Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 1 of 9 Section 1: IDENTIFICATION 1.1 PRODUCT IDENTIFIER Product Name: Kool-It Supreme Coolant Treatment Product Code: 96001, 96050, 96055, 96110, 96808 1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE Use: Supplemental Coolant Additive. 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Name/Address: International Lubricants, Inc. P.O. Box 24743, Seattle WA 98124-0743, USA Telephone Number: (206) 762-5343 (800) 333-LUBE (5823) 1.4 EMERGENCY TELEPHONE NUMBER Emergency Telephone Number: CHEM TEL (800) 255-3924 CHEM TEL (813) 248-0585 Section 2: HAZARD(S) IDENTIFICATION 2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012 Hazard class Skin Irritant 2 Eye Irritant 2A Reproductive Toxicity 2 2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012 Hazard Pictogram: Signal Word: Warning Hazard Statement: Causes skin irritation. Causes serious eye irritation. Suspected of damaging fertility or the unborn child. Prevention: Wash hands thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Response: If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. Take off contaminated clothing and wash before reuse. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 2 of 9 Storage: Store locked up. Disposal: Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3 ADDITIONAL INFORMATION Hazards not otherwise classified: Not available. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 MIXTURES Ingredient CAS No Wt. % Sodium nitrite 7632-00-0 0.5 - 1.5 Sodium metasilicate 6834-92-0 0.1 - 1 Sodium tetraborate decahydrate 1303-96-4 0.1 - 1 Sodium hydroxide 1310-73-2 0.1 - 1 Potassium hydroxide 1310-58-3 0.1 - 1 Phenolphthalein 77-09-8 < 0.1 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. Section 4: FIRST- AID MEASURES 4.1 DESCRIPTION OF THE FIRST AID MEASURE Eye: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. Skin: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. Inhalation: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED Eye: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Skin: Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Inhalation: May cause respiratory tract irritation. Ingestion: May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 3 of 9 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED Note to Physicians: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific Treatments: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Section 5: FIRE-FIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide. Unsuitable Extinguishing Media: None known. 5.2 SPECIAL HAZARDS ARISING FROM THE CHEMICAL Products of Combustion: May include, and are not limited to: oxides of carbon, nitrogen oxides, phosphorus oxides, metal oxides. 5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Section 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP Methods for Containment: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for Cleaning-Up: Scoop up material and place in a disposal container. Provide ventilation. Section 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Handling: Avoid contact with skin and eyes. Avoid breathing vapour or mist. Do not swallow. Handle and open container with care. Use only outdoors or in a well-ventilated area. When using do not eat, drink or smoke.(See section 8) General Hygiene Advice: Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Storage: Keep out of the reach of children. Keep container tightly closed. Keep only in original container. Keep out of direct sunlight. Store in a cool, dry, well ventilated place away from incompatible materials. (See section 10) Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 4 of 9 Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTROL PARAMETERS Exposure Guidelines Occupational Exposure Limits Ingredient OSHA-PEL ACGIH-TLV Sodium nitrite Not available. Not available. Sodium metasilicate Not available. Not available. Sodium tetraborate decahydrate Not available. 2 mg/m? TWA (inhalable fraction) 6 mg/m? STEL (inhalable fraction) Sodium hydroxide 2 mg/m? 2 mg/m? Potassium hydroxide Not available. 2 mg/m? Phenolphthalein Not available. Not available. 8.2 EXPOSURE CONTROLS Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. 8.3 INDIVIDUAL PROTECTIVE MEASURES Personal Protective Equipment: Eye/Face Protection: Wear eye protection. Skin Protection: Hand Protection: Wear chemically resistant protective gloves. Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. General Health and Safety Measures: Handle according to established industrial hygiene and safety practices. Section 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Appearance: Not available. Color: Pink. Odor: None. Odor Threshold: Not available. Physical State: Liquid. pH: 11.2 - 11.3 Melting Point/Freezing Point: Not available. Initial Boiling Point and Boiling Range: Not available. Flash Point: > 93.3 ?C (>200 ?F) Evaporation Rate: Not available. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 5 of 9 Flammability: Not flammable. Lower Flammability/Explosive Limit: Not available. Upper Flammability/Explosive Limit: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Relative Density/Specific Gravity: 1.05 g/mL Solubility: Easily soluble in the following materials: cold water and hot water. Partition coefficient: n-octanol/water: Not available. Auto-ignition Temperature: Not available. Decomposition Temperature: Not available. Viscosity: Not available. Oxidizing Properties: Not available. Explosive Properties: Not available. Section 10: STABILITY AND REACTIVITY 10.1 REACTIVITY No dangerous reaction known under conditions of normal use. 10.2 CHEMICAL STABILITY Stable under normal storage conditions. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS No dangerous reaction known under conditions of normal use. 10.4 CONDITIONS TO AVOID Heat. Incompatible materials. 10.5 INCOMPATIBLE MATERIALS Oxidizers, reducing agents, acids, moisture. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS May include, and are not limited to: oxides of carbon, nitrogen oxides, phosphorus oxides, metal oxides. Section 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS Likely Routes of Exposure: Skin contact, eye contact, inhalation, and ingestion. Symptoms related to physical/chemical/toxicological characteristics: Eye: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Skin: Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 6 of 9 Ingestion: May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Inhalation: May cause respiratory tract irritation. Acute Toxicity: Ingredient LC50 LD50 Sodium nitrite Inhalation LC50 Rat 5.5 mg/L 4 h Oral LD50 Rat180 mg/kg Sodium metasilicate Not available. Oral LD50 Rat 600 mg/kg Sodium tetraborate decahydrate Not available. Oral LD50 Rat 2660 mg/kg Sodium hydroxide Not available. Oral LDlo Rabbit 500 mg/kg; Dermal LD50 Rabbit 1350 mg/kg Potassium hydroxide Not available. Oral LD50 Rat 214 mg/kg Phenolphthalein Not available. Oral LD50 Rat > 2000 mg/kg Dermal LD50 Rabbit > 3 g/kg Calculated overall Chemical Acute Toxicity Values LC50 (inhalation) LD50 (oral) LD50 (dermal) > 20 mg/L 4 h, rat > 2000 mg/kg, rat > 2000 mg/kg, rabbit Ingredient Chemical Listed as Carcinogen or Potential Carcinogen (NTP, IARC, OSHA, ACGIH, CP65)* Sodium nitrite Not listed. Sodium metasilicate Not listed. Sodium tetraborate decahydrate G-A4 Sodium hydroxide Not listed. Potassium hydroxide Not listed. Phenolphthalein I-2B, N-2, CP65 * See Section 15 for more information. 11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory Sensitization: Based on available data, the classification criteria are not met. Skin Sensitization: Based on available data, the classification criteria are not met. STOT-Single Exposure: Based on available data, the classification criteria are not met. Chronic Health Effects: Carcinogenicity: Based on available data, the classification criteria are not met. Germ Cell Mutagenicity: Based on available data, the classification criteria are not met. Reproductive Toxicity: Developmental: Suspected of damaging the unborn child. Fertility: Suspected of damaging fertility. STOT-Repeated Exposure: Based on available data, the classification criteria are not met. Aspiration Hazard: Based on available data, the classification criteria are not met. Other Information: Not available. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 7 of 9 Section 12: ECOLOGICAL INFORMATION 12.1 ECOTOXICITY Acute/Chronic Toxicity: May cause long-term adverse effects in the aquatic environment. 12.2 PERSISTENCE AND DEGRADABILITY Not available. 12.3 BIOACCUMULATIVE POTENTIAL Bioaccumulation: Not available. 12.4 MOBILITY IN SOIL Not available. 12.5 OTHER ADVERSE EFFECTS Not available. Section 13: DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS Disposal Method: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. Other disposal recommendations: Not available. Section 14: TRANSPORT INFORMATION 14.1 UN NUMBER Not regulated. 14.2 UN PROPER SHIPPING NAME Not applicable. 14.3 TRANSPORT HAZARD CLASS(ES) Not applicable. 14.4 PACKING GROUP Not applicable. 14.5 ENVIRONMENTAL HAZARDS Not applicable. 14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE Not applicable. 14.7 SPECIAL PRECAUTIONS FOR USER Do not handle until all safety precautions have been read and understood. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 8 of 9 Section 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE CHEMICAL SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 SARA Title III Ingredient Section 302 (EHS) TPQ (lbs.) Section 304 EHS RQ (lbs.) CERCLA RQ (lbs.) Section 313 Sodium nitrite Not listed. Not listed. 100 313 Sodium metasilicate Not listed. Not listed. Not listed. Not listed. Sodium tetraborate decahydrate Not listed. Not listed. Not listed. Not listed. Sodium hydroxide Not listed. Not listed. 1,000 Not listed. Potassium hydroxide Not listed. Not listed. 1,000 Not listed. Phenolphthalein Not listed. Not listed. Not listed. 313 State Regulations California Proposition 65: This product contains a chemical known to the State of California to cause cancer. Global Inventories: Ingredient USA TSCA Sodium nitrite Yes. Sodium metasilicate Yes. Sodium tetraborate decahydrate Yes. Sodium hydroxide Yes. Potassium hydroxide Yes. Phenolphthalein Yes. NFPA-National Fire Protection Association: Health: 2 Fire: 1 Reactivity: 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC (I) International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. Conforms to OSHA HazCom 2012 Standard SAFETY DATA SHEET Trade Name: Kool-It Supreme Coolant Treatment Print date: 2015-05-20 Page 9 of 9 NTP (N) National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Date of Preparation: January 7, 2015 Version: 1.1 Revision Date: May 20, 2015 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. Prepared by: Nexreg Compliance Inc. Phone: (519) 488-5126 www.nexreg.com Prepared for: International Lubricants Inc. End of Safety Data Sheet Exposure Guidelines SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: