3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) 1/15/2009 7:34:15 AM Material Safety Data Sheet Purchase Order #: 739072 Customer Number: MCA0363 MSDS COORDINATOR REPLENEX INC 9815 W 74TH ST EDEN PRAIRIE, MN 55344-3522 United States of America Dear MSDS COORDINATOR Enclosed is the Material Safety Data Sheet (MSDS) for the product that your company recently purchased from 3M Please forward the attached MSDS to the individual in your organization responsible for implementing these regulations. If you are a distributor and resell this product, OSHA and EPA require that you transmit this MSDS information to your customers at the time of first shipment or whenever you receive revised MSDSs from 3M. 3M MSDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a CD-ROM of 3M MSDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M MSDSs by e-mail and would like to do so, please contact our eMSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 1 of 9 Material Safety Data Sheet Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 07/17/2007 Supercedes Date: 11/19/2004 Document Group: 09-2672-5 Product Use: Intended Use: Automotive Specific Use: Rubbing Compound for Automotive Paints SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 15 - 40 STODDARD SOLVENT 8052-41-3 15 - 40 ALUMINUM OXIDE 1344-28-1 10 - 30 POLYETHYLENE GLYCOL SORBITAN MONOOLEATE 9005-65-6 3 - 7 WHITE MINERAL OIL (PETROLEUM) 8042-47-5 1 - 5 1,2,4-TRIMETHYLBENZENE 95-63-6 0.5 - 1.5 ETHYLBENZENE 100-41-4 0.1 - 0.2 NAPHTHALENE 91-20-3 < 0.07 TOLUENE 108-88-3 < 0.05 FORMALDEHYDE 50-00-0 < 0.01 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Odor, Color, Grade: Cream color; Kerosene odor General Physical Form: Liquid 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 2 of 9 Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Dust clouds of this material in combination with an ignition source may be explosive. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Contains a chemical or chemicals which can cause cancer. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. During grinding, scraping, sanding: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer FORMALDEHYDE 50-00-0 Group 1 International Agency for Research on Cancer FORMALDEHYDE 50-00-0 Anticipated human carcinogen National Toxicology Program Carcinogens FORMALDEHYDE 50-00-0 Cancer hazard OSHA Carcinogens NAPHTHALENE 91-20-3 Group 2B International Agency for Research on Cancer NAPHTHALENE 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 3 of 9 SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 135 ?F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Dust clouds of this material in combination with an ignition source may be explosive. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 4 of 9 disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid static discharge. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Keep container closed when not in use. 7.2 STORAGE Store away from acids. Store away from heat. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton), Neoprene. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 5 of 9 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ALUMINUM OXIDE ACGIH TWA, particulate matter, < 1% crystalline silica 10 mg/m3 Table A4 ALUMINUM OXIDE CMRG TWA 1 fiber/cc ALUMINUM OXIDE OSHA TWA, respirable 5 mg/m3 Table Z-1 ALUMINUM OXIDE OSHA TWA, Vacated, as dust 10 mg/m3 ALUMINUM OXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1 ETHYLBENZENE ACGIH TWA 100 ppm Table A3 ETHYLBENZENE ACGIH STEL 125 ppm Table A3 ETHYLBENZENE OSHA TWA 100 ppm Table Z-1A ETHYLBENZENE OSHA STEL 125 ppm Table Z-1A FORMALDEHYDE ACGIH CEIL 0.3 ppm Sensitizer; Table A2 FORMALDEHYDE OSHA TWA 0.5 ppm Standard Appendix NAPHTHALENE ACGIH TWA 10 ppm Skin Notation*; Table A4 NAPHTHALENE ACGIH STEL 15 ppm Skin Notation*; Table A4 NAPHTHALENE OSHA TWA 10 ppm Table Z-1A NAPHTHALENE OSHA STEL 15 ppm Table Z-1A OIL MIST, MINERAL ACGIH TWA, as mist 5 mg/m3 OIL MIST, MINERAL ACGIH STEL, as mist 10 mg/m3 OIL MIST, MINERAL OSHA TWA, as mist 5 mg/m3 Table Z-1 STODDARD SOLVENT ACGIH TWA 100 ppm STODDARD SOLVENT OSHA TWA, Vacated 100 ppm Table Z-1A STODDARD SOLVENT OSHA TWA 500 ppm Table Z-1 TOLUENE ACGIH TWA 20 ppm Table A4 TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA, Vacated 100 ppm TOLUENE OSHA STEL, Vacated 150 ppm TOLUENE OSHA TWA 200 ppm Table Z-2 TOLUENE OSHA CEIL 300 ppm Table Z-2 WHITE MINERAL OIL (PETROLEUM) CMRG TWA 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG STEL 10 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Paste Odor, Color, Grade: Cream color; Kerosene odor General Physical Form: Liquid 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 6 of 9 Autoignition temperature No Data Available Flash Point 135 ?F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point >=95 ?F Density 1.16 g/ml Vapor Density >=1 [Ref Std: AIR=1] Vapor Pressure 1.6 mmHg [Ref Std: AIR=1] Specific Gravity Approximately 1.1 Units not avail. or not appl. [Ref Std: WATER=1] pH 7.5 - 8.5 Melting point No Data Available Solubility in Water Appreciable Evaporation rate No Data Available Hazardous Air Pollutants .510 % weight Volatile Organic Compounds 3.0 lb/gal [Test Method: ASTM METHOD] [Details: SPECIFIC METHOD: D3960] Percent volatile 60 - 75 % weight VOC Less H2O & Exempt Solvents <= 32 % Viscosity 40000 - 60000 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 7 of 9 Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-9800-3592-1, 60-9800-3697-8, 60-9800-3860-2 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 1,2,4-TRIMETHYLBENZENE 95-63-6 0.5 - 1.5 ETHYLBENZENE 100-41-4 0.1 - 0.2 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status NAPHTHALENE 91-20-3 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 8 of 9 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification ETHYLBENZENE 100-41-4 **Carcinogen FORMALDEHYDE 50-00-0 **Carcinogen NAPHTHALENE 91-20-3 **Carcinogen TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product use information was modified. Copyright was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. 3M MATERIAL SAFETY DATA SHEET 3M(tm) Perfect-It(tm) III Extra Cut Rubbing Compound PN 05935, PN 05936, PN 05940 07/17/2007 _________________________________________________________________________________________________ Page 9 of 9 Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 4: First aid for skin contact - decontamination - was modified. Section 4: First aid for skin contact - medical assistance - was modified. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 3: Immediate other hazard(s) was modified. Section 2: Ingredient table was modified. Section 14: ID Number(s) was modified. Section 15: EPCRA 313 information was modified. Section 15: California proposition 65 ingredient information was modified. Section 3: Carcinogenicity table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 9: Boiling point information was modified. Sections 3 and 9: Odor, color, grade information was modified. Section 9: Property description for optional properties was modified. Section 15: TSCA section 12[b] information was modified. Section 8: Eye/face protection phrase was added. Section 4: First aid for skin contact - termination of exposure - was added. Section 4: First aid for skin contact - handling - was added. Section 15: California proposition 65 reproductive harm warning was added. Section 8: Exposure guideline note was added. 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Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com