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3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 1 of 9 Material Safety Data Sheet Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Rocker Panel Spray (Tan), PN 05910 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 10/18/2007 Supercedes Date: 10/18/2007 Document Group: 18-9426-0 Product Use: Intended Use: Automotive Specific Use: Automotive Coating SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt METHYL ISOBUTYL KETONE 108-10-1 10 - 30 METHYL PROPYL KETONE 107-87-9 10 - 30 DIETHYL KETONE 96-22-0 10 - 30 PROPANE 74-98-6 7 - 13 VINYL CHLORIDE-VINYL ACETATE-MALEIC ACID POLYMER 9005-09-8 5 - 10 HEPTANE 142-82-5 3 - 7 KAOLIN 1332-58-7 3 - 7 TALC 14807-96-6 3 - 7 ISOBUTANE 75-28-5 3 - 7 POLY(ISOBUTYL METHACRYLATE) 9011-15-8 1 - 5 METHYLHEXANES Mixture 1 - 5 POLY(BUTYL METHACRYLATE) 9003-63-8 1 - 5 SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE 112945-52-5 0.5 - 1.5 TOLUENE 108-88-3 < 0.5 N-BUTYL METHACRYLATE 97-88-1 < 0.1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 2 of 9 Specific Physical Form: Aerosol Odor, Color, Grade: Opaque, light tan, mild solvent odor, aerosol General Physical Form: Liquid Immediate health, physical, and environmental hazards: Aerosol container contains flammable gas under pressure. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Dermal Effects: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 3 of 9 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point < 0 ?F [Test Method: Estimated] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. If possible, seal leaking container. Place leaking containers in a well- ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 4 of 9 (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in an approved metal container. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not pierce or burn container, even after use. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid eye contact with vapors, mists, or spray. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Avoid contact with oxidizing agents. For industrial or professional use only. Extinguish pilot lights and turn off stoves, ovens and other gas and electric appliances (space and water heaters, furnaces, etc.), electric motors, and other sources of ignition during adhesive use and until all vapors are gone; i.e., until the odor of vapors at the floor level has disappeared. Do not use electric light switches. Do not generate static sparks (such as by walking on carpet, etc.). Use the same precautions in the work area and all connected areas. Keep out of the reach of children. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid static discharge. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Do not store containers on their sides. Store away from oxidizing agents. Store at temperatures below 120 degrees Fahrenheit (49 degrees C). SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Fluoroelastomer (Viton). 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 5 of 9 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters, Half facepiece or fullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information DIETHYL KETONE ACGIH TWA 200 ppm DIETHYL KETONE ACGIH STEL 300 ppm DIETHYL KETONE OSHA TWA 200 ppm Table Z-1A HEPTANE ACGIH TWA 400 ppm HEPTANE ACGIH STEL 500 ppm HEPTANE OSHA TWA, Vacated 400 ppm HEPTANE OSHA TWA 500 ppm Table Z-1 HEPTANE OSHA STEL, Vacated 500 ppm ISOBUTANE ACGIH TWA 1000 ppm KAOLIN ACGIH TWA, respirable 2 mg/m3 Table A4 KAOLIN OSHA TWA, respirable 5 mg/m3 Table Z-1 KAOLIN OSHA TWA, Vacated, as dust 10 mg/m3 KAOLIN OSHA TWA, as total dust 15 mg/m3 Table Z-1 METHYL ISOBUTYL KETONE ACGIH TWA 50 ppm METHYL ISOBUTYL KETONE ACGIH STEL 75 ppm METHYL ISOBUTYL KETONE OSHA TWA, Vacated 50 ppm METHYL ISOBUTYL KETONE OSHA STEL, Vacated 75 ppm METHYL ISOBUTYL KETONE OSHA TWA 100 ppm Table Z-1 METHYL PROPYL KETONE ACGIH STEL 150 ppm METHYL PROPYL KETONE OSHA TWA 200 ppm Table Z-1A METHYL PROPYL KETONE OSHA STEL 250 ppm Table Z-1A N-BUTYL METHACRYLATE CMRG TWA 50 ppm N-BUTYL METHACRYLATE CMRG STEL 75 ppm PROPANE ACGIH TWA 1000 ppm PROPANE OSHA TWA 1000 ppm Table Z-1 TALC ACGIH TWA, respirable 2 mg/m3 Table A4 TALC CMRG TWA, as respirable dust 0.5 mg/m3 TALC OSHA TWA, respirable 2 mg/m3 Table Z-1A TOLUENE ACGIH TWA 20 ppm Table A4 TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA, Vacated 100 ppm TOLUENE OSHA STEL, Vacated 150 ppm TOLUENE OSHA TWA 200 ppm Table Z-2 TOLUENE OSHA CEIL 300 ppm Table Z-2 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 6 of 9 OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: Opaque, light tan, mild solvent odor, aerosol General Physical Form: Liquid Autoignition temperature No Data Available Flash Point < 0 ?F [Test Method: Estimated] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point [Details: Liquified Compressed Gas] Vapor Density > 1 [Ref Std: AIR=1] Vapor Pressure 45 psi [@ 68 ?F] Specific Gravity 0.852 pH Not Applicable Melting point Not Applicable Solubility in Water Slight (less than 10%) Volatile Organic Compounds 75 % VOC Less H2O & Exempt Solvents 642 g/l Viscosity 350 - 2,200 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Heat; Sparks and/or flames Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Hydrogen Chloride Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 7 of 9 ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. Combustion products will include HCl. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-9801-0703-5 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt METHYL ISOBUTYL KETONE 108-10-1 10 - 30 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status HEPTANE 142-82-5 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 8 of 9 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 2: Ingredient table was modified. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 1: Product use information was modified. Copyright was modified. Section 3: Immediate physical hazard(s) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. 3M MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray (Tan), PN 05910 10/18/2007 _________________________________________________________________________________________________ Page 9 of 9 Section 3: Potential effects from ingestion information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 7: Handling information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 4: First aid for skin contact - termination of exposure - was added. Section 4: First aid for skin contact - decontamination - was modified. Section 4: First aid for skin contact - medical assistance - was modified. Section 4: First aid for skin contact - handling - was added. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 10: Materials and conditions to avoid physical property was modified. Section 3: Other health effects information was modified. Section 3: Other health effects information (reproductive hazards) was added. Section 15: TSCA section 12[b] text was added. Section 15: EPCRA 313 information was added. Section 15: EPCRA 313 text was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines legend was added. Section 8: Exposure guideline note was added. Section 15: TSCA section 12[b] information was added. Section 8: Exposure guidelines data source legend was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com