SDS_US - POWERZOL? ZG6000 1/21 Version : 2 . 0 Revision Date : 03/24/2016 SAFETY DATA SHEET 1. Identification Identification Product name: POWERZOL? ZG6000 Additional identification Chemical name: Mixture Recommended use and restriction on use Recommended use: Aftermarket Gasoline Restrictions on use: None identified. Details of the supplier of the safety data sheet Supplier Company Name: THE LUBRIZOL CORPORATION Address: 29400 LAKELAND BOULEVARD WICKLIFFE, OH 44092-2298 US Telephone: (440)943-1200 Emergency telephone number: FOR TRANSPORT EMERGENCY CALL CHEMTREC (+1)703 527 3887, OR WITHIN USA 800 424 9300 (LUBRIZOL) 2. Hazard(s) identification Hazard Classification Physical Hazards Flammable liquids Health Hazards Category 2 Skin Corrosion/Irritation Category 1B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Toxic to reproduction Category 2 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ Toxicity - Repeated Exposure Category 2 Aspiration Hazard Unknown toxicity Category 1 Acute toxicity, oral 0.0 % Acute toxicity, dermal 2.2 % Acute toxicity, inhalation, vapor 20.6 % Acute toxicity, inhalation, dust or mist 50.6 % 10-3015, 19355198 ? ACDelco Top Engine Cleaner SDS_US - POWERZOL? ZG6000 2/21 Version : 2 . 0 Revision Date : 03/24/2016 Label Elements: Hazard Symbol: Signal Word: Danger Hazard Statement: Highly flammable liquid and vapor. Causes severe skin burns and eye damage. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary Statement: Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust or mists. Wash thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER/doctor. Specific treatment (see this label). Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical or foam for extinction. Water can be used to cool and protect exposed material. Collect spillage. Storage: Store in well-ventilated place. Keep cool. Store locked up. Keep container tightly closed. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result Static accumulating flammable liquid can become in GHS classification: electrostatically charged even in bonded and grounded SDS_US - POWERZOL? ZG6000 3/21 Version : 2 . 0 Revision Date : 03/24/2016 equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients General information: Chemical name CAS number Percent by Weight Isopropyl alcohol 67-63-0 20 - 30% Xylene 1330-20-7 10 - 20% Polyether amine Confidential 10 - 20% Butyl cellosolve 111-76-2 10 - 20% Toluene 108-88-3 10 - 20% Ethyl benzene 100-41-4 1 - 5% Morpholine 110-91-8 1 - 5% Alkenyl amine Confidential 1 - 5% Cyclic amide 872-50-4 1 - 5% Triethanolamine 102-71-6 1 - 5% Trade secret information: A specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures General information: Get medical advice/attention if you feel unwell. Ingestion: Do NOT induce vomiting. Aspiration of material due to vomiting can cause chemical pneumonitis which can be fatal. If vomiting occurs naturally, the casualty should lean forward to reduce the risk of aspiration. Rinse mouth. Immediately call a POISON CENTER/doctor. Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician or poison control center immediately. Skin Contact: Take off immediately all contaminated clothing. Wash with soap and water. Immediately call a POISON CENTER/doctor. Launder contaminated clothing before reuse. SDS_US - POWERZOL? ZG6000 4/21 Version : 2 . 0 Revision Date : 03/24/2016 Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Most important symptoms/effects, acute and delayed Symptoms: Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Treatment: Treat symptomatically. 5. Fire-fighting measures General Fire Hazards: Use water spray to keep fire-exposed containers cool. Water may be ineffective in fighting the fire. Fight fire from a protected location. Move containers from fire area if you can do so without risk. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material. Unsuitable extinguishing media: Not determined. Specific hazards arising from the chemical: Water may cause splattering. Container may rupture on heating. Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. See section 10 for additional information. Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: Special protective Firefighters must use standard protective equipment including flame equipment for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Ventilate area if spilled in confined space or other poorly ventilated areas. Ventilate closed spaces before entering them. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep upwind. Keep unauthorized personnel away. See Section 8 of the SDS for Personal Protective Equipment. SDS_US - POWERZOL? ZG6000 5/21 Version : 2 . 0 Revision Date : 03/24/2016 Methods and material for containment and cleaning up: Eliminate all ignition sources if safe to do so. Dike far ahead of larger spill for later recovery and disposal. Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or confined areas. Environmental Precautions: Avoid release to the environment. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. 7. Handling and storage Precautions for safe handling: Minimize exposure to air. If peroxide formation is suspected, do not open or move container. Do not distill to near dryness. Distillation residues should be handled with caution until shown to be peroxide-free. Open container in a well ventilated area. Avoid breathing vapors. Do not use sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharges. Ground and bond container and receiving equipment. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, on clothing. Do not get in eyes. Observe good industrial hygiene practices. Provide adequate ventilation. Use personal protective equipment as required. Wash hands thoroughly after handling. Launder contaminated clothing before reuse. Avoid environmental contamination. Maximum Handling Not determined. Temperature: Conditions for safe storage, Prolonged contact with air may cause formation of explosive peroxides. including any Keep container tightly closed. Keep cool. Store in a well-ventilated place. incompatibilities: Do not store near potential sources of ignition. Maximum Storage > 0 ?C > 32 ?F Temperature: SDS_US - POWERZOL? ZG6000 6/21 Version : 2 . 0 Revision Date : 03/24/2016 8. Exposure controls/personal protection Control Parameters: Occupational Exposure Limits Chemical name type Exposure Limit Values Source Isopropyl alcohol TWA 200 ppm US. ACGIH Threshold Limit Values (02 2012) Isopropyl alcohol STEL 400 ppm US. ACGIH Threshold Limit Values (02 2012) Isopropyl alcohol REL 400 ppm 980 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Isopropyl alcohol STEL 500 ppm 1,225 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Isopropyl alcohol PEL 400 ppm 980 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Xylene TWA 100 ppm US. ACGIH Threshold Limit Values (02 2012) Xylene STEL 150 ppm US. ACGIH Threshold Limit Values (02 2012) Xylene PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Butyl cellosolve TWA 20 ppm US. ACGIH Threshold Limit Values (02 2012) Butyl cellosolve REL 5 ppm 24 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Butyl cellosolve PEL 50 ppm 240 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Toluene TWA 20 ppm US. ACGIH Threshold Limit Values (02 2012) Toluene STEL 150 ppm 560 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Toluene REL 100 ppm 375 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Toluene TWA 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) Toluene Ceiling 300 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) Toluene MAX. CONC 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006) Ethyl benzene TWA 20 ppm US. ACGIH Threshold Limit Values (02 2012) Ethyl benzene REL 100 ppm 435 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Ethyl benzene STEL 125 ppm 545 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Ethyl benzene PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Ethyl benzene STEL 125 ppm 545 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Morpholine TWA 20 ppm US. ACGIH Threshold Limit Values (02 2012) Morpholine STEL 30 ppm 105 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Morpholine REL 20 ppm 70 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Morpholine PEL 20 ppm 70 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Morpholine TWA 20 ppm 70 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Morpholine STEL 30 ppm 105 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Triethanolamine TWA 5 mg/m3 US. ACGIH Threshold Limit Values (02 2012) Biological Limit Values SDS_US - POWERZOL? ZG6000 7/21 Version : 2 . 