3M? Intake System Cleaner Kit, 08962 09/01/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 18-2612-2 Version Number: 5.00 Issue Date: 09/01/15 Supercedes Date: 07/30/14 Product identifier 3M? Intake System Cleaner Kit, 08962 ID Number(s): LB-K100-0312-7, 60-4550-3783-2, 60-4550-6921-5 Recommended use Automotive, System of products to clean automotive engine systems. Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 09-6858-6, 23-3615-4, 18-2194-1 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Intake System Cleaner Kit, 08962 09/01/15 ________________________________________________________________________________________________________ Page 2 of 2 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 1 of 16 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 18-2194-1 Version Number: 8.00 Issue Date: 07/30/14 Supercedes Date: 03/21/13 SECTION 1: Identification 1.1. Product identifier 3M? Throttle Plate Cleaner, 08182, 08185 Product Identification Numbers LB-K100-0610-7, 60-4550-3159-5, 60-4550-6924-9, 60-9800-3834-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Clean and lubricate throttle body assemblies. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Aspiration Hazard: Category 1. Reproductive Toxicity: Category 2. Carcinogenicity: Category 2. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 2 of 16 Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Causes serious eye irritation. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Suspected of causing cancer. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | May cause damage to organs through prolonged or repeated exposure: sensory organs | Precautionary Statements General: Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 3 of 16 If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 17% of the mixture consists of ingredients of unknown acute oral toxicity. 17% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Acetone 67-64-1 15 - 40 Trade Secret * Petroleum Gases, Liquefied, Sweetened 68476-86-8 10 - 30 Trade Secret * Hydrotreated Light Naphtha (Petroleum) 64742-49-0 10 - 30 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 10 - 30 Trade Secret * Heptane 142-82-5 5 - 10 Trade Secret * Xylene 1330-20-7 5 - 10 Trade Secret * Methyl Acetate 79-20-9 3 - 7 Trade Secret * Polyether Amine Trade Secret* 1 - 5 Trade Secret * Ethylbenzene 100-41-4 1 - 5 Trade Secret * Methyl Alcohol 67-56-1 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 4 of 16 Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. In case of fire: Stop leak if safe to do so. Fight fire with normal precautions from a reasonable distance. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Close cylinder. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid eye contact. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 5 of 16 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm Hydrotreated Light Naphtha (Petroleum) 64742-49-0 CMRG TWA:50 ppm Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Skin Notation Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Acetone 67-64-1 ACGIH TWA:500 ppm;STEL:750 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 6 of 16 Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Gas Specific Physical Form: Aerosol Odor, Color, Grade: Amber Liquid dispensed as an aerosol, solvent odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point -150 ?F Evaporation rate No Data Available Flammability (solid, gas) Flammable Aerosol: Category 1. Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 35 psi Vapor Density >=1 [Ref Std: AIR=1] Density 0.88 g/ml Specific Gravity 0.88 [Ref Std: WATER=1] Solubility in Water Moderate Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature Not Applicable Viscosity No Data Available Hazardous Air Pollutants 10.03 % weight [Test Method: Calculated] Volatile Organic Compounds 44.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 524 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 98 % VOC Less H2O & Exempt Solvents 905 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 7 of 16 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Formaldehyde Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 8 of 16 Target Organ Effects: Single exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Vapor (4 hours) Rat LC50 76 mg/l Acetone Ingestion Rat LD50 5,800 mg/kg Hydrotreated Light Naphtha (Petroleum) Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Naphtha (Petroleum) Inhalation- Vapor (4 hours) Rat LC50 > 14.7 mg/l Hydrotreated Light Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Petroleum Gases, Liquefied, Sweetened Inhalation- Gas (4 hours) Rat LC50 277,000 ppm Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 Rat LC50 29 mg/l 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 9 of 16 hours) Xylene Ingestion Rat LD50 3,523 mg/kg Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Acetone Mouse Minimal irritation Hydrotreated Light Naphtha (Petroleum) Rabbit Irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Gases, Liquefied, Sweetened No significant irritation Heptane Human Mild irritant Xylene Rabbit Mild irritant Methyl Acetate Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Methyl Alcohol Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Acetone Rabbit Severe irritant Hydrotreated Light Naphtha (Petroleum) Rabbit Mild irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Gases, Liquefied, Sweetened No significant irritation Heptane Moderate irritant Xylene Rabbit Mild irritant Methyl Acetate Rabbit Moderate irritant Ethylbenzene Rabbit Moderate irritant Methyl Alcohol Rabbit