3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 25-7697-3 Version Number: 3.00 Issue Date: 04/24/15 Supercedes Date: 03/16/12 SECTION 1: Identification 1.1. Product identifier 3M? Flowable Finishing Putty PN 05823, 05824 Product Identification Numbers 41-0003-6535-7, 41-3701-1595-2 1.2. Recommended use and restrictions on use Recommended use Automotive, Finishing Putty for filling pinholes, sand scratches, low areas or other imperfections 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 3. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 2 of 14 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. Suspected of causing cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: immune system | liver | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 3 of 14 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 29% of the mixture consists of ingredients of unknown acute oral toxicity. 34% of the mixture consists of ingredients of unknown acute dermal toxicity. 30% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Limestone 1317-65-3 10 - 30 Styrene Monomer 100-42-5 10 - 30 Polyester Resin (Proprietary) Trade Secret* 10 - 30 Talc 14807-96-6 7 - 13 PROPRIETARY POLYMER Trade Secret* 7 - 13 Titanium Dioxide 13463-67-7 5 - 10 Magnesium Carbonate 546-93-0 3 - 7 Inert Filler Trade Secret* 3 - 7 Synthetic Crystalline-Free Silica Gel 112926-00-8 1 - 5 Trimethylolpropane Triacrylate 15625-89-5 1 - 5 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 4 of 14 If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of dust created by cutting, sanding, grinding or machining. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 5 of 14 potential for static electricity accumulation during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Styrene Monomer 100-42-5 ACGIH TWA:20 ppm;STEL:40 ppm A4: Not class. as human carcin Styrene Monomer 100-42-5 OSHA TWA:100 ppm;CEIL:200 ppm SILICA, AMORPHOUS 112926-00- 8 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Trimethylolpropane Triacrylate 15625-89-5 AIHA TWA:1 mg/m3 Skin Notation Magnesium Carbonate 546-93-0 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Inert Filler Trade Secret ACGIH TWA(as fiber):0.2 fiber/cc A2: Suspected human carcin. Inert Filler Trade Secret Manufacturer determined TWA(as dust):10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 6 of 14 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Pungent styrene odor Light Yellow Putty Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 145 ?C Flash Point 31 ?C [Test Method: Pensky-Martens Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 4.5 mmHg Vapor Density No Data Available Density 1.1 g/ml Specific Gravity 1.1 [Ref Std: WATER=1] Solubility in Water Nil 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 7 of 14 Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 0.46 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 241 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 21.9 % weight [Test Method: calculated per CARB title 2] Percent volatile 22 % weight VOC Less H2O & Exempt Solvents 241 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents Alkali and alkaline earth metals Strong bases 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 8 of 14 Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause additional health effects (see below). Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or respiratory reaction, and changes in immune function. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Inert Filler Trade Secret Grp. 2B: Possible human carc. International Agency for Research on Cancer Inert Filler Trade Secret Anticipated human carcinogen National Toxicology Program Carcinogens Inert Filler Trade Secret Anticipated human carcinogen National Toxicology Program Carcinogens Styrene Monomer 100-42-5 Grp. 2B: Possible human carc. International Agency for Research on Cancer Styrene Monomer 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 9 of 14 If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Styrene Monomer Dermal Rat LD50 > 2,000 mg/kg Styrene Monomer Inhalation- Vapor (4 hours) Rat LC50 8.3 mg/l Styrene Monomer Ingestion Rat LD50 5,000 mg/kg Limestone Dermal Rat LD50 > 2,000 mg/kg Limestone Inhalation- Dust/Mist (4 hours) Rat LC50 3.0 mg/l Limestone Ingestion Rat LD50 6,450 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Inert Filler Dermal LD50 estimated to be > 5,000 mg/kg Inert Filler Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Magnesium Carbonate Ingestion Mouse LD50 > 5,000 mg/kg Synthetic Crystalline-Free Silica Gel Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Crystalline-Free Silica Gel Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Crystalline-Free Silica Gel Ingestion Rat LD50 > 5,110 mg/kg Trimethylolpropane Triacrylate Dermal Rabbit LD50 5,170 mg/kg Trimethylolpropane Triacrylate Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Styrene Monomer official classifica tion Mild irritant Limestone Rabbit No significant irritation Talc Rabbit No significant irritation Titanium Dioxide Rabbit No significant irritation Inert Filler Professio nal judgeme nt No significant irritation Magnesium Carbonate In vitro data Minimal irritation Synthetic Crystalline-Free Silica Gel Rabbit No significant irritation Trimethylolpropane Triacrylate Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Styrene Monomer official classifica tion Moderate irritant Limestone Rabbit No significant irritation Talc Rabbit No significant irritation Titanium Dioxide Rabbit No significant irritation 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 10 of 14 Inert Filler Professio nal