3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 23-4964-5 Version Number: 5.00 Issue Date: 06/16/14 Supercedes Date: 12/30/11 SECTION 1: Identification 1.1. Product identifier 3M (TM) Injector Cleaner, P.N. 08812 Product Identification Numbers 60-4550-3266-8, 60-4550-6518-9 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 3. Skin Sensitizer: Category 1. Aspiration Hazard: Category 1. Carcinogenicity: Category 2. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 2 of 11 Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable liquid and vapor. May cause an allergic skin reaction. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of causing cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 3 of 11 Repeated exposure may cause skin dryness or cracking. 4% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Kerosene 8008-20-6 60 - 100 Trade Secret * Hydrocarbyl Amine Trade Secret* < 3 Trade Secret * Hydrocarbon Solvent 64741-86-2 < 3 Trade Secret * Polyether Amine Trade Secret* < 2 Trade Secret * Petroleum Naphtha 64742-94-5 < 2 Trade Secret * Naphthalene 91-20-3 < 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 4 of 11 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Vapors may travel long distances along the ground or floor to an ignition source and flash back. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Petroleum Naphtha 64742-94-5 CMRG TWA:17 ppm(100 mg/m3) 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 5 of 11 Kerosene 8008-20-6 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 Skin Notation Kerosene 8008-20-6 CMRG TWA:500 ppm(2000 mg/m3) Naphthalene 91-20-3 ACGIH TWA:10 ppm Skin Notation Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear protective gloves and eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Neoprene Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Clear liquid, Solvent/kerosene odor Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 360 - 550 ?F [Details: Based on Kerosene's MSDS] Flash Point 120 ?F [Test Method: Closed Cup] [Details: based on kerosene's 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 6 of 11 MSDS] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 6.83 lb/gal Specific Gravity 0.82 [Ref Std: WATER=1] Solubility In Water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 489 ?F [Details: based on kerosene's MSDS] Decomposition temperature No Data Available Viscosity 14.2 centipoise Hazardous Air Pollutants 0.58 % weight [Test Method: Calculated] Volatile Organic Compounds 100 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 820 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile No Data Available VOC Less H2O & Exempt Solvents 820 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 7 of 11 reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Kerosene Dermal Rabbit LD50 > 2,000 mg/kg Kerosene Inhalation- Vapor (4 hours) Rat LC50 > 5 mg/l Kerosene Ingestion Rat LD50 > 5,000 mg/kg Hydrocarbon Solvent Dermal Rabbit LD50 > 2,000 mg/kg 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 8 of 11 Hydrocarbon Solvent Ingestion Rat LD50 > 5,000 mg/kg Petroleum Naphtha Dermal Rabbit LD50 > 2,000 mg/kg Petroleum Naphtha Ingestion Rat LD50 > 5,000 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation- Vapor Human LC50 estimated to be 20 - 50 mg/l Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Kerosene Rabbit Minimal irritation Petroleum Naphtha Rabbit Irritant Naphthalene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Kerosene Rabbit No significant irritation Petroleum Naphtha Rabbit Mild irritant Naphthalene Rabbit No significant irritation Skin Sensitization Name Species Value Kerosene Guinea pig Some positive data exist, but the data are not sufficient for classification Petroleum Naphtha Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Kerosene In Vitro Some positive data exist, but the data are not sufficient for classification Kerosene In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Kerosene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Petroleum Naphtha Dermal Mouse Some positive data exist, but the data are not sufficient for classification Naphthalene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Kerosene Dermal Not toxic to female reproduction Rat NOAEL 494 mg/kg/day premating & during gestation Kerosene Dermal Not toxic to male reproduction Rat NOAEL 494 mg/kg/day premating & during gestation Kerosene Dermal Not toxic to development Rat NOAEL 494 mg/kg/day premating & during gestation 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 9 of 11 Kerosene Inhalation Not toxic to development Rat NOAEL 400 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Kerosene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL not available occupational exposure Kerosene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL not available not available Kerosene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL not available poisoning and/or abuse Kerosene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL not available not applicable Kerosene Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 18,912 mg/kg not applicable Kerosene Ingestion heart | hematoppoitic system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available poisoning and/or abuse Petroleum Naphtha Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Petroleum Naphtha Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Kerosene Dermal hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 500 mg/kg/day 13 weeks Kerosene Dermal liver | immune system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 500 mg/kg/day 2 years Kerosene Dermal nervous system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 2,700 mg/kg/day 1 weeks Kerosene Dermal heart | muscles | respiratory system All data are negative Mouse NOAEL 500 mg/kg/day 2 years Kerosene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL not available 1 years Kerosene Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.231 mg/l 14 weeks Kerosene Inhalation heart Some positive data exist, but the data are not sufficient for classification Guinea pig LOAEL 20.4 mg/l not available Kerosene Inhalation hematopoietic system | muscles | respiratory system All data are negative Multiple animal species NOAEL 0.1 mg/l 13 weeks Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Dermal eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Inhalation respiratory system Causes damage to organs Rat LOAEL .01 13 weeks 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 10 of 11 through prolonged or repeated exposure mg/l Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Naphthalene Ingestion eyes May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 500 mg/kg/day 15 days Aspiration Hazard Name Value Kerosene Aspiration hazard Petroleum Naphtha Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: 3M (TM) Injector Cleaner, P.N. 08812 06/16/14 __________________________________________________________________________________________ Page 11 of 11 Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Naphthalene 91-20-3 < 1 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 23-4964-5 Version Number: 5.00 Issue Date: 06/16/14 Supercedes Date: 12/30/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com