Moderate irritant Skin Sensitization Name Species Value Hydrotreated Light Naphtha (Petroleum) Guinea pig Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Methyl Acetate Human Not sensitizing Ethylbenzene Human Not sensitizing Methyl Alcohol Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Naphtha (Petroleum) In Vitro Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Petroleum Gases, Liquefied, Sweetened In Vitro Not mutagenic 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 10 of 16 Heptane In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Acetone Not Specified Multiple animal species Not carcinogenic Hydrotreated Light Naphtha (Petroleum) Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Ethylbenzene Inhalation Multiple animal species Carcinogenic Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not toxic to female reproduction Mouse NOAEL 11,298 mg/kg/day 13 weeks Acetone Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 1,700 mg/kg/day 13 weeks Acetone Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 5.2 mg/l during organogenesi s Xylene Ingestion Not toxic to female reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Ingestion Not toxic to male reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Xylene Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL Not available during organogenesi s Xylene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for Rat NOAEL 4.3 mg/l premating & during 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 11 of 16 classification gestation Methyl Alcohol Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s Lactation Name Route Species Value Xylene Ingestion Mouse Does not cause effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Acetone Inhalation immune system Some positive data exist, but the data are not sufficient for classification Human NOAEL 1.19 mg/l 6 hours Acetone Inhalation liver Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL Not available Acetone Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hydrotreated Light Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Hydrotreated Light Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Petroleum Gases, Liquefied, Sweetened Inhalation cardiac sensitization Causes damage to organs similar compoun ds NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Petroleum Gases, Liquefied, Sweetened Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Petroleum Gases, Liquefied, Sweetened Inhalation respiratory irritation All data are negative NOAEL Not available Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Some positive data exist, but the Rat NOAEL 3.5 not available 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 12 of 16 data are not sufficient for classification mg/l Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg not applicable Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Some positive data exist, but the data are not sufficient for classification NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Dermal eyes Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL Not available 3 weeks Acetone Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Human NOAEL 3 mg/l 6 weeks Acetone Inhalation immune system Some positive data exist, but the data are not sufficient for classification Human NOAEL 1.19 mg/l 6 days Acetone Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 119 mg/l not available Acetone Inhalation heart | liver All data are negative Rat NOAEL 45 mg/l 8 weeks Acetone Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 900 mg/kg/day 13 weeks Acetone Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 200 mg/kg/day 13 weeks Acetone Ingestion liver Some positive data exist, but the data are not sufficient for Mouse NOAEL 3,896 14 days 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 13 of 16 classification mg/kg/day Acetone Ingestion eyes All data are negative Rat NOAEL 3,400 mg/kg/day 13 weeks Acetone Ingestion respiratory system All data are negative Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion muscles All data are negative Rat NOAEL 2,500 mg/kg 13 weeks Acetone Ingestion skin | bone, teeth, nails, and/or hair All data are negative Mouse NOAEL 11,298 mg/kg/day 13 weeks Petroleum Gases, Liquefied, Sweetened Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Heptane Inhalation liver | nervous system | kidney and/or bladder All data are negative Rat NOAEL 12 mg/l 26 weeks Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | hematopoietic system | muscles | kidney and/or bladder | respiratory system All data are negative Multiple animal species NOAEL 3.5 mg/l 13 weeks Xylene Ingestion auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system All data are negative Mouse NOAEL 1,000 mg/kg/day 103 weeks Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 6.1 mg/l 28 days Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic Some positive data exist, but the Rat NOAEL 3.4 28 days 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 14 of 16 system data are not sufficient for classification mg/l Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months Methyl Alcohol Inhalation liver All data are negative Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system All data are negative Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 90 days Aspiration Hazard Name Value Hydrotreated Light Naphtha (Petroleum) Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Heptane Aspiration hazard Xylene Aspiration hazard Ethylbenzene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. The facility should be equipped to handle gaseous waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 15 of 16 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Xylene 1330-20-7 5 - 10 Ethylbenzene 100-41-4 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Ethylbenzene 100-41-4 Carcinogen Methyl Alcohol 67-56-1 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. 