3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-7344-5 Version Number: 14.00 Issue Date: 02/03/17 Supercedes Date: 07/06/16 SECTION 1: Identification 1.1. Product identifier 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 Product Identification Numbers ID Number UPC ID Number UPC LB-K000-1080-0 60-4100-0978-5 051131-05954-2 60-4100-0979-3 051131-05955-3 60-4100-0980-1 051131-05956-6 60-4400-9518-4 051131-39004-1 60-4550-5172-6 60-4550-5173-4 1.2. Recommended use and restrictions on use Recommended use Automotive, Painted surface defect repair 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 4. Carcinogenicity: Category 1A. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 2 of 14 Signal word Danger Symbols Exclamation mark | Health Hazard | Pictograms Hazard Statements Combustible liquid. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 3 of 14 Ingredient C.A.S. No. % by Wt Tripoli 1317-95-9 30 - 60 Trade Secret * Water 7732-18-5 10 - 30 Trade Secret * Stoddard Solvent 8052-41-3 7 - 13 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 1 - 10 Trade Secret * Oleic Acid 112-80-1 1 - 5 Trade Secret * Pine Oil 8002-09-3 1 - 5 Trade Secret * Solvent-Refined Heavy Paraffinic Petroleum Distillates 64741-88-4 1 - 5 Trade Secret * Mineral Oil 64741-89-5 < 2 Trade Secret * Polyethylene Glycol Sorbitan Monooleate 9005-65-6 0.5 - 1.5 Trade Secret * Ethylbenzene 100-41-4 0.3 Trade Secret * Naphthalene 91-20-3 < 0.1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 4 of 14 Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Tripoli 1317-95-9 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Tripoli 1317-95-9 OSHA TWA:0.05 mg/m3 Mineral oils (untreated and mildly 64741-88-4 ACGIH Limit value not established: A2: Suspected human 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 5 of 14 treated) carcin., Cntrl all exposr- low as possib MINERAL OILS, HIGHLY- REFINED OILS 64741-88-4 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Paraffin oil 64741-88-4 OSHA TWA(as mist):5 mg/m3 PETROLEUM DISTILLATES 64741-88-4 OSHA TWA:2000 mg/m3(500 ppm) Mineral oils (untreated and mildly treated) 64741-89-5 ACGIH Limit value not established: A2: Suspected human carcin., Cntrl all exposr- low as possib MINERAL OILS, HIGHLY- REFINED OILS 64741-89-5 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Paraffin oil 64741-89-5 OSHA TWA(as mist):5 mg/m3 Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., SKIN Stoddard Solvent 8052-41-3 ACGIH TWA:100 ppm Stoddard Solvent 8052-41-3 OSHA TWA:2900 mg/m3(500 ppm) Naphthalene 91-20-3 ACGIH TWA:10 ppm A3: Confirmed animal carcin., SKIN Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 6 of 14 For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Emulsion Odor, Color, Grade: Petroleum odor, brown viscous liquid. pH 7.5 - 8.5 Melting point Not Applicable Boiling Point > 95 ?F Flash Point 160 ?F [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 1.33 g/ml Specific Gravity 1.33 [Ref Std: WATER=1] Solubility in Water Negligible Partition coefficient: n-octanol/ water No Data Available Viscosity 14,000 - 18,000 centipoise Hazardous Air Pollutants 0.002 lb HAPS/lb solids [Test Method: Calculated] Molecular weight No Data Available Volatile Organic Compounds 239 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 16.0 % weight [Test Method: calculated per CARB title 2] Percent volatile 44.2 % weight VOC Less H2O & Exempt Solvents 367 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 7 of 14 Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation SILICA, CRYS AIRRESP 1317-95-9 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer SILICA, CRYS AIRRESP 1317-95-9 Known human carcinogen National Toxicology Program Carcinogens Generic: Mineral oils (untreated and mildly treated) 64741-88-4 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Generic: Mineral oils (untreated and mildly treated) 64741-88-4 Known human carcinogen National Toxicology Program Carcinogens Generic: Mineral oils (untreated and mildly treated) 64741-89-5 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Generic: Mineral oils (untreated and mildly 64741-89-5 Known human carcinogen National Toxicology Program Carcinogens 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 8 of 14 treated) Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Tripoli Dermal LD50 estimated to be > 5,000 mg/kg Tripoli Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Stoddard Solvent Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Stoddard Solvent Dermal Rabbit LD50 > 3,000 mg/kg Stoddard Solvent Ingestion Rat LD50 > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Solvent-Refined Heavy Paraffinic Petroleum Distillates Dermal Rabbit LD50 > 2,000 mg/kg Solvent-Refined Heavy Paraffinic Petroleum Distillates Ingestion Rat LD50 > 5,000 Mineral Oil Dermal Rabbit LD50 > 5,000 mg/kg Mineral Oil Inhalation- Dust/Mist (4 hours) Rat LC50 > 4 mg/l Mineral Oil Ingestion Rat LD50 > 5,000 mg/kg Oleic Acid Dermal Guinea pig LD50 > 3,000 mg/kg Oleic Acid Ingestion Rat LD50 57,000 mg/kg Pine Oil Dermal Rabbit LD50 > 2,000 mg/kg Pine Oil Ingestion Rat LD50 > 2,000 mg/kg Polyethylene Glycol Sorbitan Monooleate Dermal LD50 estimated to be > 5,000 mg/kg Polyethylene Glycol Sorbitan Monooleate Ingestion Rat LD50 > 38,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Tripoli Professio nal judgeme nt No significant irritation Stoddard Solvent Rabbit Irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Solvent-Refined Heavy Paraffinic Petroleum Distillates