Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1 Conforms to HazCom 2012/United States SAFETY DATA SHEET Lucas Red ?N? Tacky NLGI # 2 grease Section 1. Identification GHS product identifier Other means of identification : Lucas Red ?N? Tacky NLGI # 2 grease : Not available. Product number : 10005, 10027, 10028, 10029, 10574 Relevant identified uses of the substance or mixture and uses advised against Engine oil. Supplier's details : Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 Toll Free: (800) 342-2512 Tel: (951) 270-0154 Fax: (951) 270-1902 Website: www.LucasOil.com Emergency telephone number (with hours of operation) : (951) 493-1149 (951) 847-5949 This email address is being protected from spambots. You need JavaScript enabled to view it. 7:00A.M. to 5:00P.M. Monday thru Friday Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 3 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Causes serious eye damage. Harmful to aquatic life with long lasting effects. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear eye or face protection. Avoid release to the environment. Wash hands thoroughly after handling. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 2 Lucas Red ?N? Tacky NLGI # 2 grease Section 2. Hazards identification Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of identification : Not available. CAS number/other identifiers CAS number : Not applicable. Product code : Not available. Ingredient name % CAS number Zinc Alkyldithiophosphate 1 - 5 68649-42-3 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Get medical attention immediately. Call a poison center or physician. Wash contaminated skin with soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 3 Lucas Red ?N? Tacky NLGI # 2 grease Section 4. First aid measures Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Skin contact : No known significant effects or critical hazards. Ingestion : May cause burns to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. : None known. Specific hazards arising from the chemical Hazardous thermal decomposition products : No specific fire or explosion hazard. : No specific data. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 4 Lucas Red ?N? Tacky NLGI # 2 grease Section 5. Fire-fighting measures Special protective actions for fire-fighters Special protective equipment for fire-fighters : No special precaution is required. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Small spill : Large spill : Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 5 Lucas Red ?N? Tacky NLGI # 2 grease Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls Environmental exposure controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point : Solid. [Grease.] : Red. : Mild. Petroleum oil. : Not available. : Not applicable. : Not available. Boiling point : Not available. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 6 Lucas Red ?N? Tacky NLGI # 2 grease Section 9. Physical and chemical properties Flash point : Not available. Burning time : Not available. Burning rate Evaporation rate : Not available. : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility : Not available. : Not available. : Not available. : 0.9 : Negligible at 25oC Solubility in water : 0 g/l Partition coefficient: n- octanol/water Auto-ignition temperature : Not available. : Not available. Decomposition temperature : Not available. SADT Viscosity : Not available. : Kinematic (100?C (212?F)): 0.19 cm2/s (19 cSt) Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : Excessive heat. Incompatible materials : Reactive or incompatible with the following materials: strong oxidizers. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity There is no data available. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Zinc Alkyldithiophosphate Eyes - Irritant Rabbit - - - Sensitization Skin : Respiratory : There is no data available. There is no data available. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 7 Lucas Red ?N? Tacky NLGI # 2 grease Section 11. Toxicological information Mutagenicity There is no data available. Carcinogenicity There is no data available. Reproductive toxicity There is no data available. Teratogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard There is no data available. Information on the likely : routes of exposure Potential acute health effects Eye contact : Dermal contact. Eye contact. Inhalation. Ingestion. Causes serious eye damage. Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Skin contact : No known significant effects or critical hazards. Ingestion : May cause burns to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : No known significant effects or critical hazards. Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate effects : No known significant effects or critical hazards. Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 8 Lucas Red ?N? Tacky NLGI # 2 grease Section 11. Toxicological information Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates There is no data available. Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure Zinc Alkyldithiophosphate Acute EC50 1 to 5 mg/L Acute EC50 1 to 1.5 mg/L Chronic LC50 1 to 5 mg/L Algae Crustaceans Fish 96 hours 48 hours 96 hours Persistence and degradability There is no data available. Bioaccumulative potential There is no data available. Mobility in soil Soil/water partition coefficient (KOC) : There is no data available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 9 Lucas Red ?N? Tacky NLGI # 2 grease Section 14. Transport information DOT Classification IMDG IATA UN number Not regulated. Not regulated. Not regulated. UN proper - - - shipping name Transport - - - hazard class(es) Packing group - - - Environmental No. No. No. hazards Additional - - - information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) PAIR: Zinc Alkyldithiophosphate TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 307: Zinc Alkyldithiophosphate Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : Not listed : Not listed : Not listed : Not listed : Not listed Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. Lucas Red ?N? Tacky NLGI # 2 grease Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10 Section 15. Regulatory information SARA 311/312 Classification : Immediate (acute) health hazard Composition/information on ingredients Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Zinc Alkyldithiophosphate 1 - 5 No. No. No. Yes. No. SARA 313 Product name CAS number % Form R - Reporting requirements Zinc Alkyldithiophosphate 68649-42-3 1 - 5 Supplier notification Zinc Alkyldithiophosphate 68649-42-3 1 - 5 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : The following components are listed: Distillates (petroleum), hydrotreated heavy naphthenic; Distillates (petroleum), solvent-dewaxed heavy paraffinic; Zinc Alkyldithiophosphate Pennsylvania : The following components are listed: Zinc Alkyldithiophosphate California Prop. 65 No products were found. International regulations International lists : Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals : Not listed : Not listed : Not listed Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 11 Lucas Red ?N? Tacky NLGI # 2 grease Section 16. Other information Hazardous Material Information System (U.S.A.) Health : 2 * Flammability : 0 Physical hazards : 0 Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health : 2 Flammability : 0 Instability : 0 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue mm/dd/yyyy : 02/15/2014 Version : 1 Revised Section(s) : Not applicable. Prepared by : KMK Regulatory Services Inc. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.