3M? Throttle Plate Cleaner, 08182, 08185 07/30/14 __________________________________________________________________________________________ Page 16 of 16 Document Group: 18-2194-1 Version Number: 8.00 Issue Date: 07/30/14 Supercedes Date: 03/21/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 09-6858-6 Version Number: 13.00 Issue Date: 06/30/14 Supercedes Date: 10/09/12 SECTION 1: Identification 1.1. Product identifier 3M? Intake System Cleaner, 08958 Product Identification Numbers LB-K100-0404-1, 60-4550-4850-8, 60-4550-6923-1, 60-9800-3825-5, IE-2701-0012-6, IE-2701-0013-4 1.2. Recommended use and restrictions on use Recommended use Automotive, Remove deposits from automotive engine interiors 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Aspiration Hazard: Category 1. Carcinogenicity: Category 2. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 2 of 13 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable aerosol. Causes serious eye irritation. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of causing cancer. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 3 of 13 Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 10% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Isopropyl Alcohol 67-63-0 30 - 60 Trade Secret * Water 7732-18-5 10 - 30 Trade Secret * Heavy Aromatic Solvent Naphtha (Petroleum) 64742-94-5 10 - 30 Trade Secret * Isobutane 75-28-5 7 - 13 Trade Secret * Oleic Acid 112-80-1 6 - 13 Trade Secret * Triethanolamine 102-71-6 5 - 10 Trade Secret * Linoleic Acid 60-33-3 1 - 5 Trade Secret * Tripropylene Glycol Methyl Ether 25498-49-1 1 - 5 Trade Secret * Naphthalene 91-20-3 < 0.2 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 4 of 13 SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 5 of 13 exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Triethanolamine 102-71-6 ACGIH TWA:5 mg/m3 Heavy Aromatic Solvent Naphtha (Petroleum) 64742-94-5 CMRG TWA:17 ppm(100 mg/m3) Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) Isobutane 75-28-5 ACGIH STEL:1000 ppm Natural gas 75-28-5 ACGIH Limit value not established: Naphthalene 91-20-3 ACGIH TWA:10 ppm Skin Notation Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 6 of 13 An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Dark Amber Liquid, Solvent Odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Flash Point -120 ?F [Test Method: Tagliabue Open Cup] [Details: propellant] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.85 g/ml Specific Gravity 0.85 [Ref Std: WATER=1] [Details: Data based on liquid.] Solubility in Water Moderate Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.174 % weight [Test Method: Calculated] Volatile Organic Compounds 44.1 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 502 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 77.1 % weight VOC Less H2O & Exempt Solvents 593 g/l [Test Method: calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents 4.95 lb/gal [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Light Sparks and/or flames 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 7 of 13 10.5. Incompatible materials Strong oxidizing agents Strong acids 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 8 of 13 Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Isopropyl Alcohol Dermal Rabbit LD50 12,870 mg/kg Isopropyl Alcohol Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l Isopropyl Alcohol Ingestion Rat LD50 4,710 mg/kg Isobutane Inhalation- Gas (4 hours) Rat LC50 276,000 ppm Heavy Aromatic Solvent Naphtha (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg Heavy Aromatic Solvent Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Oleic Acid Dermal Guinea pig LD50 > 3,000 mg/kg Oleic Acid Ingestion Rat LD50 57,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Tripropylene Glycol Methyl Ether Dermal Rabbit LD50 > 19,340 mg/kg Tripropylene Glycol Methyl Ether Inhalation- Dust/Mist Rat LC50 estimated to be 5 - 12.5 mg/l Tripropylene Glycol Methyl Ether Ingestion Rat LD50 3,300 mg/kg Linoleic Acid Dermal Guinea pig LD50 > 18,000 mg/kg Linoleic Acid Ingestion Rat LD50 > 3,200 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Isopropyl Alcohol Multiple animal species No significant irritation Isobutane No significant irritation Heavy Aromatic Solvent Naphtha (Petroleum) Rabbit Irritant Oleic Acid Rabbit Minimal irritation Triethanolamine Rabbit Minimal irritation Naphthalene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Isopropyl Alcohol Rabbit Severe irritant Isobutane No significant irritation Heavy Aromatic Solvent Naphtha (Petroleum) Rabbit Mild irritant Oleic Acid Rabbit Mild irritant Triethanolamine Rabbit Mild irritant 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 9 of 13 Naphthalene Rabbit No significant irritation Skin Sensitization Name Species Value Isopropyl Alcohol Guinea pig Not sensitizing Heavy Aromatic Solvent Naphtha (Petroleum) Guinea pig Not sensitizing Triethanolamine Human Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Isopropyl Alcohol In Vitro Not mutagenic Isopropyl Alcohol In vivo Not mutagenic Isobutane In Vitro Not mutagenic Oleic Acid In Vitro Some positive data exist, but the data are not sufficient for classification Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Carcinogenicity Name Route Species Value Isopropyl Alcohol