0 Revision Date : 03/24/2016 Chemical name Exposure Limit Values Source Isopropyl alcohol (acetone: Sampling time: End of shift at end of work week.) 40 mg/l (Urine) ACGIH BEI (03 2013) Xylene (Methylhippuric acids: Sampling time: End of shift.) 1.5 g/g (Creatinine in urine) ACGIH BEI (03 2013) Butyl cellosolve (Butoxyacetic acid (BAA), with hydrolysis: Sampling time: End of shift.) 200 mg/g (Creatinine in urine) ACGIH BEI (03 2013) Toluene (o-Cresol, with hydrolysis: Sampling time: End of shift.) 0.3 mg/g (Creatinine in urine) ACGIH BEI (03 2013) Toluene (toluene: Sampling time: Prior to last shift of work week.) 0.02 mg/l (Blood) ACGIH BEI (03 2013) Toluene (toluene: Sampling time: End of shift.) 0.03 mg/l (Urine) ACGIH BEI (03 2013) Ethyl benzene (Sum of mandelic acid and phenylglyoxylic acid: Sampling time: End of shift.) 0.15 g/g (Creatinine in urine) ACGIH BEI (02 2014) Appropriate engineering Use material in well ventilated area only. Adequate ventilation should be controls: provided so that exposure limits are not exceeded. Mechanical ventilation or local exhaust ventilation may be required. Use explosion-proof ventilation equipment to stay below exposure limits. Individual protection measures, such as personal protective equipment General information: Use explosion-proof ventilation equipment. Provide easy access to water supply and eye wash facilities. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye/face protection: Skin Protection Wear tight-fitting goggles or face shield. Hand Protection: Neoprene. Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Other: Chemical resistant boots. Wear apron or protective clothing in case of contact. Long sleeve shirt is recommended. Wear apron or protective clothing in case of contact. Chemical resistant boots. Do not wear rings, watches or similar apparel that could entrap the material. SDS_US - POWERZOL? ZG6000 8/21 Version : 2 . 0 Revision Date : 03/24/2016 Respiratory Protection: Use respirator if irritation is experienced or if the recommended exposure limit is exceeded. Use respirator with a combination organic vapor and dust/mist cartridge. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Hygiene measures: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Observe good industrial hygiene practices. Do not get this material in contact with skin. Do not get in eyes. Wash contaminated clothing before reuse. When using do not smoke. Wash hands before breaks and immediately after handling the product. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: Light amber Odor: No data available. Odor threshold: No data available. pH: No data available. Freezing point: No data available. Boiling Point: 231.6 - 930.0 ?F (110.9 - 498.9 ?C) Flash Point: 55 ?F (13 ?C) (Pensky-Martens Closed Cup) Evaporation rate: No data available. Flammability (solid, gas): No data available. Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): No data available. Flammability limit - lower (%): No data available. Explosive limit - upper (%): No data available. Explosive limit - lower (%): No data available. Vapor pressure: No data available. Vapor density: No data available. Relative density: 0.863 - 0.903 60.1 ?F (15.6 ?C) Solubility(ies) Solubility in water: partly soluble Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. SDS_US - POWERZOL? ZG6000 9/21 Version : 2 . 0 Revision Date : 03/24/2016 Viscosity: 2.4 mm2/s ( 104 ?F (40 ?C) ) 6.9 mm2/s (0 ?C (32 ?F) ) 13.6 mm2/s (-18 ?C (-0.40 ?F) ) 3.4 mm2/s (25 ?C (77 ?F) ) Other information Bulk density: 7.36 lb/gal 60.1 ?F (15.6 ?C) Pour Point Temperature: -157 ?F (-105 ?C) 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous Will not occur. reactions: Conditions to avoid: Do not expose to excessive heat, ignition sources, or oxidizing materials. Heat, sparks, flames. Incompatible Materials: Amines. Aldehydes. Bases. Halogens and halogenated compounds. Strong acids. Reducing agents. Strong alkalis. Alkalies. Aluminum. mineral acids Avoid contact with nitrites, nitrates or nitrosating agents due to the potential for nitrosamine formation. Strong oxidizing agents. Hazardous Decomposition Products: Ammonia. Propylamine, polyalkylglycols, and aliphatic alcohols may also be released. Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, and other products of incomplete combustion. 11. Toxicological information Information on likely routes of exposure Inhalation: No data available. Ingestion: May be harmful if swallowed. Skin Contact: May be harmful in contact with skin. Causes severe skin burns. Eye contact: Causes serious eye damage. Information on toxicological effects Acute toxicity Oral Product: Ingestion can cause central nervous system effects such as headache, dizziness, drowsiness, and generalized weakness. Swallowing this material causes irritation of mouth, esophagus and stomach, with nausea, vomiting, diarrhea and abdominal pain. Ingestion may cause red blood cell hemolysis and possible liver and kidney injury. Swallowing material may cause irritation of the gastrointestinal lining, nausea, vomiting, diarrhea, and abdominal pain. ATEmix > 2,000 mg/kg. SDS_US - POWERZOL? ZG6000 10/21 Version : 2 . 0 Revision Date : 03/24/2016 Dermal Product: Inhalation Components of this material may be absorbed through the skin. Components of this material are absorbed through the skin. Skin absorption of components of this material will cause systemic effects; note toxicity in other sections. ATEmix > 2,000 mg/kg Product: Breathing high vapor concentrations may cause adverse central nervous system effects such as dizziness, light-headedness, headache, drowsiness, nausea and loss of coordination. High concentrations may cause headaches, dizziness, fatigue, nausea, vomiting, drowsiness, stupor, other central nervous system effects leading to visual impairment, respiratory failure, unconsciousness and death. High concentrations may cause headaches, dizziness, weakness, irritability and other behavioral changes, nausea, and vomiting. High concentrations may cause headaches, dizziness, nausea, stupor, and other central nervous system effects leading to visual impairment, difficulty breathing and convulsions. ATEmix (, 4 h): > 20 mg/l. Vapour Skin Corrosion/Irritation: Product: Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. Symptoms may include redness, edema, drying, and cracking of the skin. Prolonged or repeated exposure may cause severe irritation. Prolonged or repeated contact may cause irritation. Remarks: Causes severe skin burns. Serious Eye Damage/Eye Irritation: Product: Respiratory sensitization: Skin sensitization: Remarks: Causes serious eye damage. No data available Isopropyl alcohol Classification: Not a skin sensitizer. (Literature) Not a skin sensitizer. Xylene (Literature) Not a skin sensitizer. Polyether amine Classification: Not a skin sensitizer. (Read across) Not a skin sensitizer. SDS_US - POWERZOL? ZG6000 11/21 Version : 2 . 0 Revision Date : 03/24/2016 Butyl cellosolve Classification: Not a skin sensitizer. (Literature) Not a skin sensitizer. Toluene (Read across) Not a skin sensitizer. Alkenyl amine Remarks: May cause skin sensitzation in sensitive individuals. Cyclic amide Classification: Not a skin sensitizer. (Literature) Not a skin sensitizer. Triethanolamine (Literature) May cause skin sensitzation in sensitive individuals. Specific Target Organ Toxicity - Single Exposure: Isopropyl alcohol May cause irritation to the mucous membranes and upper respiratory tract. Xylene May cause respiratory irritation. Polyether amine Nose, throat and lung irritant. Butyl cellosolve Nose, throat and lung irritant. Toluene Nose, throat and lung irritant. Ethyl benzene Nose, throat and lung irritant. Morpholine Nose, throat and lung irritant. Alkenyl amine Respiratory tract irritation. Cyclic amide Respiratory tract irritation. Triethanolamine If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract. Aspiration Hazard: Product: Other effects: May be fatal if swallowed and enters airways. Isopropyl alcohol Central nervous system May cause drowsiness or dizziness. Butyl cellosolve Central nervous system Toluene Central nervous system Narcotic effect. SDS_US - POWERZOL? ZG6000 12/21 Version : 2 . 