judgeme nt No significant irritation Magnesium Carbonate Rabbit Mild irritant Synthetic Crystalline-Free Silica Gel Rabbit No significant irritation Trimethylolpropane Triacrylate Rabbit Corrosive Skin Sensitization Name Species Value Styrene Monomer Guinea pig Not sensitizing Titanium Dioxide Human and animal Not sensitizing Synthetic Crystalline-Free Silica Gel Human and animal Not sensitizing Trimethylolpropane Triacrylate Guinea pig Sensitizing Respiratory Sensitization Name Species Value Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Styrene Monomer In Vitro Some positive data exist, but the data are not sufficient for classification Styrene Monomer In vivo Some positive data exist, but the data are not sufficient for classification Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Inert Filler In Vitro Some positive data exist, but the data are not sufficient for classification Synthetic Crystalline-Free Silica Gel In Vitro Not mutagenic Trimethylolpropane Triacrylate In vivo Not mutagenic Trimethylolpropane Triacrylate In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Styrene Monomer Ingestion Mouse Carcinogenic Styrene Monomer Inhalation Human and animal Carcinogenic Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Inert Filler Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Synthetic Crystalline-Free Silica Gel Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Trimethylolpropane Triacrylate Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 11 of 14 Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Styrene Monomer Ingestion Not toxic to female reproduction Rat NOAEL 21 mg/kg/day 3 generation Styrene Monomer Inhalation Not toxic to female reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Inhalation Not toxic to male reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 60 days Styrene Monomer Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during gestation Styrene Monomer Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2.1 mg/l during gestation Limestone Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day premating & during gestation Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Synthetic Crystalline-Free Silica Gel Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Crystalline-Free Silica Gel Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Crystalline-Free Silica Gel Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Styrene Monomer Inhalation auditory system Causes damage to organs Multiple animal species LOAEL 4.3 mg/l not available Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 mg/l not available Styrene Monomer Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Styrene Monomer Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Styrene Monomer Inhalation endocrine system All data are negative Rat NOAEL Not available not available Styrene Monomer Inhalation kidney and/or bladder All data are negative Multiple animal species NOAEL 2.1 mg/l not available Limestone Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Styrene Monomer Inhalation eyes Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Styrene Monomer Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Multiple animal species NOAEL 1.3 mg/l not available Styrene Monomer Inhalation liver May cause damage to organs Mouse LOAEL 0.85 13 weeks 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 12 of 14 though prolonged or repeated exposure mg/l Styrene Monomer Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Multiple animal species LOAEL 1.1 mg/l not available Styrene Monomer Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.85 mg/l 7 days Styrene Monomer Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.6 mg/l 10 days Styrene Monomer Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species LOAEL 0.09 mg/l not available Styrene Monomer Inhalation heart | bone, teeth, nails, and/or hair | muscles | kidney and/or bladder All data are negative Multiple animal species NOAEL 4.3 mg/l 2 years Styrene Monomer Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 500 mg/kg/day 8 weeks Styrene Monomer Ingestion immune system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available not available Styrene Monomer Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 677 mg/kg/day 6 months Styrene Monomer Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 600 mg/kg/day 470 days Styrene Monomer Ingestion heart | respiratory system All data are negative Rat NOAEL 35 mg/kg/day 105 weeks Limestone Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Inert Filler Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Synthetic Crystalline-Free Silica Gel Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Trimethylolpropane Triacrylate Dermal immune system May cause damage to organs though prolonged or repeated exposure Mouse NOAEL 50 mg/kg/day 16 days Trimethylolpropane Triacrylate Dermal heart | hematopoietic system | kidney and/or bladder | respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 12 mg/kg/day 28 weeks Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 13 of 14 SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Styrene Monomer 100-42-5 10 - 30 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Titanium Dioxide 13463-67-7 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories 3M? Flowable Finishing Putty PN 05823, 05824 04/24/15 __________________________________________________________________________________________ Page 14 of 14 The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 25-7697-3 Version Number: 3.00 Issue Date: 04/24/15 Supercedes Date: 03/16/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com