Ingestion endocrine system | heart | skin | immune system | nervous system | eyes | kidney and/or bladder | respiratory Not classified Rat NOAEL 1,000 mg/kg/day 90 days 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 8 of 9 system | vascular system Tris(2,4,6- Dimethylaminomonomethy l)Phenol Dermal skin | liver | nervous system | auditory system | hematopoietic system | eyes Not classified Rat NOAEL 125 mg/kg/day 28 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards 3M? Universal Adhesive - Clear/Part A, P.N. 08216, 08217 12/27/17 __________________________________________________________________________________________ Page 9 of 9 Hazard Not Otherwise Classified (HNOC) Serious eye damage or eye irritation Skin Corrosion or Irritation 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 0 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-7733-4 Version Number: 5.01 Issue Date: 12/27/17 Supercedes Date: 08/16/16 Reason for Reissue Conversion to GHS format SDS. DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com