0 Revision Date : 03/24/2016 Ethyl benzene Central nervous system Triethanolamine Chronic Effects Carcinogenicity: Liver Kidney Trace quantities of ethylene oxide (ETO) may accumulate in the headspace of storage vessels. Ethylene oxide is a potential carcinogens and reproductive hazard for humans. Although such exposures are not expected to exceed exposure limits, adequate ventilation is recommended. Product: Not available. Butyl cellosolve Butyl cellosolve: A National Toxicology Program (NTP) chronic inhalation study revealed some evidence of carcinogenic activity in male and female mice, equivocal evidence in female rats. and no evidence in male rats. Ethyl benzene A National Toxicology Program (NTP) study found an increased incidence of renal tubule neoplasms in male and female rats exposed to ethylbenzene by inhalation for two years. In male and female mice similarly exposed, increased incidences of alveolar/bronchiolar neoplasms, and hepatocellular neoplasms, respectively, were observed. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Ethyl benzene Overall evaluation: 2B. Possibly carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity: Isopropyl alcohol In vitro mutagenicity tests have been negative. Xylene This material has not exhibited mutagenic or genotoxic potential in laboratory tests. Butyl cellosolve This material has not exhibited mutagenic or genotoxic potential in laboratory tests. Toluene Results of tests in workers exposed to higher concentrations of toluene have shown that this material can cause irreversible changes in the genetic material (DNA) of a cell. The human health consequences of these changes is not fully understood. Alkenyl amine This material has not exhibited mutagenic or genotoxic potential in laboratory tests. SDS_US - POWERZOL? ZG6000 13/21 Version : 2 . 0 Revision Date : 03/24/2016 Cyclic amide In vitro mutagenicity tests have been negative. Triethanolamine In vitro mutagenicity tests have been negative. Reproductive toxicity: Isopropyl alcohol Teratogenic effects have been observed in laboratory animals only at maternally toxic doses. Xylene Xylene is fetotoxic in rats and rabbits in the absence of maternal toxicity. Butyl cellosolve Based on available data this product is not expected to be classified a reproductive hazard. Butyl cellosolve causes fetotoxicity in lab animals at doses which are maternally toxic. Toluene Prolonged and repeated exposure of pregnant animals to toluene by inhalation has been reported to cause adverse fetal developmental effects. Cyclic amide This material may have adverse affects on the reproductive systems or to fetal development. Fetal effects have been seen in pregnant animals exposed by ingestion, inhalation and skin contact to cyclic amide, which has occurred in the presence and absence of maternal toxicity. Specific Target Organ Toxicity - Repeated Exposure: Product: In a 4 week inhalation study with rats, cyclic amide caused effects on the lung, thymus, blood and lymph tissues. Repeated and prolonged ingestion of cyclic amide caused increased severity of spontaneous progressive nephropathy in male rats, and increased liver weight and cell hypertrophy in male and female mice. Repeated overexposure may result in liver and kidney damage. Xylene Xylene has been found to cause cardiac, liver and kidney effects, anemia and eye damage in laboratory animals. Prolonged and repeated inhalation of hydrocarbon solvents such as xylene can cause chronic neurological disturbances. Chronic exposure to xylene has been shown to cause hearing loss in experimental animals. Unknown: Target Organ(s): Central nervous system., Hearing Butyl cellosolve Repeated overexposure may result in liver and kidney damage. Dermal: Target Organ(s): Blood Inhalation: Target Organ(s): Blood Oral: Target Organ(s): Blood Toluene Repeated overexposure to toluene may cause loss of appetite, liver enlargement, and kidney and lung damage. Repeated inhalation of hydrocarbon solvents such as toluene can cause chronic SDS_US - POWERZOL? ZG6000 14/21 Version : 2 . 