Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1/15 Conforms to HazCom 2012/United States SAFETY DATA SHEET Lucas Oil Contact Cleaner ? Aerosol Section 1. Identification GHS product identifier Other means of identification : Lucas Oil Contact Cleaner ? Aerosol : Not available. Product number : Identified uses Not available. Supplier's details : Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 Toll Free: (800) 342-2512 Tel: (951) 270-0154 Fax: (951) 270-1902 Website: www.LucasOil.com Emergency telephone number (with hours of operation) : (951) 493-1149 (951) 847-5949 This email address is being protected from spambots. You need JavaScript enabled to view it. 7:00A.M. to 5:00P.M. Monday thru Friday Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 2 GHS label elements Hazard pictograms : Signal word : Danger Lucas Oil Contact Cleaner ? Aerosol Section 2. Hazards identification CAS number : Not applicable. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 2/15 Hazard statements : H222 - Extremely flammable aerosol. H280 - Contains gas under pressure; may explode if heated. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H361 - Suspected of damaging the unborn child. H371 - May cause damage to organs. H336 - May cause drowsiness and dizziness. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P281 - Use personal protective equipment as required. P280 - Wear protective gloves. Wear eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P251 - Pressurized container: Do not pierce or burn, even after use. P211 - Do not spray on an open flame or other ignition source. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P260 - Do not breathe dust or mist. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. Response : P391 - Collect spillage. P314 - Get medical attention if you feel unwell. P309 + P311 - IF exposed or if you feel unwell: Call a POISON CENTER or physician. P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. P332 + P313 - If skin irritation occurs: Get medical attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. Storage : P405 - Store locked up. P410 - Protect from sunlight. P412 - Do not expose to temperatures exceeding 50?C/122?F. P403 - Store in a well-ventilated place. Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Substance/mixture Other means of identification : Mixture : Not available. CAS number/other identifiers Lucas Oil Contact Cleaner ? Aerosol Section 3. Composition/information on ingredients Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 3/15 Product code : Ingredient name % CAS number Acetone Heptane Toluene Carbon dioxide Methanol 30 - 60 10 - 30 10 - 30 5 - 10 1 - 5 67-64-1 142-82-5 108-88-3 124-38-9 67-56-1 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. If necessary, call a poison center or physician. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. If necessary, call a poison center or physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Lucas Oil Contact Cleaner ? Aerosol Section 4. First aid measures sewer or drain. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 4/15 Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation Skin contact Ingestion : Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. : None known. Specific hazards arising from the chemical : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, Lucas Oil Contact Cleaner ? Aerosol Section 5. Fire-fighting measures Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 5/15 Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide Special protective actions for fire-fighters Special protective equipment for fire-fighters : Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Lucas Oil Contact Cleaner ? Aerosol Section 7. Handling and storage Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid breathing gas. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Remove contaminated clothing and protective equipment before entering eating areas. : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Acetone Heptane Toluene ACGIH TLV (United States, 4/2014). STEL: 1782 mg/m? 15 minutes. STEL: 750 ppm 15 minutes. TWA: 1188 mg/m? 8 hours. TWA: 500 ppm 8 hours. NIOSH REL (United States, 10/2013). TWA: 590 mg/m? 10 hours. TWA: 250 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 2400 mg/m? 8 hours. TWA: 1000 ppm 8 hours. ACGIH TLV (United States, 4/2014). STEL: 2050 mg/m? 15 minutes. STEL: 500 ppm 15 minutes. TWA: 1640 mg/m? 8 hours. TWA: 400 ppm 8 hours. NIOSH REL (United States, 10/2013). CEIL: 440 ppm 15 minutes. TWA: 350 mg/m? 10 hours. TWA: 85 ppm 10 hours. CEIL: 1800 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 2000 mg/m? 8 hours. TWA: 500 ppm 8 hours. NIOSH REL (United States, 10/2013). STEL: 560 mg/m? 15 minutes. STEL: 150 ppm 15 minutes. TWA: 375 mg/m? 10 hours. TWA: 100 ppm 10 hours. OSHA PEL Z2 (United States, 2/2013). AMP: 500 ppm 10 minutes. CEIL: 300 ppm TWA: 200 ppm 8 hours. ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 6/15 www.kmkregservices.com www.askdrluc.com www.ghssmart.com Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 7 Lucas Oil Contact Cleaner ? Aerosol Section 8. Exposure controls/personal protection Methanol OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 375 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. ACGIH TLV (United States, 4/2014). Absorbed through skin. STEL: 328 mg/m? 15 minutes. STEL: 250 ppm 15 minutes. TWA: 262 mg/m? 8 hours. TWA: 200 ppm 8 hours. NIOSH REL (United States, 10/2013). Absorbed through skin. STEL: 325 mg/m? 15 minutes. STEL: 250 ppm 15 minutes. TWA: 260 mg/m? 10 hours. TWA: 200 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 260 mg/m? 8 hours. TWA: 200 ppm 8 hours. Appropriate engineering controls Environmental exposure controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 8 Lucas Oil Contact Cleaner ? Aerosol Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point : Liquid. : Colorless. : Citrus. : Not available. : Not available. : Not available. Boiling point : Not available. Flash point Evaporation rate : Closed cup: <-17.77?C (<0.014?F) : >1 (Butyl acetate = 1) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 12.8% Vapor pressure Vapor density Relative density Solubility Partition coefficient: n- octanol/water Auto-ignition temperature : 758.4 kPa (5688.64 mm Hg) [room temperature] : >1 [Air = 1] : 0.73 to 0.75 : Not available. : Not available. : Not available. Decomposition temperature : Not available. Viscosity Volatility : Not available. : Not available. VOC content : 42 % (w/w). The product is VOC compliant. Aerosol product Type of aerosol : Spray Heat of combustion : 32.7 kJ/g Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 9 Lucas Oil Contact Cleaner ? Aerosol Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Acetone Heptane Toluene Methanol LD50 Oral LC50 Inhalation Gas. LC50 Inhalation Vapor LC50 Inhalation Vapor LD50 Oral LC50 Inhalation Gas. LC50 Inhalation Gas. LD50 Dermal LD50 Oral Rat Rat Rat Rat Rat Rat Rat Rabbit Rat 5800 mg/kg 48000 ppm 103 g/m? 49 g/m? 636 mg/kg 145000 ppm 64000 ppm 15800 mg/kg 5600 mg/kg - 4 hours 4 hours 4 hours - 1 hours 4 hours - - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Acetone Toluene Methanol Eyes - Mild irritant Eyes - Mild irritant Eyes - Moderate irritant Eyes - Severe irritant Skin - Mild irritant Skin - Mild irritant Eyes - Mild irritant Skin - Moderate irritant Eyes - Mild irritant Eyes - Severe irritant Skin - Mild irritant Skin - Mild irritant Skin - Moderate irritant Eyes - Moderate irritant Skin - Moderate irritant Eyes - Moderate irritant Human Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Pig Rabbit Rabbit Rabbit Rabbit Rabbit - - - - - - - - - - - - - - - - 186300 ppm 10 ?L 24 hours 20 mg 20 mg 24 hours 500 mg 395 mg 0.5 minutes 100 mg 24 hours 20 mg 870 ?g 24 hours 2 mg 24 hours 250 ?L 435 mg 500 mg 24 hours 100 mg 24 hours 20 mg 40 mg - - - - - - - - - - - - - - - - Sensitization There is no data available. Carcinogenicity Classification Product/ingredient name OSHA IARC NTP ACGIH EPA NIOSH Acetone Toluene Methanol - - - - 3 - - - - A4 A4 - - - - - - None. Specific target organ toxicity (single exposure) Name Category Route of exposure Target organs Acetone Heptane Toluene Methanol Category 3 Category 3 Category 3 Category 1 Not applicable. Not applicable. Not applicable. Not determined Narcotic effects Narcotic effects Narcotic effects central nervous system (CNS) and gastrointestinal tract Specific target organ toxicity (repeated exposure) Name Category Route of exposure Target organs Toluene Category 2 Not determined Not determined Aspiration hazard Potential delayed effects : No known significant effects or critical hazards. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10/15 Lucas Oil Contact Cleaner ? Aerosol Section 11. Toxicological information Name Result Heptane Toluene ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Potential acute health effects : Not available. Eye contact : Causes serious eye irritation. Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation Skin contact Ingestion : Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : No known significant effects or critical hazards. Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate effects : No known significant effects or critical hazards. Lucas Oil Contact Cleaner ? Aerosol Section 11. Toxicological information Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 11 Potential chronic health effects General : Carcinogenicity : Mutagenicity : Teratogenicity : May cause damage to organs through prolonged or repeated exposure. No known significant effects or critical hazards. No known significant effects or critical hazards. Suspected of damaging the unborn child. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route ATE value Oral Dermal Inhalation (vapors) 2200 mg/kg 6600 mg/kg 66 mg/L Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure Acetone Heptane Toluene Methanol Acute EC50 20.565 mg/L Marine water Acute LC50 6000000 ?g/L Fresh water Acute LC50 10000 ?g/L Fresh water Acute LC50 100 mg/L Fresh water Chronic NOEC 4.95 mg/L Marine water Chronic NOEC 0.016 ml/L Fresh water Chronic NOEC 0.1 ml/L Fresh water Acute LC50 375000 ?g/L Fresh water Acute EC50 433 ppm Marine water Acute EC50 12500 ?g/L Fresh water Acute EC50 11600 ?g/L Fresh water Acute EC50 6000 ?g/L Fresh water Acute LC50 5500 ?g/L Fresh water Chronic NOEC 500000 ?g/L Fresh water Chronic NOEC 1000 ?g/L Fresh water Acute EC50 16.912 mg/L Marine water Acute EC50 10000000 ?g/L Fresh water Acute LC50 2500000 ?g/L Marine water Acute LC50 100 mg/L Fresh water Chronic NOEC 9.96 mg/L Marine water Algae - Ulva pertusa Crustaceans - Gammarus pulex Daphnia - Daphnia magna Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) Algae - Ulva pertusa Crustaceans - Daphniidae Daphnia - Daphnia magna - Neonate Fish - Oreochromis mossambicus Algae - Skeletonema costatum Algae - Pseudokirchneriella subcapitata Crustaceans - Gammarus pseudolimnaeus - Adult Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) Fish - Oncorhynchus kisutch - Fry Algae - Pseudokirchneriella subcapitata Daphnia - Daphnia magna Algae - Ulva pertusa Daphnia - Daphnia magna Crustaceans - Crangon crangon - Adult Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) Algae - Ulva pertusa 96 hours 48 hours 48 hours 96 hours 96 hours 21 days 21 days 96 hours 96 hours 72 hours 48 hours 48 hours 96 hours 96 hours 21 days 96 hours 48 hours 48 hours 96 hours 96 hours Persistence and degradability There is no data available. Bioaccumulative potential Product/ingredient name LogPow BCF Potential Acetone Heptane Toluene Methanol -0.23 4.66 2.73 -0.77 - 552 90 <10 low high low low Mobility in soil Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 12 Lucas Oil Contact Cleaner ? Aerosol Section 12. Ecological information Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. United States - RCRA Toxic hazardous waste "U" List Ingredient CAS # Status Reference number Acetone Toluene 67-64-1 108-88-3 Listed Listed U002 U220 Methanol 67-56-1 Listed U154 Section 14. Transport information DOT Classification IMDG IATA UN number UN1950 UN1950 UN1950 UN proper shipping name Transport hazard class(es) Packing group AEROSOLS. Marine pollutant (Heptane) RQ (Toluene, Acetone) 2.1 - AEROSOLS. Marine pollutant (Heptane) 2.1 - AEROSOLS 2.1 - Environmental hazards Yes. Yes. No. Additional information The marine pollutant mark is not required when transported on inland waterways in sizes of ?5 L or ?5 kg or by road, rail, or inland air in non-bulk sizes. Reportable quantity 5000 lbs / 2270 kg [810.37 gal / 3067.6 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. The marine pollutant mark is not required when transported in sizes of ?5 L or ?5 kg. The environmentally hazardous substance mark may appear if required by other transportation regulations. AERG : Not available. DOT-RQ Details : Toluene 1000 lbs / 454 kg [137.86 gal / 521.84 L] Acetone 5000 lbs / 2270 kg [758.12 gal / 2869.8 L] Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 13 Lucas Oil Contact Cleaner ? Aerosol Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) PAIR: Heptane TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 307: Toluene Clean Water Act (CWA) 311: Toluene Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : Listed : Not listed : Not listed : Not listed : Listed Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Sudden release of pressure Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Acetone Heptane Toluene Methanol 30 - 60 10 - 30 10 - 30 1 - 5 Yes. Yes. Yes. Yes. No. No. No. No. No. No. No. No. Yes. Yes. Yes. Yes. No. No. Yes. No. SARA 313 Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 14 Lucas Oil Contact Cleaner ? Aerosol Section 15. Regulatory information Product name CAS number % Form R - Reporting requirements Toluene Methanol 108-88-3 67-56-1 10 - 30 1 - 5 Supplier notification Toluene Methanol 108-88-3 67-56-1 10 - 30 1 - 5 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State regulations Massachusetts : The following components are listed: Acetone; Heptane; Toluene; Carbon dioxide; Methanol New York : The following components are listed: Acetone; Toluene; Methanol New Jersey : The following components are listed: Acetone; Heptane; Toluene; Carbon dioxide; Methanol Pennsylvania : The following components are listed: Acetone; Heptane; Toluene; Carbon dioxide; Methanol California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Toluene Methanol No. No. Yes. Yes. No. No. 7000 ?g/day (ingestion) 13000 ?g/day (inhalation) 23000 ?g/day (ingestion) 47000 ?g/day (inhalation) Section 16. Other information Hazardous Material Information System (U.S.A.) Health : 2 Flammability : 4 Physical hazards : 0 Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health : 2 Flammability : 4 Instability : 0 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue mm/dd/yyyy : 01/15/2015 Version : Prepared by : 1 KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 15 Section 16. Other information Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor Lucas Oil Contact Cleaner ? Aerosol Notice to reader GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.