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3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-5391-7 Version Number: 50.01 Issue Date: 03/02/15 Supercedes Date: 01/20/15 SECTION 1: Identification 1.1. Product identifier 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 Product Identification Numbers 62-5508-5209-9 1.2. Recommended use and restrictions on use Recommended use Automotive, Joint and seam sealer for interior and exterior joints and seams. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Solid: Category 1. Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 2 of 15 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable solid. Causes eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 3 of 15 Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 27% of the mixture consists of ingredients of unknown acute dermal toxicity. 59% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Toluene 108-88-3 15 - 40 Trade Secret * Styrene/Alpha-Methylstyrene Copolymer 9011-11-4 10 - 30 Trade Secret * Hydrocarbon Polymer, Hydrogenated Trade Secret* 10 - 30 Trade Secret * Synthetic Rubber Polymer Trade Secret* 7 - 13 Trade Secret * White Mineral Oil (Petroleum) 8042-47-5 7 - 13 Trade Secret * Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 5 - 10 Trade Secret * Xylene 1330-20-7 1 - 5 Trade Secret * Ethylbenzene 100-41-4 < 2 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * Cumene 98-82-8 < 0.05 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 4 of 15 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible using non-sparking tools. Vacuum or sweep up. WARNING ! A motor could be an ignition source and cause flammable gases or vapors or dust in the spill area to burn or explode. Place in a metal container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent loss of stabilizing materials. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 5 of 15 Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Skin Notation Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 White Mineral Oil (Petroleum) 8042-47-5 CMRG TWA:5 mg/m3;STEL:10 mg/m3 Paraffin oil 8042-47-5 OSHA TWA(as mist):5 mg/m3 MINERAL OILS, HIGHLY- REFINED OILS 8042-47-5 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm) Skin Notation Cumene 98-82-8 ACGIH TWA:50 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate Respiratory protection 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 6 of 15 An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Clear buttery paste with solvent odor Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 232 ?F [Details: CONDITIONS: (toluene)] Flash Point 24 ?F [Test Method: Closed Cup] [Details: Method D56] Evaporation rate 4.50 [Ref Std: ETHER=1] Flammability (solid, gas) Flammable Solid: Category 1. Flammable Limits(LEL) 1.27 % volume Flammable Limits(UEL) 7.00 % volume Vapor Pressure 25.19 mmHg [Details: CONDITIONS: @ 68F] Vapor Density 3.14 [Ref Std: AIR=1] Density 0.98 g/ml Specific Gravity 0.980 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Approximately 450,000 centipoise Hazardous Air Pollutants 0.83 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 39.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 393 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 40.1 % weight VOC Less H2O & Exempt Solvents 393 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 7 of 15 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 8 of 15 Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Cumene 98-82-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Styrene/Alpha-Methylstyrene Copolymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Hydrocarbon Polymer, Hydrogenated Dermal Rat LD50 > 2,000 mg/kg Hydrocarbon Polymer, Hydrogenated Ingestion Rat LD50 > 5,000 mg/kg White Mineral Oil (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White Mineral Oil (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Synthetic Rubber Polymer Ingestion LD50 estimated to be > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Cumene Dermal Rabbit LD50 > 3,160 mg/kg Cumene Inhalation- Vapor (4 hours) Rat LC50 39.4 mg/l Cumene Ingestion Rat LD50 1,400 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 9 of 15 Toluene Rabbit Irritant White Mineral Oil (Petroleum) Rabbit No significant irritation Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Xylene Rabbit Mild irritant Ethylbenzene Rabbit Mild irritant Cumene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Toluene Rabbit Moderate irritant White Mineral Oil (Petroleum) Rabbit Mild irritant Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Xylene Rabbit Mild irritant Ethylbenzene Rabbit Moderate irritant Cumene Rabbit Mild irritant Skin Sensitization Name Species Value Toluene Guinea pig Not sensitizing White Mineral Oil (Petroleum) Guinea pig Not sensitizing Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not sensitizing Ethylbenzene Human Not sensitizing Cumene Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic White Mineral Oil (Petroleum) In Vitro Not mutagenic Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Cumene In Vitro Not mutagenic Cumene In vivo Not mutagenic Carcinogenicity Name Route Species Value Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification White Mineral Oil (Petroleum) Dermal Mouse Not carcinogenic White Mineral Oil (Petroleum) Inhalation Multiple animal species Not carcinogenic Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Xylene Dermal Rat Not carcinogenic 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 10 of 15 Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Ethylbenzene Inhalation Multiple animal species Carcinogenic Cumene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse White Mineral Oil (Petroleum) Ingestion Not toxic to female reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not toxic to male reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not toxic to development Rat NOAEL 4,350 mg/kg/day during gestation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Xylene Ingestion Not toxic to female reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Ingestion Not toxic to male reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Xylene Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL Not available during organogenesi s Xylene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 4.3 mg/l premating & during gestation Cumene Inhalation Not toxic to female reproduction Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion Not toxic to male reproduction Rat NOAEL 769 mg/kg/day 6 months Cumene Inhalation Not toxic to male reproduction Rat NOAEL 59 mg/l 13 weeks 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 11 of 15 Cumene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rabbit NOAEL 11.3 mg/l during organogenesi s Lactation Name Route Species Value Xylene Ingestion Mouse Does not cause effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg not applicable Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cumene Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2 mg/l occupational exposure Cumene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for Rat LOAEL 2.3 mg/l 15 months 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 12 of 15 classification Toluene Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks White Mineral Oil (Petroleum) Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,381 mg/kg/day 90 days White Mineral Oil (Petroleum) Ingestion liver | immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,336 mg/kg/day 90 days Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | hematopoietic system | muscles | kidney and/or bladder | respiratory system All data are negative Multiple animal species NOAEL 3.5 mg/l 13 weeks Xylene Ingestion auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 13 of 15 Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system All data are negative Mouse NOAEL 1,000 mg/kg/day 103 weeks Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months Cumene Inhalation auditory system | endocrine system | hematopoietic system | liver | nervous system | eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 59 mg/l 13 weeks Cumene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4.9 mg/l 13 weeks Cumene Inhalation respiratory system All data are negative Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 769 mg/kg/day 6 months Cumene Ingestion heart | endocrine system | hematopoietic system | liver | respiratory system All data are negative Rat NOAEL 769 mg/kg/day 6 months Aspiration Hazard Name Value Toluene Aspiration hazard White Mineral Oil (Petroleum) Aspiration hazard Xylene Aspiration hazard Ethylbenzene Aspiration hazard Cumene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 14 of 15 Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 15 - 40 Xylene (Benzene, 1,2-dimethyl-) 1330-20-7 1 - 5 Xylene (Benzene, dimethyl-) 1330-20-7 1 - 5 Xylene 1330-20-7 1 - 5 Xylene (Benzene, 1,3-dimethyl-) 1330-20-7 1 - 5 Xylene (Benzene, 1,4-dimethyl-) 1330-20-7 1 - 5 Ethylbenzene 100-41-4 < 2 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Ethylbenzene 100-41-4 Carcinogen Toluene 108-88-3 Female reproductive toxin 3M? Flexiclear? Body Seam Sealer, PN 08401, 08405 03/02/15 __________________________________________________________________________________________ Page 15 of 15 Toluene 108-88-3 Developmental Toxin Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin Cumene 98-82-8 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-5391-7 Version Number: 50.01 Issue Date: 03/02/15 Supercedes Date: 01/20/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com