0 Revision Date : 03/24/2016 neurological disturbances. Chronic exposure to toluene has been shown to cause hearing loss in animal experiments. The effect may be potentiated by acetyl salicylic acid and n-hexane to produce irreversible auditory damage. Prolonged and repeated exposure to toluene may cause color vision loss in humans. Inhalation: Target Organ(s): Kidney, Liver, Central nervous system., Hearing Alkenyl amine Oral: Target Organ(s): digestive organs Cyclic amide Unknown: Target Organ(s): Central nervous system. Triethanolamine Repeated overexposure may result in liver and kidney damage. 12. Ecological information Ecotoxicity Fish Xylene LC 50 (Fathead Minnow, 4 Days): 13.4 mg/l LC 50 (Rainbow Trout, 4 Days): 2.6 mg/l LC 50 (Rainbow Trout, 56 d): > 1.3 mg/l NOEC (Rainbow Trout, 56 d): > 1.3 mg/l Butyl cellosolve LC 50 (Bluegill Sunfish, 4 d): 1,490 mg/l LC 50 (Rainbow Trout, 4 d): 1,471 mg/l LC 50 (Zebra Fish, 21 d): > 100 mg/l NOEC (Zebra Fish, 21 d): > 100 mg/l Toluene LC 50 (Coho salmon,silver salmon (Oncorhynchus kisutch), 96 h): 5.5 mg/l NOEC (Coho salmon,silver salmon (Oncorhynchus kisutch), 40 Days): 1.39 mg/l Ethyl benzene LC 50 (Rainbow Trout, 96 h): 4.2 mg/l LC 50 (Not reported, 96 h): 5.1 mg/l NOEC (Not reported, 96 h): 3.3 mg/l Alkenyl amine LC 50 (Fathead Minnow, 4 d): 0.11 mg/l LC 50 (Rainbow Trout, 4 d): 1.3 mg/l LC 50 (Sheepshead Minnow, 4 d): 0.9 mg/l Cyclic amide LC 50 (Rainbow Trout, 4 Days): > 500 mg/l Triethanolamine LC 50 (Rainbow Trout, 4 d): 11,800 mg/l Aquatic Invertebrates Xylene EC 50 (Water flea (Ceriodaphnia dubia), 7 d): > 1.17 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 3.82 mg/l EC 50 (Water flea (Daphnia magna), 7 d): > 0.96 mg/l NOEC (Water flea (Ceriodaphnia dubia), 7 d): 1.17 mg/l NOEC (Water flea (Daphnia magna), 7 d): 0.96 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 1.57 mg/l NOEC (Water flea (Daphnia magna), 21 d): 1.57 mg/l Butyl cellosolve EC 50 (Water flea (Daphnia magna), 2 d): 1,550 mg/l SDS_US - POWERZOL? ZG6000 15/21 Version : 2 . 0 Revision Date : 03/24/2016 EC 50 (Water flea (Daphnia magna), 21 d): 297 mg/l NOEC (Water flea (Daphnia magna), 21 d): 100 mg/l Toluene EC 50 (Water Flea (Ceriodaphnia Dubia), 48 h): 3.78 mg/l Ethyl benzene EC 50 (Water flea (Ceriodaphnia dubia), 7 d): 3.6 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 1.8 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): 2.6 mg/l NOEC (Water flea (Ceriodaphnia dubia), 7 d): 1 mg/l NOEC (Shrimp (Mysidopsis Bahia), 4 d): 1 mg/l Alkenyl amine EC 50 (Water flea (Daphnia magna), 2 d): 0.011 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.27 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.013 mg/l Cyclic amide EC 50 (Water flea (Daphnia magna), 1 d): > 1,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 12.5 mg/l NOEC (Water flea (Daphnia magna), 21 d): 12.5 mg/l Triethanolamine EC 50 (Water flea (Ceriodaphnia dubia), 2 d): 609.88 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 16 mg/l NOEC (Water flea (Daphnia magna), 21 d): 16 mg/l Toxicity to Aquatic Plants Xylene LC 50 (Alga, 3 Days): 4.36 mg/l Butyl cellosolve EC 50 (Green algae (Selenastrum capricornutum), 3 d): 911 mg/l EC 50 (Green algae (Selenastrum capricornutum), 7 d): > 1,000 mg/l NOEC (Green algae (Selenastrum capricornutum), 3 d): 88 mg/l Toluene EC 50 (Green algae (Chlorella vulgaris), 3 h): 134 mg/l Ethyl benzene EC 50 (Green algae (Selenastrum capricornutum), 96 h): 3.6 mg/l NOEC (Green algae (Selenastrum capricornutum), 96 h): 3.4 mg/l NOEC (Alga, 96 h): 4.5 mg/l EC 50 (Alga, 96 h): 7.7 mg/l Alkenyl amine EC 50 (Alga, 3 d): > 0.1 mg/l Cyclic amide EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 600.5 mg/l Triethanolamine EC 50 (Green algae (Selenastrum capricornutum), 3 d): 512 mg/l Toxicity to soil dwelling organisms No data available Sediment Toxicity No data available Toxicity to Terrestrial Plants No data available Toxicity to Above-Ground Organisms SDS_US - POWERZOL? ZG6000 16/21 Version : 2 . 