Inhalation Rat Some positive data exist, but the data are not sufficient for classification Heavy Aromatic Solvent Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Oleic Acid Dermal Mouse Not carcinogenic Oleic Acid Ingestion Rat Not carcinogenic Oleic Acid Not Specified Multiple animal species Not carcinogenic Triethanolamine Dermal Multiple animal species Not carcinogenic Triethanolamine Ingestion Mouse Some positive data exist, but the data are not sufficient for classification Naphthalene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Isopropyl Alcohol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s Isopropyl Alcohol Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation Triethanolamine Ingestion Not toxic to development Mouse NOAEL 1,125 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 10 of 13 Isopropyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Isopropyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Isopropyl Alcohol Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours Isopropyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available Isobutane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not available Heavy Aromatic Solvent Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Heavy Aromatic Solvent Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isopropyl Alcohol Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months Isopropyl Alcohol Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks Isopropyl Alcohol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks Isobutane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks Oleic Acid Ingestion liver | immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,250 mg/kg/day 108 weeks Oleic Acid Ingestion hematopoietic system All data are negative Rat NOAEL 2,550 mg/kg/day 108 weeks Triethanolamine Dermal kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,000 mg/kg/day 2 years Triethanolamine Dermal liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 4,000 mg/kg/day 13 weeks Triethanolamine Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1,000 mg/kg/day 2 years Triethanolamine Ingestion liver Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 1,600 mg/kg/day 24 weeks Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL .01 mg/l 13 weeks 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 11 of 13 Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Aspiration Hazard Name Value Heavy Aromatic Solvent Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 12 of 13 Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Naphthalene 91-20-3 < 0.2 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Naphthalene 91-20-3 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 09-6858-6 Version Number: 13.00 Issue Date: 06/30/14 Supercedes Date: 10/09/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M? Intake System Cleaner, 08958 06/30/14 __________________________________________________________________________________________ Page 13 of 13 3M USA SDSs are available at www.3M.com 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 23-3615-4 Version Number: 3.00 Issue Date: 02/11/14 Supercedes Date: 02/11/14 SECTION 1: Identification 1.1. Product identifier 3M? Complete Fuel System Cleaner, 08813, 38814 Product Identification Numbers 60-4550-3265-0, 60-4550-4499-4, 60-4550-6487-7, 60-4550-8195-4 1.2. Recommended use and restrictions on use Recommended use Automotive, Clean Automotive Fuel System Components 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 3. Aspiration Hazard: Category 1. Carcinogenicity: Category 2. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 2 of 12 Pictograms Hazard Statements Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of causing cancer. Precautionary Statements General: Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Not applicable 2.3. Hazards not otherwise classified None. 11% of the mixture consists of ingredients of unknown acute oral toxicity. 14% of the mixture consists of ingredients of unknown acute dermal toxicity. 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 3 of 12 29% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Kerosene 8008-20-6 60 - 100 Trade Secret * Sweetened Middle Distillates (Petroleum) 64741-86-2 10 - 30 Trade Secret * Polyether Amine Trade Secret* 5 - 15 Trade Secret * Propoxylated Alcohol Trade Secret* 1 - 5 Trade Secret * Heavy Aromatic Solvent Naphtha (Petroleum) 64742-94-5 0.5 - 1.5 Trade Secret * Naphthalene 91-20-3 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 4 of 12 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Vapors may travel long distances along the ground or floor to an ignition source and flash back. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Heavy Aromatic Solvent Naphtha (Petroleum) 64742-94-5 Chemical Manufacturer Rec Guid TWA:17 ppm(100 mg/m3) Kerosene 8008-20-6 Amer Conf of Gov. Indust. TWA(as total hydrocarbon vapor, non-aerosol):200 Skin Notation 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 5 of 12 Hyg. mg/m3 Kerosene 8008-20-6 Chemical Manufacturer Rec Guid TWA:500 ppm(2000 mg/m3) Naphthalene 91-20-3 Amer Conf of Gov. Indust. Hyg. TWA:10 ppm;STEL:15 ppm Skin Notation Naphthalene 91-20-3 US Dept of Labor - OSHA TWA:50 mg/m3(10 ppm) Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists American Indust. Hygiene Assoc : American Industrial Hygiene Association Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear protective gloves and eye/face protection. Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Light yellow liquid; Solvent/kerosene odor. Odor threshold No Data Available 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 6 of 12 pH No Data Available Melting point No Data Available Boiling Point <=550 ?F Flash Point >=120 ?F [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.83 g/ml Specific Gravity 0.83 [Ref Std: WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Decomposition temperature No Data Available Viscosity 6.04 centipoise [Test Method: Brookfield] Hazardous Air Pollutants 0.449 % weight [Test Method: Calculated] Volatile Organic Compounds 88.8 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 723 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 87.2 % weight [Test Method: Estimated] VOC Less H2O & Exempt Solvents 723 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 7 of 12 relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: May be harmful in contact with skin. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,374.8 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 23.1 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Kerosene Dermal Rabbit LD50 > 2,000 mg/kg Kerosene Inhalation- Vapor (4 Rat LC50 > 5 mg/l 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 8 of 12 hours) Kerosene Ingestion Rat LD50 > 5,000 mg/kg Sweetened Middle Distillates (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg Sweetened Middle Distillates (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Propoxylated Alcohol Ingestion LD50 estimated to be > 5,000 mg/kg Heavy Aromatic Solvent Naphtha (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg Heavy Aromatic Solvent Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Kerosene Rabbit Minimal irritation Heavy Aromatic Solvent Naphtha (Petroleum) Rabbit Irritant Naphthalene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Kerosene Rabbit No significant irritation Heavy Aromatic Solvent Naphtha (Petroleum) Rabbit Mild irritant Naphthalene Rabbit No significant irritation Skin Sensitization Name Species Value Kerosene Guinea pig Some positive data exist, but the data are not sufficient for classification Heavy Aromatic Solvent Naphtha (Petroleum) Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Kerosene In Vitro Some positive data exist, but the data are not sufficient for classification Kerosene In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Kerosene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Heavy Aromatic Solvent Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Naphthalene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Kerosene Dermal Not toxic to female reproduction Rat NOAEL 494 mg/kg/day premating & during gestation Kerosene Dermal Not toxic to male reproduction Rat NOAEL 494 mg/kg/day premating & during gestation 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 9 of 12 Kerosene Dermal Not toxic to development Rat NOAEL 494 mg/kg/day premating & during gestation Kerosene Inhalation Not toxic to development Rat NOAEL 400 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Kerosene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL not available occupational exposure Kerosene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL not available not available Kerosene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL not available poisoning and/or abuse Kerosene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL not available not applicable Kerosene Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 18,912 mg/kg not applicable Kerosene Ingestion heart | hematoppoitic system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available poisoning and/or abuse Heavy Aromatic Solvent Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Heavy Aromatic Solvent Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Kerosene Dermal hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 500 mg/kg/day 13 weeks Kerosene Dermal liver | immune system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 500 mg/kg/day 2 years Kerosene Dermal nervous system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 2,700 mg/kg/day 1 weeks Kerosene Dermal heart | muscles | respiratory system All data are negative Mouse NOAEL 500 mg/kg/day 2 years Kerosene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL not available 1 years Kerosene Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.231 mg/l 14 weeks Kerosene Inhalation heart Some positive data exist, but the data are not sufficient for classification Guinea pig LOAEL 20.4 mg/l not available Kerosene Inhalation hematopoietic system | muscles | respiratory system All data are negative Multiple animal species NOAEL 0.1 mg/l 13 weeks Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Some positive data exist, but the Human NOAEL Not occupational 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 10 of 12 data are not sufficient for classification available exposure Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL .01 mg/l 13 weeks Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Aspiration Hazard Name Value Kerosene Aspiration hazard Heavy Aromatic Solvent Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 11 of 12 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Naphthalene 91-20-3 < 0.5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Naphthalene 91-20-3 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 23-3615-4 Version Number: 3.00 Issue Date: 02/11/14 Supercedes Date: 02/11/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer 3M? Complete Fuel System Cleaner, 08813, 38814 02/11/14 __________________________________________________________________________________________ Page 12 of 12 may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com