Rabbit Minimal irritation Mineral Oil Rabbit Minimal irritation Oleic Acid Rabbit Minimal irritation Pine Oil Not available Irritant Ethylbenzene Rabbit Mild irritant 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 9 of 14 Naphthalene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Stoddard Solvent Rabbit No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Solvent-Refined Heavy Paraffinic Petroleum Distillates Rabbit Mild irritant Mineral Oil Rabbit No significant irritation Oleic Acid Rabbit Mild irritant Pine Oil Rabbit Severe irritant Ethylbenzene Rabbit Moderate irritant Naphthalene Rabbit No significant irritation Skin Sensitization Name Species Value Stoddard Solvent Guinea pig Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Solvent-Refined Heavy Paraffinic Petroleum Distillates Guinea pig Not sensitizing Mineral Oil Guinea pig Not sensitizing Pine Oil Guinea pig Not sensitizing Ethylbenzene Human Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Tripoli In Vitro Some positive data exist, but the data are not sufficient for classification Tripoli In vivo Some positive data exist, but the data are not sufficient for classification Stoddard Solvent In vivo Not mutagenic Stoddard Solvent In Vitro Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Solvent-Refined Heavy Paraffinic Petroleum Distillates In Vitro Some positive data exist, but the data are not sufficient for classification Mineral Oil In vivo Not mutagenic Mineral Oil In Vitro Some positive data exist, but the data are not sufficient for classification Oleic Acid In Vitro Some positive data exist, but the data are not sufficient for classification Pine Oil In Vitro Not mutagenic Pine Oil In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Tripoli Inhalation Human and animal Carcinogenic Stoddard Solvent Dermal Mouse Some positive data exist, but the data are not sufficient for classification Stoddard Solvent Inhalation Human Some positive data exist, but the data are not 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 10 of 14 and animal sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Solvent-Refined Heavy Paraffinic Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Mineral Oil Dermal Mouse Some positive data exist, but the data are not sufficient for classification Oleic Acid Dermal Mouse Not carcinogenic Oleic Acid Ingestion Rat Not carcinogenic Oleic Acid Not Specified Multiple animal species Not carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Naphthalene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Stoddard Solvent Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s Pine Oil Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 600 mg/kg/day during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 4.3 mg/l premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Stoddard Solvent Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Stoddard Solvent Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Stoddard Solvent Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Stoddard Solvent Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Notavailable Solvent-Refined Heavy Paraffinic Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 11 of 14 Solvent-Refined Heavy Paraffinic Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Pine Oil Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available Pine Oil Ingestion central nervous system depression Some positive data exist, but the data are not sufficient for classification NOAEL Not available Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Tripoli Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Stoddard Solvent Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Stoddard Solvent Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Stoddard Solvent Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Stoddard Solvent Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Stoddard Solvent Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days Solvent-Refined Heavy Paraffinic Petroleum Distillates Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.21 mg/l 28 days Mineral Oil Dermal hematopoietic system | liver | kidney and/or bladder All data are negative Rabbit NOAEL 5,000 mg/kg/day 3 weeks Oleic Acid Ingestion liver | immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,250 mg/kg/day 108 weeks Oleic Acid Ingestion hematopoietic system All data are negative Rat NOAEL 2,550 mg/kg/day 108 weeks Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 12 of 14 Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.01 mg/l 13 weeks Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Aspiration Hazard Name Value Stoddard Solvent Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Solvent-Refined Heavy Paraffinic Petroleum Distillates Aspiration hazard Mineral Oil Aspiration hazard Ethylbenzene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 13 of 14 unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Ethylbenzene 100-41-4 Trade Secret 0.3 Naphthalene 91-20-3 Trade Secret < 0.1 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Ethylbenzene 100-41-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include 3M(TM) Super Duty Rubbing Compound PN 5954 5955 5956 39004 59002 02/03/17 __________________________________________________________________________________________ Page 14 of 14 the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 19-7344-5 Version Number: 14.00 Issue Date: 02/03/17 Supercedes Date: 07/06/16 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com