0 Revision Date : 03/24/2016 No data available Toxicity to microorganisms Xylene LD 50 (Bacteria, 0.1 Days): > 100 mg/l Butyl cellosolve EC 50 (Sludge, 0.1 d): > 1,000 mg/l Alkenyl amine EC 50 (Sludge, 0.1 d): 15.5 mg/l Triethanolamine Persistence and Degradability Biodegradation EC 50 (Sludge, 7.5 d): > 1,000 mg/l Xylene OECD TG 301 C, 100 %, 28 d, Readily biodegradable Butyl cellosolve OECD TG 302 B, 100 %, 28 d, Readily biodegradable OECD TG 301 E, 95 %, 28 d, Readily biodegradable OECD TG 301 B, 90.4 %, 28 d, Readily biodegradable Toluene Miscellaneous, 80 %, 20 d, Readily biodegradable Ethyl benzene Miscellaneous, 79 %, 28 d, Readily biodegradable Alkenyl amine OECD TG 301 D, 44 %, 28 d, Readily biodegradable OECD TG 301 D, 72 %, 42 d, Not readily degradable. OECD TG 301 B, 66 %, 28 d, Readily biodegradable Cyclic amide OECD TG 301 C, 73 %, 28 d, Readily biodegradable Triethanolamine Bioaccumulative Potential Bioconcentration Factor (BCF) OECD TG 301 E, 96 %, 19 d, Readily biodegradable Xylene Bioconcentration Factor (BCF): 23.99 (Measured) Ethyl benzene Bioconcentration Factor (BCF): 1 (Measured) Alkenyl amine Bioconcentration Factor (BCF): 500 (calculated) Partition Coefficient n-octanol / water (log Kow) Xylene Log Kow: 3.15 (Measured) Butyl cellosolve Log Kow: 0.81 (Measured) Ethyl benzene Log Kow: 1.75 (calculated) Log Kow: 3.6 (Measured) Alkenyl amine Log Kow: 7.5 (calculated) Cyclic amide Log Kow: -0.46 (Measured) SDS_US - POWERZOL? ZG6000 17/21 Version : 2 . 0 Revision Date : 03/24/2016 Triethanolamine Mobility: Log Kow: -1.75 (calculated) No data available Other Adverse Effects: No data available. 13. Disposal considerations Disposal instructions: Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Dispose of packaging or containers in accordance with local, regional, national and international regulations. Empty containers retain material residue. Do not cut, weld, braze, solder, drill, grind or expose containers to heat, flame, spark or other sources of ignition. Contaminated Packaging: Container packaging may exhibit hazards. 14. Transport information DOT UN Number: UN 2924 UN Proper Shipping Name: Flammable liquids, corrosive, n.o.s.(Xylene, Morpholine) Transport Hazard Class(es) Class: 3 Label(s): 3, 8 Packing Group: II Marine Pollutant: Yes Special precautions for user: None established Reportable quantity Morpholine IMDG Xylene 100 lbs UN Number: UN 2924 UN Proper Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.(Xylene, Morpholine) Transport Hazard Class(es) Class: 3 Label(s): 3, 8 EmS No.: F-E, S-C Packing Group: II Marine Pollutant: Yes Limited quantity 1.00L Excepted quantity E2 Special precautions for user: IATA None established UN Number: UN 2924 Proper Shipping Name: Flammable liquid, corrosive, n.o.s.(Xylene, Morpholine) Transport Hazard Class(es): Class: 3 Label(s): 3, 8 SDS_US - POWERZOL? ZG6000 18/21 Version : 2 . 0 Revision Date : 03/24/2016 Marine Pollutant: Yes Packing Group: II Limited quantity 0.50L Excepted quantity E2 Environmental Hazards Marine Pollutant Special precautions for user: Other information None established Passenger and cargo aircraft: Allowed. Cargo aircraft only: Allowed. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code None known. The DOT shipping information in this section is based on a bulk container. Please review the accompanying shipping papers for the correct shipping descriptions based the size of the package. Shipping descriptions may vary based on mode of transport, quantities, temperature of the material, package size, and/or origin and destination. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. During transportation, steps must be taken to prevent load shifting or materials falling, and all relating legal statutes should be obeyed. Review classification requirements before shipping materials at elevated temperatures. 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4) Chemical Identity CAS number Reportable quantity Calculated1 Xylene 1330-20-7 100 lbs 652 lbs 296 kgs Toluene 108-88-3 1000 lbs 9889 lbs 4486 kgs Ethyl benzene 100-41-4 1000 lbs 26042 lbs 11813 kgs Diethanolamine 111-42-2 100 lbs > 50000 lbs > 22680 kgs Ethylenediamine 107-15-3 5000 lbs > 50000 lbs > 22680 kgs Benzene 71-43-2 10 lbs > 50000 lbs > 22680 kgs N-ethylmopholine Confidential 100 lbs > 50000 lbs > 22680 kgs Alkyl alcohol 71-23-8 100 lbs > 50000 lbs > 22680 kgs 1This is the amount product/material required to be released before CERCLA reporting is required. Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 311 Classifications Fire Hazard Immediate (Acute) Health Hazards SDS_US - POWERZOL? ZG6000 19/21 Version : 2 . 0 Revision Date : 03/24/2016 Delayed (Chronic) Health Hazard SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity CAS number Percent by Weight Reportable quantity Xylene 1330-20-7 15.4 % 100 lbs Butyl cellosolve 111-76-2 12.0 % *See regulation for further details Toluene 108-88-3 10.1 % 1000 lbs Ethyl benzene 100-41-4 3.8 % 1000 lbs Morpholine 110-91-8 3.6 % *See regulation for further details Diethanolamine 111-42-2 216.0 PPM 100 lbs Methyl Cellosolve 109-86-4 144.0 PPM *See regulation for further details Ethylenediamine 107-15-3 108.0 PPM 5000 lbs Benzene 71-43-2 79.0 PPM 10 lbs N-ethylmopholine Confidential 68.0 PPM 100 lbs Alkyl alcohol 71-23-8 44.0 PPM 100 lbs *These specific chemicals are not listed please check the generic entries on the SARA 304 listings for applicability. SARA 313 (TRI Reporting) Chemical Identity CAS number Percent by Weight Reporting threshold for other uses Reporting threshold for manufacturing and processing Isopropyl alcohol 67-63-0 29.5 % 10000 lbs 25000 lbs Xylene 1330-20-7 15.4 % 10000 lbs 25000 lbs Butyl cellosolve 111-76-2 12.0 % 10000 lbs 25000 lbs Toluene 108-88-3 10.1 % 10000 lbs 25000 lbs Ethyl benzene 100-41-4 3.8 % 10000 lbs 25000 lbs Cyclic amide 872-50-4 2.4 % 10000 lbs 25000 lbs US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Toluene 10.112% Ethyl benzene 3.84% Cyclic amide 2.389% Diethanolamine 216.00PPM Methyl Cellosolve 144.00PPM Benzene 79.00PPM Alkyl alcohol 44.00PPM Inventory Status SDS_US - POWERZOL? ZG6000 20/21 Version : 2 . 0 Revision Date : 03/24/2016 Australia (AICS) All components are in compliance with chemical notification requirements in Australia. Canada (DSL/NDSL) All components are in compliance with the Canadian Environmental Protection Act and are present on the Domestic Substances List. China (IECSC) All components of this product are listed on the Inventory of Existing Chemical Substances in China. European Union (REACh) To obtain information on the REACH compliance status of this product, please e-mail This email address is being protected from spambots. You need JavaScript enabled to view it.. Japan (ENCS) This product contains a substance that is not listed on the Japanese Existing and New Chemical Substances (ENCS) list. Korea (ECL) All components are in compliance in Korea. New Zealand (NZIoC) All components are in compliance with chemical notification requirements in New Zealand. Philippines (PICCS) All components are in compliance with the Philippines Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990 (R.A. 6969). Switzerland (SWISS) All components are in compliance with the Environmentally Hazardous Substances Ordinance in Switzerland. Taiwan (TCSCA) All components of this product are listed on the Taiwan inventory. United States (TSCA) All components of this material are on the US TSCA Inventory. The information that was used to confirm the compliance status of this product may deviate from the chemical information shown in Section 3. 16.Other information, including date of preparation or last revision HMIS Hazard ID Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible; *Chronic health effect NFPA Hazard ID Health * 3 Flammability 3 Physical Hazards 0 SDS_US - POWERZOL? ZG6000 21/21 Version : 2 . 0 Revision Date : 03/24/2016 Flammability Health Reactivity Special hazard. Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible Issue Date: 03/24/2016 Version #: 2.0 Source of information: Internal company data and other publically available resources. Further Information: Contact supplier (see Section 1) Disclaimer: As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local regulations remains the responsibility of the user. 3 0 3 Product name: POWERZOL? ZG6000 2. Hazard(s) identification 3. Composition/information on ingredients 8. Exposure controls/personal protection 11. Toxicological information 12. Ecological information 13. Disposal considerations 14. Transport information 15. Regulatory information 16.Other information, including date of preparation or last revision